发明授权
- 专利标题: Pressure-tuned solid catalyzed heterogeneous chemical reactions
- 专利标题(中): 压力调节固体催化的异质化学反应
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申请号: US09940015申请日: 2001-08-27
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公开(公告)号: US06924407B2公开(公告)日: 2005-08-02
- 发明人: Bala Subramaniam , Christopher James Lyon
- 申请人: Bala Subramaniam , Christopher James Lyon
- 申请人地址: US KS Lawrence
- 专利权人: The University of Kansas
- 当前专利权人: The University of Kansas
- 当前专利权人地址: US KS Lawrence
- 代理机构: Hovey Williams LLP
- 主分类号: B01J3/00
- IPC分类号: B01J3/00 ; B01J8/02 ; B01J31/10 ; B01J31/40 ; B01J35/10 ; B01J38/00 ; B01J38/04 ; C07B61/00 ; C07C2/58 ; C07C2/62 ; C07C9/15 ; C07C9/16 ; C07C9/18 ; C07C9/21 ; C07C11/02 ; C10G29/20 ; C07C2/56 ; B01J20/00 ; C07C5/22
摘要:
Improved methods for conducting solid acid-catalyzed, near- or supercritical heterogeneous chemical reactions (e.g., alkylation reactions) are provided which give enhanced product yields and permit longer processing runs. The preferred reactions of the invention are carried out in the presence of a solid macroporous catalyst having a surface area of from about 50-400 m2/g and a pore size of from about 70-150 Å. Product selectivity is enhanced by pressure-tuning of the reaction to promote production and separation of desired reaction products. In continuous processing, the chemical reaction may be interrupted before significant catalyst deactivation, followed by increasing reactor pressure and/or reducing reactor temperature to remove the accumulating coke; when the catalyst is regenerated, the original reaction conditions and reactant introduction may be resumed.