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    SYSTEM FOR PHOTOBIOSYNTHETIC PRODUCTION, SEPARATION AND SATURATION OF CARBONACEOUS CHEMICALS AND FUELS
    1.
    发明申请
    SYSTEM FOR PHOTOBIOSYNTHETIC PRODUCTION, SEPARATION AND SATURATION OF CARBONACEOUS CHEMICALS AND FUELS 审中-公开
    碳氢化合物和燃料的光合作用生产，分离和饱和系统

    公开(公告)号：US20120065439A1

    公开(公告)日：2012-03-15

    申请号：US13203717

    申请日：2010-03-01

    申请人： Christian Siemer ,  Simon Eric Aspland ,  Annastasiah Mudiwa Mhaka ,  Philip Goelet

    发明人： Christian Siemer ,  Simon Eric Aspland ,  Annastasiah Mudiwa Mhaka ,  Philip Goelet

    IPC分类号： C07C11/10 ,  C12M1/42 ,  C07C9/18 ,  C12P5/02

    CPC分类号： C12P5/007 ,  C12M21/02 ,  C12M23/04 ,  C12M23/06 ,  C12M29/22 ,  C12M43/06

    摘要： The present invention provides new energy solutions that are sustainable both environmentally and economically. The invention relates to photo-biocatalytic (PBC) methods and systems designed to produce and isolate carbonaceous chemicals using carbon dioxide, sunlight, and genetically engineered photosynthetic microorganisms. The PBC system comprises of procedural, mechanical and biological components designed for the production of carbonaceous chemicals. In an exemplary embodiment, the system includes a photo-biochemical reactor designed to maintain the genetically modified photosynthetic microorganisms in the optimal condition to capture carbon dioxide and convert it into metabolic intermediates using energy from sunlight, convert the metabolic intermediates into isoprene using recombinant enzymes, allow for the release of isoprene from cells, capture, separate and concentrate isoprene, and ultimately collect the isoprene at levels and in a form that would serve as a viable alternative to petroleum-dependent energy.

    摘要翻译： 本发明提供了在环境和经济上可持续的新能源解决方案。 本发明涉及光生物催化（PBC）方法和系统，其设计用于使用二氧化碳，阳光和基因工程的光合微生物来生产和分离碳质化学品。 PBC系统包括用于生产含碳化学物质的程序，机械和生物部件。 在一个示例性实施方案中，该系统包括光生化反应器，其设计用于将经过遗传修饰的光合微生物保持在最佳条件下以捕获二氧化碳并使用来自阳光的能量将其转化为代谢中间体，使用重组酶将代谢中间体转化为异戊二烯， 允许从细胞释放异戊二烯，捕获，分离和浓缩异戊二烯，并最终收集异戊二烯的水平和形式，作为石油依赖能量的可行替代品。

    Process for alkane isomerization using reactive chromatography
    2.
    发明授权
    Process for alkane isomerization using reactive chromatography 失效
    使用反应层析的烷烃异构化方法

    公开(公告)号：US5763730A

    公开(公告)日：1998-06-09

    申请号：US666717

    申请日：1996-06-18

    申请人： Hemant W. Dandekar ,  Gregory A. Funk ,  Ralph D. Gillespie ,  Herman A. Zinnen ,  Charles P. McGonegal ,  Masami Kojima ,  Simon H. Hobbs

    发明人： Hemant W. Dandekar ,  Gregory A. Funk ,  Ralph D. Gillespie ,  Herman A. Zinnen ,  Charles P. McGonegal ,  Masami Kojima ,  Simon H. Hobbs

    IPC分类号： C07C5/27 ,  C07C7/13 ,  C07C9/12 ,  C07C9/16 ,  C07C9/18 ,  C07C5/122

    CPC分类号： C07C5/2789 ,  C07C5/2791 ,  C07C7/13 ,  C07C9/12 ,  C07C9/16 ,  C07C9/18 ,  C07C2521/04 ,  C07C2521/06 ,  C07C2523/42 ,  C07C2523/54 ,  C07C2527/126 ,  C07C2529/22 ,  Y02P20/582

    摘要： A process for the continuous isomerization of an alkane to produce an isomerized product through contacting the alkane with a simulated moving bed acting as a catalyst for isomerization and an adsorbent for the alkanes has been developed. The alkane may be n-butane and the isomerized product 2-methylpropane, the alkane may be n-pentane and the isomerized product 2-methylbutane or 2,2-dimethylpropane, the alkane may have from 6 up to about 8 carbon atoms with no more than one methyl branch and the isomerized product having the same number of carbon atoms and at least two methyl branches, or the reactant may be a mixture of the foregoing alkanes with the corresponding isomerized products being formed. In a zone of the simulated moving bed, the alkanes are catalytically isomerized to form the isomerized products. The unreacted alkanes are adsorbed, and the isomerized products are collected. In a subsequent zone of the simulated moving bed, the unreacted alkanes are desorbed using a desorbent and may be catalytically isomerized to form additional isomerized products which are also separated and collected. The catalyst used in the simulated moving bed may be platinum on tungstated zirconia, and the adsorbent used in the simulated moving bed may be EU-1, ZSM-12, SAPO-5, Y-82, faujasite, erionite, zeolite beta exchanged with sodium, lithium, potassium, barium, calcium, strontium or combinations thereof, zeolite X exchanged with calcium and strontium, mordenite exchanged with sodium, lithium, potassium, barium, calcium, strontium, or combinations thereof.

    摘要翻译： 已经开发了通过使烷烃与用作异构化的催化剂的模拟移动床和用于烷烃的吸附剂使烷烃连续异构化以产生异构化产物的方法。 烷烃可以是正丁烷，异构化产物2-甲基丙烷，烷烃可以是正戊烷，异构化产物2-甲基丁烷或2,2-二甲基丙烷，烷烃可以具有6个至约8个碳原子，没有 多于一个甲基支链和具有相同数目的碳原子和至少两个甲基支链的异构化产物，或者反应物可以是前述烷烃与形成相应的异构化产物的混合物。 在模拟移动床的区域中，烷烃被催化异构化以形成异构化产物。 未反应的烷烃被吸附，收集异构化产物。 在模拟移动床的随后区域中，未反应的烷烃使用解吸剂解吸，并且可以被催化异构化以形成也被分离和收集的另外的异构化产物。 在模拟移动床中使用的催化剂可以是钨酸氧化锆上的铂，模拟移动床中使用的吸附剂可以是EU-1，ZSM-12，SAPO-5，Y-82，八面沸石，毛沸石，沸石β与 钠，锂，钾，钡，钙，锶或其组合，与钙和锶交换的沸石X，与钠，锂，钾，钡，钙，锶或它们的组合交换的丝光沸石。

    Process for converting butane and hexane into isopentane by averagingand isomerization
    3.
    发明授权
    Process for converting butane and hexane into isopentane by averagingand isomerization 失效
    通过平均异构转化棕榈酸和异黄酮进入异构体的方法

    公开(公告)号：US3752862A

    公开(公告)日：1973-08-14

    申请号：US3752862D

    申请日：1970-10-15

    申请人： CHEVRON RES

    发明人： SIEG R

    IPC分类号： C07C5/27 ,  C07C6/10 ,  C07C9/18 ,  C07C9/00

    CPC分类号： C07C9/18 ,  C07C5/2791 ,  C07C6/10 ,  C07C9/14

    摘要： A PROCESS FOR CONVERTING BUTANE AND HEXANE INTO ISOPENTANE WHICH COMPRISES: (A) AVERAGING A C6 RICH HYDROCARBON STREAM CONTAINING LESS THAN 1 P.P.M. SULFUR WITH BUTANE IN AN AVERAGING ZONE BY CONTACTING THE C6 AND BUTANE HYDROCARBONS WITH AN AVERAGING CATALYST HAVING A COMPONENT WHICH HAS CATALYTIC ACTIVITY FOR ALKANE DEHYDROGENATION AND A COMPONENT WHICH HAS CATALYTIC ACTIVITY FOR OLEFIN AVERAGING TO OBTAIN AN NC5 RICH AVERAGING EFFLUENT STREAM, AND (B) ISOMERIZING AT LEAST A PORTION OF THE NC5 IN THE AVERAGING EFFLUENT STREAM IN AN ISOMERIZATION ZONE BY CONTACTING THE NC5 WITH AN ISOMERIZATION CATALYST AT A HYDROGEN PARTIAL PRESSURE BETWEEN 10 P.S.I.G. AND 3,000 P.S.I.G. AND A TEMPERATURE BETWEEN 100*F. AND 900*F. TO OBTAIN AN IC5 RICH STREAM.

    O,S-dialkyl O-benzoyl-phenyl phosphorothiolates and phosphorodithioates, pesticidal compositions and methods of use
    7.
    发明授权
    O,S-dialkyl O-benzoyl-phenyl phosphorothiolates and phosphorodithioates, pesticidal compositions and methods of use 失效
    O，S-二烷基O-苯甲酰基 - 苯基硫代磷酸酯和二硫代磷酸酯，农药组合物和使用方法

    公开(公告)号：US4008319A

    公开(公告)日：1977-02-15

    申请号：US576837

    申请日：1975-05-12

    申请人： William S. Hurt

    发明人： William S. Hurt

    IPC分类号： A01N57/14 ,  C07F9/18 ,  A01N9/36 ,  C07C9/18

    CPC分类号： C07F9/18 ,  A01N57/14

    摘要： This invention relates to novel organophosphorothiolates and phosphorodithioates of the formula: ##STR1## wherein R is a (C.sub.1 -C.sub.4) alkyl group;R' is a (C.sub.3 -C.sub.6) alkyl group;Y is an oxygen atom or a sulfur atom;X is a halogen atom, a (C.sub.1 -C.sub.5) alkyl group, a (C.sub.1 -C.sub.5) alkoxy group, a trifluoromethyl group, a cyano group, or a group of the formula: ##STR2## wherein R" is a hydrogen atom or a (C.sub.1 -C.sub.3) alkyl group; X' is a halogen atom, a nitro group, a (C.sub.1 -C.sub.5) alkyl group, a (C.sub.1 -C.sub.5) alkoxy group, a trifluoromethyl group, a cyano group, or a group of the formula: ##STR3## wherein R" is a hydrogen atom or a (C.sub.1 -C.sub.3) alkyl group; and M AND M' ARE THE SAME OR DIFFERENT AND ARE INTEGERS FROM 0 TO 3;To compositions containing them and to methods of using them to control pests.

    摘要翻译： 本发明涉及下式的新型有机硫代硫酸酯和二硫代磷酸酯：其中R是（C 1 -C 4）烷基; R'是（C 3 -C 6）烷基; Y是氧原子或硫原子; X是卤素原子，（C1-C5）烷基，（C1-C5）烷氧基，三氟甲基，氰基或下式的基团：其中R“是氢原子 或（C1-C3）烷基; X'是卤素原子，硝基，（C1-C5）烷基，（C1-C5）烷氧基，三氟甲基，氰基或下式的基团：其中R' '是氢原子或（C1-C3）烷基; 和M和M'相同或不同，并且是从0到3的整数; 包含它们的组合物以及使用它们来控制PES的方法。

    A process for disproportionating paraffinic hydrocarbons to yield products containing iso-paraffinic hydrocarbons
    8.
    发明授权
    A process for disproportionating paraffinic hydrocarbons to yield products containing iso-paraffinic hydrocarbons 失效
    用于将含有碳氢化合物的含油产物分散在一起的方法

    公开(公告)号：US3668269A

    公开(公告)日：1972-06-06

    申请号：US3668269D

    申请日：1970-06-26

    申请人： ATLANTIC RICHFIELD CO

    发明人： CHLOUPEK FRANK J

    IPC分类号： B01J29/068 ,  C07C9/18 ,  C07C9/00

    CPC分类号： B01J29/068 ,  C07C9/18

    摘要： A process for disproportionating paraffinic hydrocarbons containing three to seven, four to five, carbon atoms in a hydrogen atmosphere to yield products containing iso-paraffinic hydrocarbons containing one more and hydrocarbons containing one less carbon fragment per molecule is disclosed. In the process, the paraffinic hydrocarbon is contacted in a hydrogen atmosphere at about 700* to 900* F. with a solid, acidic catalyst comprising a minor, catalytically effective amount of a platinum-group metal and containing a hydrogen or metal exchanged crystalline aluminosilicate having pores in the 8 to 15 A range and a mole ratio of silica-to-alumina of greater than about 2 to 1 and a solid oxide support. The catalyst can contain from about 1 up to about 85 weight percent of the crystalline aluminosilicate. A preferred oxide support is silica-alumina which can further contain a minor amount of alumina such as an activated alumina of the gamma family.

    摘要翻译： 公开了一种用于在氢气氛中歧化含有三至七个，四个至五个碳原子的链烷烃的方法，以产生含有一个以上含有异链烷烃的产物和每分子含有少一个碳片段的烃。 在该过程中，链烷烃在约700-900°F的氢气氛中与含有少量催化有效量的铂族金属并含有氢或金属交换的结晶硅铝酸盐的固体酸性催化剂接触 具有8至15A范围的孔隙和大于约2:1的二氧化硅与氧化铝的摩尔比和固体氧化物载体。 催化剂可以含有约1至约85重量％的结晶硅铝酸盐。 优选的氧化物载体是二氧化硅 - 氧化铝，其可以进一步含有少量的氧化铝，例如γ族的活性氧化铝。