发明授权
- 专利标题: Supported catalysts with controlled metal cluster size
- 专利标题(中): 具有受控金属簇尺寸的负载型催化剂
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申请号: US11466900申请日: 2006-08-24
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公开(公告)号: US07582586B2公开(公告)日: 2009-09-01
- 发明人: Paul T. Fanson , Hirohito Hirata , Michael D. Amiridis , Christopher T. Williams , David S. Deutsch , Attilio Siani , Shinichi Matsumoto
- 申请人: Paul T. Fanson , Hirohito Hirata , Michael D. Amiridis , Christopher T. Williams , David S. Deutsch , Attilio Siani , Shinichi Matsumoto
- 申请人地址: JP Toyota US KY Erlanger
- 专利权人: Toyota Motor Corporation,Toyotal Motor Engineering & Manufacturing North America, Inc.
- 当前专利权人: Toyota Motor Corporation,Toyotal Motor Engineering & Manufacturing North America, Inc.
- 当前专利权人地址: JP Toyota US KY Erlanger
- 代理机构: Gifford, Krass, Sprinkle, Anderson & Citkowski, P.C.
- 主分类号: B01J31/00
- IPC分类号: B01J31/00 ; B01J37/00 ; B01J21/00 ; B01J23/42 ; B01J23/44 ; C08F4/60 ; C08F4/02 ; B01J23/40 ; B01J23/10 ; B01J23/00
摘要:
There is disclosed a process for producing a catalyst. The process includes the steps of: a) combining a dendrimer polymer and metal salt in solution forming a metal ion complex; b) exposing the metal ion complex to a reducing environment forming a dendrimer metal nanocomposite; c) depositing the dendrimer metal nanocomposite onto a catalyst support material; d) removing a solvent from the dendrimer metal nanocomposite forming metal clusters; and e) removing the dendrimer polymer forming a catalyst. Additionally, there is disclosed a catalyst having a catalytic metal deposited on a substrate. The catalytic metal is formed in clusters having a size of from 2 to 150 atoms. In another aspect, the clusters may have a spacing of from 2 to 100 nanometers between adjacent metal clusters. Further, in another aspect, the metal clusters which comprise the catalyst have a size distribution in which 70% of the clusters are within 0.6 nm of the average diameter and 99% of the particles are within 1.5 nm of the average diameter.
公开/授权文献
- US20080051282A1 SUPPORTED CATALYSTS WITH CONTROLLED METAL CLUSTER SIZE 公开/授权日:2008-02-28
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