Invention Grant
- Patent Title: Polyurethane adhesives containing alkyl-substituted 4,4′-di(aminocyclohexyl)alkanes, 2,4′-di(aminocyclohexyl)alkanes and/or 2,2′-di(aminocyclohexyl)amines
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Application No.: US14410307Application Date: 2013-06-26
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Publication No.: US09708516B2Publication Date: 2017-07-18
- Inventor: Bradley D. Suerer , Syed Z. Mahdi , Gary L. Jialanella , Gary A. Hunter
- Applicant: DOW GLOBAL TECHNOLOGIES LLC
- Applicant Address: US MI Midland
- Assignee: Dow Global Technologies LLC
- Current Assignee: Dow Global Technologies LLC
- Current Assignee Address: US MI Midland
- Agency: Gary C Cohn PLLC
- International Application: PCT/US2013/047962 WO 20130626
- International Announcement: WO2014/004710 WO 20140103
- Main IPC: C09J175/06
- IPC: C09J175/06 ; C09J175/04 ; C08G18/10 ; C08G18/12 ; C08G18/32 ; C08G18/48 ; C08G18/66 ; C08G18/36 ; C08K3/26 ; C08K3/36

Abstract:
Two component polyurethane adhesives contain (a) at least one alkyl-substituted 4,4′-di(aminocyclohexyl)alkane wherein each cyclohexyl group is alkyl-substituted in at least one position ortho to the amino group, (b) at least one 2,4′-di(aminocyclohexyl)alkane or 2,2′-di(aminocyclohexyl)alkane, (c) a mixture of (ii) at least one alkyl-substituted 4,4′-di(aminocyclohexyl)alkane wherein each cyclohexyl group is alkyl-substituted and (ii) at least one 2,4′-di(aminocyclohexyl)alkane and/or 2,2′-di(aminocyclohexyl)alkane, or (d) a mixture of 40 to 99.9% by weight (a), (b) or (c) with 0.1 to 60% by weight of at least one unsubstituted 4,4′-di(aminocyclohexyl)alkane, The adhesives also contain one or more polyols, in which at least 50% of the hydroxyl groups are secondary hydroxyls. These adhesive provide a useful combination of long open time and excellent sag resistance.
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