ROHRBÜNDELREAKTOR FÜR UNKATALYSIERTE ODER HOMOGENKATALYSIERTE REAKTIONEN
    5.
    发明公开
    ROHRBÜNDELREAKTOR FÜR UNKATALYSIERTE ODER HOMOGENKATALYSIERTE REAKTIONEN 有权
    管式反应器非催化或均匀催化反应

    公开(公告)号:EP2389241A2

    公开(公告)日:2011-11-30

    申请号:EP10701318.7

    申请日:2010-01-19

    申请人: BASF SE

    IPC分类号: B01J19/24

    摘要: The invention relates to a tube bundle reactor having a flat feed dome. Alternatively, the discharge dome can also be designed flat. The flat design reduces the reaction heat developing in the hood in reaction types that take place not only in the tube bundle (non-catalyzed reactions and reactions with homogenously distributed catalyst). Undesired reactions that already take place in the dome due to accumulated heat are thus heavily suppressed, whereby greater selectivity in temperature-sensitive reactions is achieved. Additionally, the temperature distribution within the domes can be precisely controlled. The tube bundle reactor comprises a tube bundle that has a feed end connected to a feed dome of the tube bundle reactor, wherein the feed dome is designed in a flat shape having a cross-sectional surface at the feed end and an inner volume, and the ratio of the inner volume to the cross-sectional surface is less than 0.35 m. The invention is furthermore implemented by a method for operating a tube bundle reactor, comprising: introducing a reactant mixture into a tube bundle and converting at least a portion of the reactant mixture into a product inside the tube bundle. The introduction step comprises: feeding the reactant mixture into an inner space of a feed dome of the tube bundle reactor and forwarding the reactant mixture into a feed end of the tube bundle in the form of a fluid flow. The fluid flow has a cross-sectional surface upon entering the feed end and the inner space of the feed dome through which the fluid flows has an inner volume; wherein the ratio of the inner volume to the cross-sectional surface is less than 0.35 m.

    VERFAHREN ZUR REINIGUNG VON N2O
    6.
    发明公开
    VERFAHREN ZUR REINIGUNG VON N2O 有权
    清理方法氧化亚氮

    公开(公告)号:EP2271584A1

    公开(公告)日:2011-01-12

    申请号:EP09727777.6

    申请日:2009-03-13

    申请人: BASF SE

    IPC分类号: C01B21/22 B01D53/14

    摘要: The present invention relates to a process for purifying a gas mixture containing dinitrogen monoxide at least comprising treatment of a gas mixture G-O containing dinitrogen monoxide with a gas mixture G-A being obtained, at least comprising the absorption of the gas mixture G-O in a solvent mixture LM-I with an off-gas stream and a composition Z-A being obtained, and desorption of a gas mixture G-1 from the composition Z-A with a solvent mixture LM-I' being obtained, subsequent condensation of the gas mixture G-A with a liquid composition Z-1 containing dinitrogen monoxide and a gaseous mixture G-K being obtained, wherein the gaseous mixture G-K is recirculated to the process.