VERFAHREN ZUR REINIGUNG VON CYCLISCHEN KETONEN
    4.
    发明公开
    VERFAHREN ZUR REINIGUNG VON CYCLISCHEN KETONEN 有权
    通过热处理环十二酮纯化

    公开(公告)号:EP2041061A1

    公开(公告)日:2009-04-01

    申请号:EP07765650.2

    申请日:2007-06-27

    Applicant: BASF SE

    Abstract: The invention relates to a method for purifying a composition (I) containing at least one cyclic ketone having 7 to 16 C atoms. The method encompasses the thermal treatment of the composition (I) with a catalyst containing at least one transition metal and the further purification by a method selected from the group consisting of destillation, extraction and crystallization. The invention also relates to a method for producing cyclododecanone, which includes a purification of this type, and to the use of at least one catalyst containing at least one transition metal for purifying a composition (I) containing at least one cyclic ketone having 7 to 16 C atoms by thermal treatment of the composition (I) with a catalyst that contains at least one transition metal.

    VERFAHREN ZUR HERSTELLUNG VON ISOCYANATEN

    公开(公告)号:EP1401802B1

    公开(公告)日:2008-04-30

    申请号:EP02745367.9

    申请日:2002-06-06

    Applicant: BASF SE

    CPC classification number: C07C263/10 C07C265/14

    Abstract: The invention relates to a method for producing isocyanates by reacting primary amines with phosgene, and using isocyanate as the solvent. The inventive method is characterized in that a portion or the entire quantity of the isocyanate used as the solvent is only added to the reaction batch once the amine and the phosgene have been combined.

    Abstract translation: 本发明涉及通过使伯胺与光气反应并使用异氰酸酯作为溶剂来生产异氰酸酯的方法。 本发明的方法的特征在于,一旦胺和光气结合后,仅将用作溶剂的部分或全部量的异氰酸酯加入反应批料中。

    VERFAHREN ZUR HERSTELLUNG VON CYCLISCHEN KETONEN

    公开(公告)号:EP2041059B1

    公开(公告)日:2010-06-16

    申请号:EP07765652.8

    申请日:2007-06-27

    Applicant: BASF SE

    Abstract: The invention relates to a method for producing a cyclic ketone that has 7 to 16 C atoms. Said method encompasses at least the following stages: (a) a composition (i) at least containing a cyclic alkene with 7 to 16 C atoms, including at least one C-C double bond, is oxidized by means of dinitrogen monoxide so as to obtain a composition (A); (b) composition (A) is treated with at least one base so as to obtain a composition (B); (c) composition (B) is hydrogenated in the presence of at least one catalyst so as to obtain a composition (C); (d) composition (C) is purified in at least the following steps: (di) composition (C) is thermally treated with at least one acid or at least one catalyst containing at least one transition metal; (dii) composition (C) is further purified by means of a process selected from the group comprising distillation, extraction, and crystallization.

    Abstract translation: 本发明涉及一种制备具有7至16个碳原子的环酮的方法,其至少包括步骤(a)包含至少一种具有7至16个碳原子的环烯烃的组合物(I)的氧化 和至少一种C-C双键,得到组合物(A),(b)用至少一种碱处理组合物(A),得到组合物(B),(c)氢化 在组合物(B)的存在下,在至少一种催化剂的存在下,得到组合物(C),(d)组合物(C)的纯化,至少包括步骤(ii)组合物(C)的热处理, 至少一种酸或至少一种包含至少一种过渡金属的催化剂,(dii)通过选自蒸馏,萃取和结晶的方法进一步纯化。

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