VERFAHREN ZUR HERSTELLUNG VON REINEM CYCLODODECANON

    公开(公告)号:EP2391597A1

    公开(公告)日:2011-12-07

    申请号:EP10701244.5

    申请日:2010-01-27

    Applicant: BASF SE

    Abstract: The invention relates to a method for producing at least one cyclic compound comprising Z cycles and between 7 and 16 C atoms with one carbonyl group, said method comprising at least the following steps: (a1) oxidation of a composition (A), at least containing one cyclic olefin with Z cycles and between 7 and 16 C atoms and at least two C-C double bonds, using dinitrogen monoxide, to obtain a composition (A1); (a2) isolation of the at least one cyclic olefin comprising Z cycles and between 7 and 16 C atoms with at least two C-C double bonds from the composition (A1) to obtain a composition (A2); and (b) distillatory treatment of the composition (A2) from step (a2) to obtain a composition (B) containing the at least one cyclic compound with Z cycles and between 7 and 16 C atoms with one carbonyl group and less than 1.0 wt. % of the at least one compound comprising Z-1 cycles and between 7 and 16 C atoms with at least one aldehyde group. According to the invention, Z can be 1, 2, 3 or 4.

    Abstract translation: 本发明涉及一种制备至少一种具有Z循环和7至16个碳原子的具有酮基的环状化合物的方法,至少包括以下步骤:(a1)组合物(A)的氧化,至少包含一个环状 烯烃,Z循环和7至16个碳原子和至少两个C-C双键,借助于一氧化二氮,得到组合物(A1),(a2)以Z循环分离出至少一种环状烯烃,并将7分离成 16个碳原子与来自组合物(A1)的至少两个C-C双键,以获得组合物(A2),和(b)从步骤(a2)中对组合物(A2)进行蒸馏处理,以获得 组合物(B),其包含至少一种Z循环的环状化合物和具有酮基的7至16个碳原子和小于1.0重量%的至少一种具有Z-1个循环和7至16个碳原子的化合物, 至少一个醛基,其中Z可以是1,2,3或4个。

    ROHRBÜNDELREAKTOR FÜR UNKATALYSIERTE ODER HOMOGENKATALYSIERTE REAKTIONEN
    9.
    发明公开
    ROHRBÜNDELREAKTOR FÜR UNKATALYSIERTE ODER HOMOGENKATALYSIERTE REAKTIONEN 有权
    管式反应器非催化或均匀催化反应

    公开(公告)号:EP2389241A2

    公开(公告)日:2011-11-30

    申请号:EP10701318.7

    申请日:2010-01-19

    Applicant: BASF SE

    Abstract: The invention relates to a tube bundle reactor having a flat feed dome. Alternatively, the discharge dome can also be designed flat. The flat design reduces the reaction heat developing in the hood in reaction types that take place not only in the tube bundle (non-catalyzed reactions and reactions with homogenously distributed catalyst). Undesired reactions that already take place in the dome due to accumulated heat are thus heavily suppressed, whereby greater selectivity in temperature-sensitive reactions is achieved. Additionally, the temperature distribution within the domes can be precisely controlled. The tube bundle reactor comprises a tube bundle that has a feed end connected to a feed dome of the tube bundle reactor, wherein the feed dome is designed in a flat shape having a cross-sectional surface at the feed end and an inner volume, and the ratio of the inner volume to the cross-sectional surface is less than 0.35 m. The invention is furthermore implemented by a method for operating a tube bundle reactor, comprising: introducing a reactant mixture into a tube bundle and converting at least a portion of the reactant mixture into a product inside the tube bundle. The introduction step comprises: feeding the reactant mixture into an inner space of a feed dome of the tube bundle reactor and forwarding the reactant mixture into a feed end of the tube bundle in the form of a fluid flow. The fluid flow has a cross-sectional surface upon entering the feed end and the inner space of the feed dome through which the fluid flows has an inner volume; wherein the ratio of the inner volume to the cross-sectional surface is less than 0.35 m.

    VERFAHREN ZUR GEWINNUNG VON CYCLODODECATRIEN DURCH VERDAMPFUNG
    10.
    发明公开
    VERFAHREN ZUR GEWINNUNG VON CYCLODODECATRIEN DURCH VERDAMPFUNG 有权
    一种获得三烯由于膨胀

    公开(公告)号:EP1907342A1

    公开(公告)日:2008-04-09

    申请号:EP06763996.3

    申请日:2006-06-30

    Applicant: BASF SE

    CPC classification number: C07C7/04 C07C13/277

    Abstract: The invention relates to a method for obtaining cyclododecatriene (CDT) from a solution containing CDT and high-boiling components such as a deactivated catalyst and polymers. Said solution is supplied to a preheater and heated, and is then relaxed over a downstream pressure maintaining device, and the two-phase mixture obtained is supplied to a spiral tube evaporator where the CDT content of the liquid phase is reduced by partial evaporation and a gaseous product flow with an increased CDT concentration is derived.

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