摘要:
The invention relates to a catalyst complex comprising boron trifluoride and a co-catalyst mixture of 10 to 90 wt% of a monovalent primary C 1 to C 20 alcohol and 90 to 10 wt% of a monovalent secondary C 3 to C 20 alcohol, wherein the molar ratio of boron trifluoride to the sum of all alcohols is 2:1 to 1:10. Said catalyst complex is used in the production of highly reactive isobutene homopolymers having a number-average molecular weight of 300 to 50,000, wherein a C 4 hydrocarbon mixture containing at least 20 wt% of isobutene and in total at least 10 wt% of other C 4 olefins is used as a feed material.
摘要:
Polyisobutylene having a total percentage of vinylidene double bonds of more than 50 mol.% and a number average molecular weight of 500 to 10,000 daltons, wherein at least 10% of all the vinylidene double bonds in the polyisobutylene are in one or more side chains composed of at least 2 carbon atoms on the polyisobutylene main chain. Polyisobutylene of this type is suitable for producing fuel additives and lubricant additives.
摘要:
The invention relates to the production of isobutylene homopolymers having a weight-average molecular weight of 75,000 to 10,000,000 by means of the polymerization of isobutylene by (a) performing the polymerization at -80°C to -190°C, (b) using optionally halogenated C 1 to C 5 hydrocarbons as an inert solvent, (c) using a Lewis acid complex as a polymerization catalyst, and (d) performing the polymerization in the presence of at least one reaction accelerator in the form of an ethylenically saturated hydrocarbon compound, which contains an oxygen atom and no proton that can be emitted, and performing the polymerization in the presence of at least one chain length regulator, which contains a tertiary olefinic carbon atom.
摘要:
Continuous production of polyisobutylene having a content of terminal double bonds of greater than 50% by polymerization of isobutene in the presence of a polymerization catalyst usual therefor, by combining a technical 1-butene-, 2-butene- and isobutene-containing C4 hydrocarbon stream together with a stream of pure isobutene, and feeding the combined stream into the reaction zone in such a manner that the steady state concentration of isobutene in the combined stream at the point where the combined stream is fed into the reaction zone has a value of on average at least 40% by weight, and the invention also relates to a polymerization system therefor.