BORTRIFLUORID-KATALYSATORKOMPLEX UND VERFAHREN ZUR HERSTELLUNG VON HOCHREAKTIVEN ISOBUTENHO-MOPOLYMEREN
    5.
    发明公开
    BORTRIFLUORID-KATALYSATORKOMPLEX UND VERFAHREN ZUR HERSTELLUNG VON HOCHREAKTIVEN ISOBUTENHO-MOPOLYMEREN 审中-公开
    BORTRIFLUORID-KATALYSATOROMPLEX UND VERFAHREN ZUR HERSTELLUNG VON HOCHREAKTIVEN ISOBUTENHO-MOPOLYMEREN

    公开(公告)号:EP2814852A1

    公开(公告)日:2014-12-24

    申请号:EP13705952.3

    申请日:2013-02-13

    CPC classification number: C08F10/10 C08F4/14 C08F110/10 C08F2500/02

    Abstract: The invention relates to a catalyst complex comprising boron trifluoride and a co-catalyst mixture of 10 to 90 wt% of a monovalent primary C
    1 to C
    20 alcohol and 90 to 10 wt% of a monovalent secondary C
    3 to C
    20 alcohol, wherein the molar ratio of boron trifluoride to the sum of all alcohols is 2:1 to 1:10. Said catalyst complex is used in the production of highly reactive isobutene homopolymers having a number-average molecular weight of 300 to 50,000, wherein a C
    4 hydrocarbon mixture containing at least 20 wt% of isobutene and in total at least 10 wt% of other C
    4 olefins is used as a feed material.

    Abstract translation: 本发明涉及一种催化剂配合物,其包含三氟化硼和10至90重量%的一价一价C 1至C 20醇和90至10重量%的一价仲C3至C20醇的助催化剂混合物,其中摩尔比 三氟化硼与所有醇的总和为2:1至1:10。 所述催化剂络合物用于生产数均分子量为300至50,000的高活性异丁烯均聚物,其中含有至少20重量%异丁烯和总共至少10重量%的其它C 4烯烃的C 4烃混合物 用作饲料。

    HERSTELLUNG VON POLYMEREN DURCH KONTROLLIERTE RADIKALISCHE POLYMERISATION
    6.
    发明公开
    HERSTELLUNG VON POLYMEREN DURCH KONTROLLIERTE RADIKALISCHE POLYMERISATION 审中-公开
    聚合物通过受控的自由基聚合生产

    公开(公告)号:EP2751143A1

    公开(公告)日:2014-07-09

    申请号:EP12753968.2

    申请日:2012-08-30

    Applicant: BASF SE

    Abstract: Method for producing polymers by means of controlled radical polymerisation, wherein the polymerisation of one or several radically polymerisable monomers of general formula (I), where R
    1 , R
    2 , R
    3 are H, C
    1 -C
    4 alkyl, R
    4 is C(=O)OR
    5 , C(=O)NHR
    15 , C(=O)NR
    5 R
    6 , OC(=O)CH
    3 , C(=O)OH, CN, aryl, hetaryl, C(=O)OR
    5 OH, C(=O)OR
    5 Si(OR
    5 )
    3 , halogen, NHC(O)H, P(=O)(OR
    7 )
    2 , R
    5 is C
    1 -C
    20 alkyl, R
    15 is C
    1 -C
    20 -alkyl, R
    6 is C
    1 -C
    20 alkyl, and R
    7 is H, C
    1 -C
    20 alkyl, occurs in the presence of a. one or several catalysts containing Cu in the form of Cu(0), Cu(l), Cu (II) or mixtures thereof, b. one or several initiators selected from the group of organic halogenides or pseudohalogenides, c. one or several ligands, d. optionally one or several solvents, and e. optionally one or several inorganic halogenide salts, said method consisting of the following steps i) addition of the catalyst a., ii) optional addition of monomers of general formula (I), iii) optional addition of solvent d., iv) addition of ligand c., v) addition of initiator b., vi) addition of monomers of general formula (I), and vii) optional addition of inorganic halogenide salts e., on the proviso that the addition of at least some of the monomers of general formula (I) occurs immediately before or shortly after the last of the steps i), iv) and v).

    VERFAHREN ZUR HERSTELLUNG VON LEDER
    8.
    发明公开

    公开(公告)号:EP2257650A1

    公开(公告)日:2010-12-08

    申请号:EP09722872.0

    申请日:2009-03-16

    Applicant: BASF SE

    CPC classification number: C14C3/20 C14C3/10 C14C3/28

    Abstract: The present invention relates to a method for manufacturing leather, characterized in that the pre-tanning, main-tanning or post-tanning is carried out in the presence of (a) at least one compound of the general formula (I) (b) and oxalic acid or the corresponding ammonium or alkali metal salts thereof, respectively, where R
    1 is selected from methyl, ethyl, phenyl, benzyl, hydroxymethyl, isopropyl, isobutyl and sec.-butyl.

    Abstract translation: 本发明涉及一种制造皮革的方法,其特征在于预鞣,主晒黑或后鞣在(a)至少一种通式(I)(b)化合物存在下进行, 和草酸或其相应的铵或碱金属盐,其中R 1选自甲基,乙基,苯基,苄基,羟甲基,异丙基,异丁基和仲丁基。

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