公开(公告)号：EP1910430A1

公开(公告)日：2008-04-16

申请号：EP06762534.3

申请日：2006-07-11

申请人： BASF SE

发明人： BODE, Andreas ,  RACHWALSKY, Uwe ,  SAUER, Friedrich ,  SCHAUSS, Eckard ,  VOLLAND, Marco-Christian ,  WETTLING, Thomas

IPC分类号： C08F10/10 ,  C08F4/14

CPC分类号： B01F3/1221 ,  B01F7/00758 ,  B01J19/1806 ,  C08F110/10 ,  C08F2/01 ,  C08F4/14 ,  C08F2500/03

摘要： The invention relates to a method for producing polyisobutenes, in which isobutene is polymerized in liquid organic phase in the presence of a Lewis acid catalyst, the organic phase is mixed with an aqueous terminating agent in a dynamic mixer in order to terminate the reaction, said dynamic mixer comprising an axially symmetrical mixing chamber formed by a peripheral wall and two end walls as well as a mixing rotor that is rotatably driven therein. The organic phase is introduced via a first inlet located in the peripheral wall while the aqueous terminating agent is introduced via a second inlet located in the peripheral wall, and a finely dispersed mixture of the organic phase and the terminating agent is withdrawn via an outlet located in the peripheral wall and is delivered to a phase separation process. The inventive method is used for producing highly reactive polyisobutenes and/or polyisobutenes having a narrow molecular weight distribution.

公开(公告)号：EP1937729A1

公开(公告)日：2008-07-02

申请号：EP06807125.7

申请日：2006-10-10

申请人： BASF SE

发明人： SEIDL, Volker ,  DÜCKER, Carolin Nadine ,  WIEDEMANN, Alexandra ,  WETTLING, Thomas ,  RACHWALSKY, Uwe ,  VOLLAND, Marco-Christian ,  KARCHES, Martin ,  STÜTZER, Dieter ,  WEBER, Franz ,  BOCHNITSCHEK, Werner

IPC分类号： C08F10/10 ,  C08F2/34

CPC分类号： C08F110/10 ,  C08F2/14 ,  C08F2500/01 ,  C08F2500/04

摘要： The invention relates to a method for producing polyisobutene by polymerization of isobutene using an inert diluent and a halogenated Lewis acid as the catalyst. Said method is characterized by contacting a liquid mixture of the isobutene and the inert diluent with the catalyst in the gas chamber of a polymerization device.

摘要翻译： 本发明涉及一种通过使用惰性稀释剂和卤化路易斯酸作为催化剂聚合异丁烯生产聚异丁烯的方法。 所述方法的特征在于使异丁烯和惰性稀释剂的液体混合物与催化剂在聚合装置的气室中接触。

公开(公告)号：EP1910430B1

公开(公告)日：2009-09-30

申请号：EP06762534.3

申请日：2006-07-11

申请人： BASF SE

发明人： BODE, Andreas ,  RACHWALSKY, Uwe ,  SAUER, Friedrich ,  SCHAUSS, Eckard ,  VOLLAND, Marco-Christian ,  WETTLING, Thomas

IPC分类号： C08F10/10 ,  C08F4/14

CPC分类号： B01F3/1221 ,  B01F7/00758 ,  B01J19/1806 ,  C08F110/10 ,  C08F2/01 ,  C08F4/14 ,  C08F2500/03

摘要： The invention relates to a method for producing polyisobutenes, in which isobutene is polymerized in liquid organic phase in the presence of a Lewis acid catalyst, the organic phase is mixed with an aqueous terminating agent in a dynamic mixer in order to terminate the reaction, said dynamic mixer comprising an axially symmetrical mixing chamber formed by a peripheral wall and two end walls as well as a mixing rotor that is rotatably driven therein. The organic phase is introduced via a first inlet located in the peripheral wall while the aqueous terminating agent is introduced via a second inlet located in the peripheral wall, and a finely dispersed mixture of the organic phase and the terminating agent is withdrawn via an outlet located in the peripheral wall and is delivered to a phase separation process. The inventive method is used for producing highly reactive polyisobutenes and/or polyisobutenes having a narrow molecular weight distribution.

公开(公告)号：EP2814851A1

公开(公告)日：2014-12-24

申请号：EP13704127.3

申请日：2013-02-15

申请人： BASF SE

发明人： WETTLING, Thomas ,  HIRSCH, Stefan ,  BRYM, Markus ,  WEIS, Markus ,  CORBERAN ROC, Rosa ,  MÜHLBACH, Klaus ,  HASCHICK, Robert ,  DAISS, Andreas ,  VOLLAND, Marco-Christian

IPC分类号： C08F10/10

CPC分类号： C08F10/10 ,  C08F4/14 ,  C08F2/01 ,  C08F110/10 ,  C08F2500/01 ,  C08F2500/04

摘要： The invention relates to the production of isobutylene homopolymers having a weight-average molecular weight of 75,000 to 10,000,000 by means of the polymerization of isobutylene by (a) performing the polymerization at -80°C to -190°C, (b) using optionally halogenated C
1 to C
5 hydrocarbons as an inert solvent, (c) using a Lewis acid complex as a polymerization catalyst, and (d) performing the polymerization in the presence of at least one reaction accelerator in the form of an ethylenically saturated hydrocarbon compound, which contains an oxygen atom and no proton that can be emitted, and performing the polymerization in the presence of at least one chain length regulator, which contains a tertiary olefinic carbon atom.

摘要翻译： 本发明涉及通过（a）在-80℃至-190℃下进行聚合反应，（b）任选地使用异丁烯的聚合反应制备重均分子量为75,000至10,000,000的异丁烯均聚物 卤代C1至C5烃作为惰性溶剂，（c）使用路易斯酸配合物作为聚合催化剂，和（d）在至少一种烯属饱和烃化合物形式的反应促进剂存在下进行聚合， 含有氧原子并且不能发射的质子，并且在至少一个包含叔烯烃碳原子的链长调节剂的存在下进行聚合。