公开(公告)号：EP2788338A1

公开(公告)日：2014-10-15

申请号：EP12795304.0

申请日：2012-11-27

申请人： Dow Global Technologies LLC

发明人： GU, Leming ,  FAN, William, W. ,  HOOK, Bruce, D. ,  JEAN, David ,  JEWELL, Dennis, W.

IPC分类号： C07D301/32 ,  C07D303/02

CPC分类号： C07D301/32 ,  C07D303/02

摘要： A process for recovering a divinylarene dioxide from a crude feed stream comprising the steps of: (a) providing an effluent reaction stream containing at least one divinylarene dioxide product and other compounds; and (b) separating/recovering the divinylarene dioxide product from the other compounds of the reaction effluent from step (a); wherein the percent recovery of the divinylarene dioxide product recovered comprises greater than about 85 percent; and wherein the percent purity of the divinylarene dioxide product recovered comprises greater than about 85 percent.

公开(公告)号：EP2516409A1

公开(公告)日：2012-10-31

申请号：EP10798907.1

申请日：2010-12-17

申请人： Dow Global Technologies LLC

发明人： RIPPLINGER, Eric, B. ,  JEAN, David ,  BUROW, David, L. ,  PHAM, Khiet, T. ,  GULYAS, Gyongyi ,  HOOK, Bruce, D.

IPC分类号： C07D301/19 ,  C07D301/12

CPC分类号： C08G59/22 ,  C07D301/12 ,  C07D301/19 ,  C08G59/027

摘要： A process for preparing a divinylarene dioxide including reacting (a) at least one divinylarene; (b) at least one peroxycarboximidic acid; (c) at least one solvent; and (d) at least one basic compound, under conditions to form a reaction mixture containing a divinylarene dioxide product; and then separating the divinylarene dioxide product from the other reaction mixture components to obtain a purified divinylarene dioxide product.

摘要翻译： 一种制备二乙烯基芳烃二氧化物的方法，包括使（a）至少一种二乙烯基芳烃反应; （b）至少一种过氧羧酰亚胺酸; （c）至少一种溶剂; 和（d）至少一种碱性化合物，在形成含有二乙烯基芳烃二氧化物产物的反应混合物的条件下进行; 然后将二乙烯基芳烃二氧化物产物与其他反应混合物组分分离以获得纯化的二乙烯基芳烃二氧化物产物。

公开(公告)号：EP2459516B1

公开(公告)日：2017-08-23

申请号：EP10739811.7

申请日：2010-07-30

申请人： Dow Global Technologies LLC

发明人： SANTHANY, Stacie ,  AU-YEUNG, Patrick ,  DARE, Gerald ,  FEIST, Shawn ,  FISH, Barry ,  HICKMAN, Daniel ,  JEAN, David ,  MOLITOR, Erich ,  SCHUITMAN, Abraham ,  TOYZAN, Todd

IPC分类号： C07C209/84

CPC分类号： C07C209/86 ,  C07C2601/14 ,  C07C211/28

公开(公告)号：EP2459516A2

公开(公告)日：2012-06-06

申请号：EP10739811.7

申请日：2010-07-30

申请人： Dow Global Technologies LLC

发明人： SANTHANY, Stacie ,  AU-YEUNG, Patrick ,  DARE, Gerald ,  FEIST, Shawn ,  FISH, Barry ,  HICKMAN, Daniel ,  JEAN, David ,  MOLITOR, Erich ,  SCHUITMAN, Abraham ,  TOYZAN, Todd

IPC分类号： C07C209/84

CPC分类号： C07C209/86 ,  C07C2601/14 ,  C07C211/28

摘要： The instant invention provides a process for separating one or more aliphatic diamines from reductive amination reaction solvents and impurities, and aliphatic diamines obtained via such a process. The process for separating one or more aliphatic diamines from reductive amination reaction solvents and impurities according to the instant invention comprises the steps of: (1) feeding one or more cycloaliphatic cyanoaldehydes, hydrogen, ammonia, and optionally one or more solvents into a continuous reductive amination reactor system; (2) contacting said one or more cycloaliphatic cyanoaldehydes, hydrogen, and ammonia with each other in the presence of one or more heterogeneous metal based catalyst systems at a temperature in the range of from 80° C to about 160° C and a pressure in the range of from 700 to 3500 psig; (3) thereby forming a product mixture comprising one or more cycloaliphatic diamines, optionally one or more bicyclic by-products, optionally one or more cycloaliphatic aminonitriles, optionally one or more cycloaliphatic aminoalcohols, optionally one or more oligomeric by-products, ammonia, water, hydrogen, and optionally one or more solvents; (4) removing said product mixture from the reactor system; (5) removing at least a portion of said ammonia, said hydrogen, or mixture thereof from said product mixture via distillation; (6) removing at least a portion of said water and said one or more optional solvents via distillation; (7) removing at least a portion of one or more optional bicyclic by-products via distillation; (8) removing one or more optional cycloaliphatic aminonitriles, one or more optional cycloaliphatic aminoalcohols, one or more optional oligomeric by-products via distillation; and (9) thereby separating said one or more cycloaliphatic diamines from said product mixture.

摘要翻译： 本发明提供用于分离一种或还原阿米娜灰反应溶剂和杂质，并且经由检索处理得到的脂肪族二胺更多脂族二胺的方法。 用于分离一种或还原阿米娜灰反应溶剂和杂质雅丁给本发明以上的脂肪族二胺的方法，包括以下步骤：（1）将一种或多种脂环族氰基，氢，氨和任选的一种或多种溶剂为连续还原 阿米娜和灰的反应器系统; （2）使所述一种或多种脂环族氰基，氢，和氨海誓山盟在一种或多种非均相基于金属的催化剂体系的在温度从80℃至约160℃，范围内的存在 压力在700至3500 psig的的范围内; （3）由此形成的产物混合物，其包括副产物的一种或多种脂环族二胺，任选的一种或多种双环副产物，任选的一种或多种脂环族的氨基腈，任选的一种或多种脂环族氨基醇，任选的一种或多种低聚，氨，水 ，氢，和任选的一种或多种溶剂; （4）从该反应器系统，其中所述产品混合物; （5）去除至少所述氨，所述氢，或它们的混合物从蒸馏经由所述产品混合物的一部分; （6）除去至少一部分水和所述一个或经由蒸馏多种任选的溶剂; （7）除去至少一个副产物通过蒸馏一种或多种任选的双环部分; （8）去除一个或多个任选的脂环族氨基腈，一种或多种任选的环脂族氨基醇，副产物通过蒸馏一种或多种任选的低聚; 和（9），从而从所述产品混合物中分离所述一种或多种脂环族二胺。

公开(公告)号：EP2651909A1

公开(公告)日：2013-10-23

申请号：EP11802244.1

申请日：2011-12-07

申请人： Dow Global Technologies LLC

发明人： GU, Leming ,  FAN, William W. ,  JEAN, David ,  RIPPLINGER, Eric B. ,  HOOK, Bruce D. ,  WEST, David H.

IPC分类号： C07D301/16 ,  C07D303/04

CPC分类号： C07D301/16 ,  C07D303/04

摘要： A process for preparing a divinylarene oxide including (a) reacting (i) at least one divinylarene; (ii) at least one peroxycarboximidic acid; (iii) at least one solvent; and (iv) at least one basic compound, under reaction conditions to form a reaction effluent containing a divinylarene oxide product; and then (b) evaporating the reaction effluent of step (a) to form a concentrate containing the divinylarene oxide product; and wherein the concentrate separates into two liquid phases.

摘要翻译： 一种制备二乙烯基芳烃氧化物的方法，包括（a）使（i）至少一种二乙烯基芳烃反应; （ii）至少一种过氧羧酰亚胺酸; （iii）至少一种溶剂; 和（iv）至少一种碱性化合物，在反应条件下形成含有二乙烯基芳烃氧化物产物的反应流出物; 然后（b）蒸发步骤（a）的反应流出物以形成含有二乙烯基芳烃氧化物产物的浓缩物; 并且其中浓缩物分成两个液相。