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    Tertiary amine compounds
    1.
    发明公开
    Tertiary amine compounds 失效
    叔胺化合物

    公开(公告)号：EP0253502A3

    公开(公告)日：1990-04-11

    申请号：EP87305245.0

    申请日：1987-06-12

    申请人： IMPERIAL CHEMICAL INDUSTRIES PLC

    发明人： Worthington, Paul Anthony ,  Anthony, Vivienne Margaret

    IPC分类号： C07D307/52 ,  C07D333/20 ,  C07D207/32 ,  C07D413/08 ,  C07F7/08 ,  A01N43/08 ,  A01N43/10 ,  A01N43/36 ,  A01N43/84

    CPC分类号： C07D207/335 ,  A01N43/08 ,  A01N43/10 ,  A01N55/00 ,  C07D307/52 ,  C07D333/20 ,  C07D405/08 ,  C07D413/08 ,  C07F7/0814

    摘要： According to the invention there are provided compounds having the general formula (I):
    and stereoisomers thereof, wherein one of X and Y, but not both, is a group of the formula (II): and the other of X and Y is a hydrogen atom, a halogen atom, or an alkyl, cycloalkyl, cycloalkylalkyl. alkenyl, alkynyl, aryl, aralkyl, alkoxy, aryloxy or haloalkyl group or a
    group wherein R 9 , R 10 and R 11 can be alkyl, alkenyl, alkynyl, cycloalkyl, cycloalkylalkyl or aryl, Z is an oxygen atom, a sulphur atom or an -NH-group, A and B have the same significance as X or Y excluding a group of formula (II), R'. R 2 , R 3 and R 4 each represent a hydrogen atom, a halogen atom or an alkyl group containing from I to 4 carbon atoms, R 5 and R 6 each represent a hydrogen atom or an alkyl group containing from I to 4 carbon atoms, and R 7 and R 8 each represent an alkyl group containing from I to 4 carbon atoms or R 7 and R 8 together with the adjacent nitrogen atom form a heterocyclic ring which may optionally contain an additional hetero atom; and acid addition salts thereof.

    摘要翻译： 根据本发明，提供了具有通式（I）的化合物及其立体异构体，其中X和Y中的一个，但不是两个是式（II）的基团：并且X和Y中的另一个是 氢原子，卤素原子或烷基，环烷基，环烷基烷基。 炔基，芳基，芳烷基，烷氧基，芳氧基或卤代烷基或其中R9，R10和R11可以是烷基，链烯基，炔基，环烷基，环烷基烷基或芳基，Z是氧原子，硫原子或-NH - 基团，A和B具有与除式（II）的基团R'以外的X或Y相同的含义。 R2，R3和R4分别代表氢原子，卤素原子或含1至4个碳原子的烷基，R5和R6分别代表氢原子或含1至4个碳原子的烷基，R7和R8 各自表示含有1至4个碳原子的烷基或者R 7和R 8与相邻的氮原子一起形成可以任选地含有另外的杂原子的杂环; 和它们的酸加成盐。

    Tertiary amine compounds
    3.
    发明公开
    Tertiary amine compounds 失效
    Tertiär阿明 - Verbindungen。

    公开(公告)号：EP0253502A2

    公开(公告)日：1988-01-20

    申请号：EP87305245.0

    申请日：1987-06-12

    申请人： IMPERIAL CHEMICAL INDUSTRIES PLC

    发明人： Worthington, Paul Anthony ,  Anthony, Vivienne Margaret

    IPC分类号： C07D307/52 ,  C07D333/20 ,  C07D207/32 ,  C07D413/08 ,  C07F7/08 ,  A01N43/08 ,  A01N43/10 ,  A01N43/36 ,  A01N43/84

    CPC分类号： C07D207/335 ,  A01N43/08 ,  A01N43/10 ,  A01N55/00 ,  C07D307/52 ,  C07D333/20 ,  C07D405/08 ,  C07D413/08 ,  C07F7/0814

    摘要： According to the invention there are provided compounds having the general formula (I):
    and stereoisomers thereof, wherein one of X and Y, but not both, is a group of the formula (II):
    and the other of X and Y is a hydrogen atom, a halogen atom, or an alkyl, cycloalkyl, cycloalkylalkyl. alkenyl, alkynyl, aryl, aralkyl, alkoxy, aryloxy or haloalkyl group or a
    group wherein R 9 , R 10 and R 11 can be alkyl, alkenyl, alkynyl, cycloalkyl, cycloalkylalkyl or aryl, Z is an oxygen atom, a sulphur atom or an -NH-group, A and B have the same significance as X or Y excluding a group of formula (II), R'. R 2 , R 3 and R 4 each represent a hydrogen atom, a halogen atom or an alkyl group containing from I to 4 carbon atoms, R 5 and R 6 each represent a hydrogen atom or an alkyl group containing from I to 4 carbon atoms, and R 7 and R 8 each represent an alkyl group containing from I to 4 carbon atoms or R 7 and R 8 together with the adjacent nitrogen atom form a heterocyclic ring which may optionally contain an additional hetero atom; and acid addition salts thereof.

    摘要翻译： 根据本发明，提供了具有通式（I）的化合物及其立体异构体，其中X和Y中的一个，但不是两者是式（II）的基团：其中另一个 的X和Y是氢原子，卤素原子或烷基，环烷基，环烷基烷基，烯基，炔基，芳基，芳烷基，烷氧基，芳氧基或卤代烷基或基，其中R 9，R 1 > 0和R 1可以是烷基，烯基，炔基，环烷基，环烷基烷基或芳基，Z是氧原子，硫原子或-NH-基团，A和B具有与 不包括式（II）基团的X或Y，R 1，R 2，R 3和R 4各自表示氢原子，卤素原子或含有1至4个碳原子的烷基 原子，R 5和R 6各自表示氢原子或含有1至4个碳原子的烷基，R 7和R 8各自表示含有1至4个碳原子的烷基 或R 7和R 8与相邻的氮原子一起形成a 可以任选地含有另外的杂原子的杂环; 及其酸加成盐。

    Fungicidal azolyl-ethyl-phosphonate derivatives
    5.
    发明公开
    Fungicidal azolyl-ethyl-phosphonate derivatives 失效
    杀真菌唑酰基 - 乙基 - 膦酸酯衍生物

    公开(公告)号：EP0120609A3

    公开(公告)日：1985-01-23

    申请号：EP84301230

    申请日：1984-02-24

    申请人： IMPERIAL CHEMICAL INDUSTRIES PLC

    发明人： Dalziel, John ,  Worthington, Paul Anthony ,  Sugavanam, Balasubramanyan

    IPC分类号： C07F09/65 ,  A01N57/24 ,  C07D249/08 ,  C07D233/60 ,  C07F09/141 ,  C07F09/38

    CPC分类号： A01N57/24 ,  C07F9/65061 ,  C07F9/65181

    摘要： Compounds of formula:
    and stereoisomers thereof, wherein R 1 and R 2 are each hydrogen, a cation, alkyl, cycloalkyl, aryl or aralkyl optionally substituted with halogen, nitro, alkyl, haloalkyl, alkoxy, haloalkoxy, phenyl, phenoxy, halophenyl, or halophenoxy, or together form a ring; R 3 and R 4 are each hydrogen, alkyl, cycloalkyl, heterocyclyl, aryl or aralkyl optionally substituted with halogen, nitro, alkyl, haloalkyl, alkoxy, haloalkoxy, phenyl, phenoxy, halophenyl, or halophenoxy; W is N or CH; X is oxygen or sulphur; ester and ether derivatives of the alcohol; and their acid addition salts and metal complexes.

    摘要翻译： 下式的化合物及其立体异构体，其中R1和R2各自为氢，任选被卤素，硝基，烷基，卤代烷基，烷氧基，卤代烷氧基，苯基，苯氧基，卤代苯基或卤代苯氧基取代的阳离子，烷基，环烷基，芳基或芳烷基， 或者一起形成一个环; 硝基，烷基，卤代烷基，烷氧基，卤代烷氧基，苯基，苯氧基，卤代苯基或卤代苯氧基; R 3和R 4各自为氢，烷基，环烷基，杂环基，芳基或芳烷基。 W是N或CH; X是氧或硫; 醇的酯和醚衍生物; 和它们的酸加成盐和金属络合物。

    Improved process for preparing imidazole and 1,2,4-triazole derivatives
    10.
    发明公开
    Improved process for preparing imidazole and 1,2,4-triazole derivatives 失效
    制备咪唑并1,2,4-三唑衍生物的改进方法

    公开(公告)号：EP0027685A3

    公开(公告)日：1981-05-06

    申请号：EP80303158

    申请日：1980-09-09

    申请人： IMPERIAL CHEMICAL INDUSTRIES PLC

    发明人： Worthington, Paul Anthony ,  Sugavanam, Balasubramanyan

    IPC分类号： C07D249/08 ,  C07D233/60 ,  C07C69/716 ,  C07C49/12 ,  C07C49/203

    CPC分类号： C07D231/12 ,  C07C45/65 ,  C07C45/673 ,  C07C59/185 ,  C07D233/56 ,  C07D249/08 ,  C07C49/203 ,  C07C49/12

    摘要： An improved process for preparing imidazole and 1 ,2,4-triazole derivatives comprises the steps of:-
    (a) reacting a β-keto ester R 1 -CO-CH 2 COOR with a a-halo ketone R 2 COCH 2 X where X = halogen, (b) hydrolysing the diketo ester to a diketone R 1 COCH 2 CH 2 COR (c) oxidising the diketone esterto an unsaturated diketone (d) reacting the unsaturated diketone with imidazole or 1,2,4-triazole (e) selectively reducing the product of (d) to give a compound offormula:
    wherein R' and R 2 are optionally substituted alkyl, cycloalkyl or phenyl.

    摘要翻译： 制备咪唑和1,2,4-三唑衍生物的改进方法包括以下步骤： - （a）使β-酮酯R 1 -CO-CH 2 COOR与α-卤代酮R 2 COCH 2 X反应，其中 X =卤素，（b）将二酮酯水解成二酮R 1 COCH 2 CH 2 COR 2（c）将二酮氧化成不饱和二酮（d）使不饱和二酮与咪唑或1,2,4-三唑反应 （e）选择性地还原（d）的产物得到下式的化合物：其中R 1和R 2为任选取代的烷基，环烷基或苯基。