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    PREPARATION OF CYANOPHOSPHONATES FROM PYROPHOSPHATES AND CYANIDE
    1.
    发明公开
    PREPARATION OF CYANOPHOSPHONATES FROM PYROPHOSPHATES AND CYANIDE 失效
    而离去CYANOPHOSPHONATEN焦磷酸盐和氰化物

    公开(公告)号：EP0948504A1

    公开(公告)日：1999-10-13

    申请号：EP97954170.0

    申请日：1997-12-23

    申请人： MONSANTO COMPANY

    发明人： LENNON, Patrick, J. ,  VULFSON, Sergey, G.

    IPC分类号： B01J23 ,  B01J27 ,  C07B61 ,  C07F9

    CPC分类号： C07F9/4062 ,  C07F9/3808 ,  C07F9/3886

    摘要： Phosphorus-containing compounds such as cyanophosphonate derivatives are important precursors for the synthesis of organophosphorus compounds, which have numerous applications, for example, in herbicides, insecticides, fertilizers, flame retardants and plasticizers. Cyanophosphonate derivatives can be further converted to aminomethylphosphonate derivatives, which have been particularly important precursors in the synthesis of N-phosphonomethyglycine, a highly effective commercial herbicide (available under the trade name Roundup) useful for the control of a large variety of weeds. The syntheses of such organophosphorus compounds have commonly used a hologen derivative of phosphorus as a starting material.

    HYDROGENATION OF MIXTURES OF CYANOPHOSPHONATES AND GLYCINE
    3.
    发明公开
    HYDROGENATION OF MIXTURES OF CYANOPHOSPHONATES AND GLYCINE 失效
    氰基膦酸酯与甘氨酸混合物的氢化

    公开(公告)号：EP0948505A1

    公开(公告)日：1999-10-13

    申请号：EP97954171.0

    申请日：1997-12-23

    申请人： MONSANTO COMPANY

    发明人： LENNON, Patrick, J.

    IPC分类号： C07F9

    CPC分类号： C07F9/3813

    摘要： A process for preparing N-phosphonomethylglycine or an N-phosphonomethylglycine derivative involves the hydrogenation of cyanophosphonate derivatives in the presence of a glycine derivative and a catalyst to produce N-phosphonomethylglycine.

    摘要翻译： 制备N-膦酰基甲基甘氨酸或N-膦酰基甲基甘氨酸衍生物的方法涉及氰基膦酸酯衍生物在甘氨酸衍生物和催化剂存在下的氢化以产生N-膦酰基甲基甘氨酸。

    PROCESS FOR PREPARING SUBSTITUTED POLYAZAMACROCYCLES
    9.
    发明公开
    PROCESS FOR PREPARING SUBSTITUTED POLYAZAMACROCYCLES 失效
    用于生产的取代的POLYAZAMACRORINGEN

    公开(公告)号：EP0830351A1

    公开(公告)日：1998-03-25

    申请号：EP96916578.0

    申请日：1996-05-30

    申请人： MONSANTO COMPANY

    发明人： LENNON, Patrick, J. ,  HENKE, Susan, L. ,  ASTON, Karl, W.

    IPC分类号： C07D259 ,  C07F9 ,  C07F13

    CPC分类号： C07D259/00 ,  C07F9/6524 ,  C07F13/005

    摘要： A process for preparing a substituted polyazamacrocycle is provided which comprises contacting a diamine or triamine and a dicarboxylic acid or ester or anhydride thereof in the presence of a suitable base and a suitable solvent to produce the substituted polyazamacrocycle provided that when an ester of said dicarboxylic acid is used, said suitable base is optional, and when said dicarboxylic acid or an anhydride of said dicarboxylic acid is used, the reaction mixture further comprises a suitable coupling agent.