摘要:
A polymer compound comprising a constitutional unit represented by the following formula (1) and a constitutional unit represented by the following formula (X) and/or a constitutional unit represented by the following formula (Y), wherein the content of the hydroxyl groups contained in the polymer compound is less than 0.02 mol%:
[wherein, Ar 1 represents an arylene group and this group optionally has a substituent.]
[wherein, a X1 and a X2 each independently represent an integer of 0 or more. Ar X1 and Ar X3 each independently represent an arylene group or a divalent heterocyclic group and these groups each optionally have a substituent. Ar X2 and Ar X4 each independently represent an arylene group, a divalent heterocyclic group or a divalent group in which at least one arylene group and at least one divalent heterocyclic group are bonded directly to each other, and these groups each optionally have a substituent. When there are a plurality of Ar X2 and a plurality of Ar X4 , each of them may be the same or different. R X1 , R X2 and R X3 each independently represent an alkyl group, an aryl group or a monovalent heterocyclic group and these groups each optionally have a substituent. When there are a plurality of R X2 and a plurality of R X3 , each of them may be the same or different.]
[wherein, Ar Y1 represents an arylene group, a divalent heterocyclic group or a divalent group in which at least one arylene group and at least one divalent heterocyclic group are bonded directly to each other, and these groups each optionally have a substituent.].
摘要翻译:包含由下式(1)表示的结构单元和由下式(X)表示的结构单元和/或由下式(Y)表示的结构单元的聚合物化合物,其中所含的羟基含量 在高分子化合物中,低于0.02摩尔%:[式中,Ar 1表示亚芳基,该基团任选具有取代基。] [式中,X1和X2各自独立地表示0以上的整数。 Ar X1和Ar X3各自独立地表示亚芳基或二价杂环基,并且这些基团各自任选具有取代基。 Ar X2和Ar X4各自独立地表示亚芳基,二价杂环基或二价基团,其中至少一个亚芳基和至少一个二价杂环基彼此直接键合,并且这些基团各自任选具有取代基。 当存在多个Ar X2和多个Ar X4时,它们各自可以相同或不同。 R X1,R X2和R X3各自独立地表示烷基,芳基或1价的杂环基,这些基团各自含有取代基。 当存在多个R X2和多个R X3时,它们各自可以相同或不同。] [其中,Ar Y1表示亚芳基,二价杂环基或二价基团,其中至少一个亚芳基 基团和至少一个二价杂环基团彼此直接键合,并且这些基团各自任选具有取代基。
摘要:
A method for producing a biaryl compound represented by the formula (2)
Ar-Ar (2)
wherein Ar represents an aromatic group which can have a substituent, comprising conducting a coupling reaction of a compound represented by the formula (1)
Ar-Cl (1)
wherein Ar represents the same meaning as defined above, in the presence of copper metal and a copper salt.
摘要:
Provided is a polyarylene type block copolymer comprising a block having an ion exchange group and a block having substantially no ion exchange group, wherein the main chain of the block having an ion exchange group has a polyarylene structure in which a plurality of aromatic rings are directly connected, and the ion exchange group is directly bonded to the aromatic ring composing the main chain; a method for production thereof; and a use thereof.
摘要:
A method for producing a compound, comprising mixing a compound (1) having one or two leaving groups, a compound (2) having one or two boron atom-containing leaving groups, an organic base (P), and at least one selected from the group consisting of a phase transfer catalyst and an organic base (Q) larger in the number of carbon atoms than the above-mentioned organic base in the presence of a transition metal catalyst, thereby performing a coupling reaction between the above-mentioned compound (1) and the above-mentioned compound (2).
摘要:
The invention provides a process for producing a metallocene compound of formula (3)
wherein R 1 to R 9 independently denote a hydrogen atom, a halogen atom, an alkyl, or the like; R 10 denotes a halogen atom, an alkyl, an alkoxy, or the like; X 5 and X 6 independently denote a hydrogen atom, a halogen atom, or the like; and M denotes a transition metal atom of Group 4 of the Periodic Table, which process is characterized by reacting a silicon-substituted cyclopentadiene compound of formula (1)
wherein R 1 to R 10 independently denote the same as described above; R 11 denotes a hydrocarbon group or a tri-substituted silyl; and R 12 to R 14 independently denote a halogen atom or a hydrocarbon group, with a transition metal compound of the following formula (2)
wherein M denotes the same as described above; X 1 , X 2 , X 3 , and X 4 independently denotes a hydrogen atom, a halogen atom, an alkyl, or the like, in a solvent containing an aromatic hydrocarbon.
摘要翻译:本发明提供一种制备式(3)的茂金属化合物的方法,其中R 1至R 9独立地表示氢原子,卤素原子,烷基等; R 10表示卤素原子,烷基,烷氧基等; X 5和X 6独立地表示氢原子,卤素原子等; M表示周期表第4族的过渡金属原子,该方法的特征在于使式(1)的硅取代的环戊二烯化合物(其中R 1至R 10独立地表示与上述相同的基团) R 11表示烃基或三取代甲硅烷基; 和R 12至R 14独立地表示卤素原子或烃基,与下式(2)的过渡金属化合物,其中M表示与上述相同的基团; 在含有芳烃的溶剂中,X 1,X 2,X 3和X 4独立地表示氢原子,卤素原子,烷基等。
摘要:
Polyarylene comprising a dihalobenzene compound represented by the formula (1): (1) (wherein A represents an alkoxy group having 3 to 20 carbon atoms or the like, R1 represents a hydrogen atom, a fluorine atom, an alkyl group having 1 to 20 carbon atoms or the like, X1 represents a chlorine atom or the like, m represents 1 or 2, and k represents 4-m) and a repeating unit represented by the formula (2): (2) (wherein A, R1, m and k have the same meaning as above).
摘要:
A dihalobiphenyl compound represented by the formula (1): (1) (wherein A represents amino substituted by one or two C1-20 hydrocarbon groups or represents C1-20 alkoxy; R1 represents fluorine, C1-20 alkyl, etc.; X1 represents chlorine, bromine, or iodine; and k is an integer of 0-3). Also provided is a polyarylene comprising repeating units represented by the formula (2): (2) (wherein A, R1, and k have the same meanings as defined above).
摘要:
A dihalobiphenyl compound represented by the formula (1):
wherein A represents an amino group substituted with one or two C1-C20 hydrocarbon groups or a C1-C20 alkoxy group, R 1 represents a fluorine atom, a C1-C20 alkyl group, etc., X 1 represents a chlorine atom, a bromine atom or an iodine atom, an k represents an integer of 0 to 3, and a polyarylene comprising a repeating unit represented by the formula (2):
wherein A, R 1 and k represent the same meanings as defined above.
摘要翻译:由式(1)表示的二卤代联苯化合物:其中A表示被一个或两个C1-C20烃基或C1-C20烷氧基取代的氨基,R1表示氟原子,C1-C20烷基等 X 1表示氯原子,溴原子或碘原子,k表示0至3的整数,和包含由式(2)表示的重复单元的聚亚芳基:其中A,R 1和k表示相同的含义 如上所述。