摘要:
A method for producing an aromatic polymer containing aromatic polyamide structural units and aromatic carbohydrazide structural units at a specific ratio is disclosed. A film having a high Young's modulus, high elongation at break and low moisture absorption can be formed from such an aromatic polymer. Dehydration cyclization of a compound having a carbohydrazide structure can be conducted under mild conditions at low cost by causing the chemical reaction using a chemical which is selected from the acids and bases.
摘要:
A process for the bulk polymerization, in the absence of any solvent, of a reactant containing azide functionality and a reactant containing a terminal alkyne functionality, in the presence of Cu (I) catalyst or in the presence of a Cu(II) catalyst without a reducing agent, is described. Polymerization can be achieved at temperatures less than 100 °C, which is suitable for low temperature cures. A controlled synthesis for low molecular weight oligomers is disclosed.
摘要:
In a preparation of random polyoxadiazole copolymer by reaction of a mixture of oleum, hydrazine sulfate, terephthalic acid, and isophthalic acid, the improvement requires the addition of oleum in more than one step.
摘要:
The high efficiency and fidelity of click chemistry permits a large number of diverse dendrimers encompassing a wide variety of functionalities at the chain ends, repeat units, and/or core to be prepared. Almost quantitative yields were obtained during the synthesis. In some cases, filtration or solvent extraction was the only method required for purification. These features represent a significant advancement in dendrimer chemistry and demonstrate an evolving synergy between organic chemistry and functional materials.
摘要:
This invention discloses a class of soluble poly(arylene-oxadiazole) polymers and copolymers comprising from 3 to 300 repeat units, which may be the same or different, represented by the formula: (I) wherein Arom can be a fluorene group, an aromatic hydrocarbon ring, an aromatic C2+ heterocyclic ring, or two aromatic rings linked by a single bond, ethenyl bond, or ethynyl bond. A process for preparing the polymers and copolymers by reacting dicarboxylic acids and hydrazine salt is provided. The polymers are useful in electroluminescent devices, photovoltaic cells, and diodes.
摘要:
Block copolymers may contain polybenzazole blocks and blocks of polybenzoxazinone polymer or polyoxadiazole polymer. The block copolymers may be coagulated from isotropic dopes to form shaped articles or granular compositions. The granular compositions may be compression molded to form molded articles. The block copolymers may be molded at high temperatures without substantial phase separation, and the polybenzazole polymer provides support to improve the tensile propoerties of the polymer.