FLAME-RETARDANT STYRENE RESIN COMPOSITION AND MOLDED ARTICLE OBTAINED THEREFROM
    116.
    发明公开
    FLAME-RETARDANT STYRENE RESIN COMPOSITION AND MOLDED ARTICLE OBTAINED THEREFROM 审中-公开
    多功能激光打标机FLAMMWIDRIGE STYROLHARZZUSAMMENSETZUNG

    公开(公告)号:EP1693412A1

    公开(公告)日:2006-08-23

    申请号:EP03778782.7

    申请日:2003-12-10

    摘要: It is an object of the present invention to provide a styrene type resin composition excellent in thermal stability, hue, fluidity, and heat resistance, and also having the flame retardant performance, and a molded product excellent in outward appearance, formed therefrom.
    The present invention provides a flame retardant styrene type resin composition comprising (A) a styrene type resin (component A) in an amount of 100 parts by weight, (B) a polyphenylene ether type resin (component B) in an amount of 0 to 100 parts by weight, and (C) an organophosphorus compound (component C) represented by the following formula (1) in an amount of 1 to 100 parts by weight, characterized in that the organophosphorus compound (component C) satisfies:

    (i) the weight loss residue on heating at 500°C is 10% or less;
    (ii) the HPLC purity is 90% or more, and
    (iii) the acid value is 0.5 mg KOH/g or less

    (where in the formula, Ar 1 and Ar 2 may be the same or different, and is a phenyl group which may have a substituent.)

    摘要翻译: 本发明的目的是提供热稳定性,色调,流动性和耐热性优异并且具有阻燃性能的苯乙烯型树脂组合物,以及由其形成的外观优异的模塑制品。 本发明提供一种阻燃苯乙烯类树脂组合物,其包含(A)100重量份的苯乙烯类树脂(组分A),(B)聚苯醚型树脂(组分B),其量为0至 100重量份,和(C)由下式(1)表示的有机磷化合物(组分C)的量为1〜100重量份,其特征在于有机磷化合物(C成分)满足:(i) 在500℃下加热时的减重残留量为10%以下; (ii)HPLC纯度为90%以上,(iii)酸值为0.5mgKOH / g以下(式中,Ar 1和Ar 2可以相同或不同,为苯基 其可以具有取代基。)

    FLAMEPROOF THERMOPLASTIC RESIN COMPOSITION
    117.
    发明公开
    FLAMEPROOF THERMOPLASTIC RESIN COMPOSITION 有权
    防火热塑性树脂组合物

    公开(公告)号:EP1654315A1

    公开(公告)日:2006-05-10

    申请号:EP04773821.6

    申请日:2004-05-25

    摘要: The flameproof resin composition according to the present invention comprises (A) 100 parts by weight of a transparent ABS resin containing (a1) 20 to 100 % by weight of graft copolymer composed of 5 to 60 parts by weight of a rubber polymer, 1 to 30 parts by weight of aromatic vinyl compound, 10 to 40 parts by weight of a unsaturated nitrile compound and 10 to 60 parts by weight of a (meth)acrylic acid alkylester compound; and (a2) 0 to 80 % by weight of styrenic copolymer composed of 40 to 80 parts by weight of a (meth)acrylic acid alkyl ester compound, 10 to 30 parts by weight of an aromatic vinyl compound and 0 to 50 parts by weight of a unsaturated nitrile compound; (B) 0.1 to 15 parts by weight of a ring-shaped alkyl phosphonic acid compound; and optionally (C) 0 to 20 parts by weight of an aromatic phosphoric acid ester compound.

    摘要翻译: 本发明的阻燃树脂组合物含有(A)100重量份透明ABS树脂,其含有(a1)20〜100重量%的接枝共聚物,该接枝共聚物由5〜60重量份的橡胶聚合物, 30重量份的芳香族乙烯基化合物,10〜40重量份的不饱和腈化合物和10〜60重量份的(甲基)丙烯酸烷基酯化合物; 和(a2)0-80重量%的由40-80重量份的(甲基)丙烯酸烷基酯化合物,10-30重量份的芳族乙烯基化合物和0-50重量份的苯乙烯类共聚物 的不饱和腈化合物; (B)0.1至15重量份的环状烷基膦酸化合物; 和(C)0至20重量份的芳族磷酸酯化合物。

    FLAMEPROOF THERMOPLASTIC RESIN COMPOSITION
    118.
    发明公开
    FLAMEPROOF THERMOPLASTIC RESIN COMPOSITION 有权
    防火热塑性树脂组合物

    公开(公告)号:EP1651716A1

    公开(公告)日:2006-05-03

    申请号:EP03817808.3

    申请日:2003-12-09

    IPC分类号: C08K5/5317

    摘要: The flameproof thermoplastic resin composition according to the present invention comprises (A) 100 parts by weight of a rubber modified styrene comprising resin (a1) 10 to 100 % by weight of a grafted copolymer resin prepared by graft polymerization with a rubber phase polymer, an aromatic vinyl monomer, a monomer copolymerizable with said aromatic vinyl monomer and a monomer for processability and thermal resistance, and (a2) 0 to 90 % by weight of a copolymer resin prepared by copolymerization with an aromatic vinyl monomer, a ,monomer copolymerizable with said aromatic vinyl monomer and a monomer for processability and thermal resistance, and (B) 0.1 to 15 parts by weight of a ring-shaped alkyl phosphonic acid compound represented by the following formula: (I) wherein R1 and R2 are independently of each other C1-C4 alkyl and x is 0 or 1.

    摘要翻译: 本发明的耐火性热塑性树脂组合物含有(A)橡胶改性苯乙烯100重量份,树脂(a1)10〜100重量%与橡胶相聚合物接枝聚合而成的接枝共聚树脂, 芳香族乙烯基单体,可与所述芳香族乙烯基单体和可加工单体和耐热性单体共聚的单体,和(a2)0-90重量%通过共聚合芳族乙烯基单体制备的共聚物树脂,a,可与所述 芳族乙烯基单体和用于加工性和耐热性的单体,和(B)0.1至15重量份由下式表示的环状烷基膦酸化合物:(I)其中R 1和R 2彼此独立地为C 1 -C4烷基,并且x是0或1。