摘要:
A process to regenerate metal oxide desulfurization sorbents using an oxidizing and reducing atmosphere. The sorbents may be mono- or multi-metallic in nature, and preferably comprise Cu, Ni and/or Co. If desired, secondary metals may be incorporated to increase regeneration efficiency and/or capacity. Other additives may be used to suppress hydrocarbon cracking. A sorbent containing Zn may be combined with an Fe, Co, Ni, Mo, or W catalyst or a noble metal catalyst and combinations thereof.
摘要:
A method for desulfurization of hydrocarbon comprising reducing the sulfur content of hydrocarbons containing sulfur compounds, which comprises mixing the hydrocarbons containing sulfur compounds with water vapor, and contacting the resultant mixture with a catalyst comprising an inorganic oxide support and either platinum or palladium fixed to the support, and with a desulfurizing material at a temperature of 300°C or higher.
摘要:
The invention relates to a process for producing a hydrocarbon component of biological origin. The process comprises at least two steps, the first one of which is a HDO step and the second one is an isomerization step operated using the counter-current flow principle. A biological raw material containing fatty acids and/or fatty acid esters serves as the feed stock.
摘要:
A catalyst for hydrotreating of a gas oil which comprises an alumina-containing inorganic oxide carrier and, carried thereon, 0.1 to 10 mass % of platinum, 0.1 to 20 mass % of palladium and 0.05 to 1.2 mass % of a halogen, characterized in that the crystalline alumina contained in the above alumina has a crystallite diameter of 20 to 40 ANGSTROM ; a method for hydrotreating of a gas oil which comprises carrying out a catalytic reaction of gas oil in the presence of said catalyst; and a method for hydrotreating of a gas oil which comprises a first desulfurization process of carrying out a catalytic reaction of a straight-run gas oil having a boiling range of 160 to 400 DEG C in the presence of a catalyst comprising an inorganic carrier and, carried thereon, 10 to 25 mass % of at least one metal selected from those belonging to 6a Group of the periodic Table and 0.1 to 6 mass % of at least one metal selected from those belonging to 8 Group of the periodic Table, to thereby produce an oil having a content of sulfur compounds of 0.2 mass % or less, and a second desulfurization process of carrying out a catalytic reaction in the presence of a catalyst comprising an alumina-containing inorganic oxide carrier and, carried thereon, 0.1 to 10 mass % of platinum, 0.1 to 20 mass % of palladium and 0.05 to 1.2 mass % of a halogen.
摘要:
A catalyst for the hydrodesulfurization and isomerization of a light hydrocarbon oil, comprising a support comprising zirconium oxide or a zirconium hydroxide, from 1 to 3 wt% sulfuric acid radicals in terms of sulfur amount based on the total weight of the catalyst composition, and (I) from 0.05 to 10 wt% palladium, (II) from 0.05 to 10 wt% palladium and from 0.05 to 10 wt% platinum, or (III) from 0.05 to 10 wt% nickel based on the total weight of the catalyst composition, and having a specific surface area of from 50 to 150 m /g after stabilization by burning at a temperature of from 550 to 800 DEG C; a process for producing the catalyst; and a method for the hydrodesulfurization and isomerization of a light hydrocarbon oil with the catalyst.
摘要:
The invention concerns a process for hydrogenation, hydroisomerization and/or hydrodesulfurization of a sulfur contaminant containing hydrocarbon feedstock, wherein the feedstock is contacted in the presence of hydrogen gas with a catalyst, which catalyst comprises platinum, palladium or a combination thereof on a non-crystalline, acidic silica-alumina support, which support is obtained by sol-gel techniques and wherein the ratio of Si to Al is from 1:10 to 200:1.
摘要:
A process for treating a light cracked naphtha (2) in a catalytic distillation column (10) in which mercaptans and diolefins are removed simultaneously using a Pd catalyst (12). The treated naphtha is subsequently etherified. The mercaptans and diolefins are reacted to form sulfides which are removed as bottoms (8) from the distillation column. Any diolefins not converted to sulfides are selectively hydrogenated to monolefins for use in the etherification process.
摘要:
Methods are provided for making base metal catalysts with improved activity. After forming catalyst particles based on a support comprising a zeolitic molecular sieve, the catalyst particles can be impregnated with a solution comprising a) metal salts (or other precursors) for a plurality of base metals and b) an organic dispersion agent comprising 2 to 10 carbons. The impregnated support particles can be dried to form a base metal catalyst, and then optionally sulfided to form a sulfided base metal catalyst. The resulting (sulfided) base metal catalyst can have improved activity for cloud point reduction and/or for improved activity for heteroatom removal, relative to a base metal dewaxing catalyst prepared without the use of a dispersion agent.