摘要:
Die Erfindung betrifft ein Verfahren zum Schwarzverchromen von Oberflächen in einem Bad mit Chromsäure, bei welchem Verfahren mit einem Salz der Fluorwasserstoffsäure eine erste wässrige Lösung hergestellt wird, und dann die erste wässrige Lösung dem Bad mit der Chromsäure dosiert zugeführt wird.
摘要:
To provide a trivalent chromium plating film, in which the generation of cracks penetrating from the film surface to a substrate interface is suppressed, and a sliding member coated with the trivalent chromium plating film, plating is conducted with a chromium plating bath containing trivalent chromium as a chromium source, with a second phase dispersed in a planar and/or fibrous form, such that the second phase in a planar and/or fibrous form is dispersed in the hard chromium plating film to prevent or deflect the propagation of cracks, and to suppress the increase of the crack width, thereby suppressing the propagation of cracks in the hard chromium plating film.
摘要:
A method of treating a substrate, wherein the substrate comprises a layer deposited from a trivalent chromium electrolyte, is described. The method includes the steps of providing an anode and the chromium(III) plated substrate as a cathode in an electrolyte comprising (i) a trivalent chromium salt; and (ii) a complexant; and passing an electrical current between the anode and the cathode to passivate the chromium(III) plated substrate. The substrate may be first plated with a plated nickel layer so that the chromium(III) plated layer is deposited over the nickel plated layer.
摘要:
An electrolyte for the electrodeposition of chromium is described. The electrolyte comprises: (A) water; (B) at least one chromium salt; and (C) at least one complexing agent, wherein the molar ratio of components B:C is 1:1 to 1:50. The electrolyte complexing agent may comprise an ionic liquid such as choline chloride (ChCl), urea or glycerol. Additives can also be added to the electrolyte such as boric acid, cirtic acid, methyl nicotinate (C7H7NO2) or sodium phosphate . Sodium chloride (NaCl) or sodium (NaI) may also be added. The electrolyte can also contain 10-25% water.
摘要:
The invention relates to a chromium-based coating comprising at least one layer rich in crystalline phase or phases of nickel (Ni) and/or Ni compounds, and at least one layer rich in crystal-line phase or phases of chromium (Cr) and/or Cr compounds, Cr being electroplated from a trivalent chromium bath. The coating is characterized in that the it further comprises one or more crystalline phases of chromium-nickel-phosphorus (CrNiP), which CrNiP phase has been produced by heat treating a coating comprising at least one layer of nickel-phosphorus (NiP) and at least one layer of Cr. The invention also relates to a method for producing a chromiumbased coating and to a coated object.
摘要:
The invention relates to a corrosion protection layer system for metal surfaces, said layer system comprising as the two top most layers: a) a discontinuous nickel-phosphorous layer and b) a chromium layer plated from a trivalent chromium electrolyte solution, as well as to a method of producing such a layer system. The inventive layer system is capable to combine the good corrosion resistance of the nickel-phosphorous layer against sodium chloride with the protective power of the chromium layer from the trivalent plating process against magnesium and calcium salts, especially without the need for any post-treatment.
摘要:
The present invention refers to an electroplating bath for depositing chromium which comprises at least one trivalent chromium salt, at least one complexing agent, at least one halogen salt and optionally further additives. Moreover, the invention refers to a process for depositing chromium on a substrate using the mentioned electroplating bath.