摘要:
The invention relates to the use of an electrolyte for the electrolyte deposition of chromium as metal on an intaglio printing cylinder, comprising (a) a chromium(III)-salt, (b) a compound of formula (I), wherein R represents NH 2 , OH or SO 3 H and n is a whole number between 1 - 3, (c) formic acid, and (d) at least one additive. The invention also relates to a method for the deposition of a chromium layer, to an intaglio printing cylinder coated with chromium and obtained according to said method, and to an electrolytic cell for coating intaglio printing cylinders with chromium.
摘要:
The invention consists of a chromium electroplating solution comprising a chromium electroplating solution comprising: (1) a water soluble trivalent chromium salt; (2) at least one complexant for trivalent chromium ions; (3) a source of hydrogen ions sufficient to create a pH of from 2.8-4.2; (4) a pH buffering compound; and (5) a sulfur-containing organic compound. The chromium electroplating solution is usable in a method for producing an adherent metallic coating on a decorative article, such coating having enhanced resistance to corrosion in environments containing calcium chloride.
摘要:
The chromium (III) carbonate of the present invention exhibits a light blue color in a solid state. This chromium (III) carbonate has an L* value of 50 to 70, an a* value of -4 to -2, and a b* value of -10 to -7, which are represented by the L*a*b* color system (JIS Z8729). This chromium (III) carbonate is preferably completely dissolved within 30 minutes when the chromium (III) carbonate is added, in an amount corresponding to a Cr content of 1 g, to 1 liter of an aqueous solution of hydrochloric acid having a pH of 0.2 at a temperature of 25°C. This chromium (III) carbonate is preferably obtained by contacting an aqueous solution of carbonate and an aqueous solution containing trivalent chromium at a pH of 6 to 12 under the condition of a reaction liquid temperature of 0°C or more and less than 50°C. Also, preferably, after production of the chromium (III) carbonate, filtration is performed, and the chromium (III) carbonate is washed with water until the conductivity of the filtrate is 5 mS/cm or less.
摘要翻译:本发明的碳酸铬(III)表现出固态的淡蓝色。 该碳酸铬(III)的L *值为50〜70,a *为-4〜-2,ab *为-10〜-7,由L * a * b *颜色 系统(JIS Z8729)。 当碳酸铬(III)以相当于Cr含量1g的量加入到1升pH为0.2的盐酸水溶液中时,碳酸铬(III)优选在30分钟内完全溶解 在25℃的温度下。 该碳酸铬(III)优选通过在反应液温度为0℃以上且小于50℃的条件下使碳酸盐水溶液和含有3价铬的水溶液在pH6〜12下接触而得到 。 此外,优选在碳酸铬(III)的制造之后,进行过滤,并用水洗涤碳酸铬(III)直到滤液的电导率为5mS / cm以下。
摘要:
A method for electroplating a plastic substrate includes the following steps a plastic substrate is firstly provided. The plastic substrate is then pretreated to form a noble metal coating. The noble metal coating is coated with a copper coating. A first chrome coating is electroplated onto the copper coating using a first electrolyte including a chromic component. A second chrome coating is electroplated onto the first chrome coating using a second electrolyte including a chromyl component.
摘要:
A composite chromium plating film containing hard particles in fine cracks in the form of a network formed on the film, wherein the above fine cracks account for 10 to 20 area % of the surface thereof, the above fine cracks distribute in a density of 1,200 to 2,500 pieces/cm, and the above hard particles are contained in a content of 1 to 15 mass % relative to 100 mass % of the whole plating film. The above composite chromium plating film is excellent in abrasion resistance and the resistance to seizure and also is reduced in the attack to a mating material.
摘要:
The invention relates to a method for producing a structured hard chromium layer, during which chromium from an electrolyte is deposited onto a workpiece, which contains: a) a Cr(VI) compound in a quantity corresponding to between 50 and 300 g/l of chromic anhydride; b) 0.5 g/l to 10 g/l sulfuric acid, and; c) 5 g/l to 15 g/l aliphatic sulfonic acid having 1 to 6 carbon atoms. The electrolyte contains essentially no compounds from the group consisting of ammonium molybdate, alkaline molybdate, alkaline earth molybdate, ammonium vanadate, alkaline vanadate and alkaline earth vanadate, ammonium zirconate, alkaline zirconate and alkaline earth zirconate, and is processed with a cathodic efficiency of 12 % or less. The invention also relates to a method for producing a coating, to a structured hard chromium layer, a coating and an electrolyte.
摘要:
In forming a plating layer for a sliding portion, which comprises Cr that is electrolytically-deposited in a plating bath containing Cr, the plating bath contains organic sulfonic acid. Accordingly, micro-cracks are formed at the plating layer. The plating layer for a sliding portion has superior low friction and lubricating property.
摘要:
The invention relates to a galvanic bath, to a method for precipitating chromium onto objects using said galvanic bath, and to the use of this method for producing structured hard chromium layers on machine parts. The galvanic bath contains at least one compound which provides chromium (VI) ions, in an aqueous solution, and comprises a) a quantity of chromium (VI) ions corresponding to 100 to 600 g/l chromic acid anhydride, b) sulphate ions in the form of sulphuric acid and/or a soluble salt thereof, the molar concentration ratio of chromium (VI) ions to sulphate ions (SO42-) being 90:1 to 120:1 and c) a quantity of 2-hydroxyethane sulphonate ions corresponding to 0.01 to 3.0 g/l of the sodium salt.
摘要:
Novel electrodeposited chromium layers, processes for their electrodepositions and plating baths suitable for use therein are disclosed. The chromium layers are bright, adherent, smooth, hard, wear resistant, exhibit a low coefficient of friction, thus, providing increased life and efficiency for devices employing the layers as wear surfaces, and are capable of being formed at both high and low current densities.