公开(公告)号：EP2504098B1

公开(公告)日：2016-07-06

申请号：EP10779561.9

申请日：2010-11-23

Applicant: BASF SE ,  The Dow Chemical Company

Inventor： MÜLLER, Ulrich ,  RUDOLF, Peter ,  KRUG, Georg ,  SENK, Rainer

IPC: B01J37/08 ,  B01J37/00 ,  C07D301/12 ,  B01J29/89

CPC classification number: B01J29/89 ,  B01J37/0018 ,  B01J37/084 ,  B01J2229/42 ,  C07D301/12

公开(公告)号：EP3024580A1

公开(公告)日：2016-06-01

申请号：EP14739190.8

申请日：2014-07-16

Applicant: BASF SE ,  Dow Global Technologies LLC

Inventor： TELES, Joaquim Henrique ,  SEELIG, Bianca ,  RIEDEL, Dominic ,  KAMPE, Philip ,  URBANCZYK, Daniel ,  WEBER, Markus ,  MÜLLER, Ulrich ,  PARVULESCU, Andrei-Nicolae ,  SCHRÖDER, Alexander ,  WEIDENBACH, Meinolf ,  WITZL, Werner

IPC: B01J29/89 ,  B01J29/70 ,  B01J37/02 ,  C07D301/12 ,  C07D301/36 ,  C07D303/04 ,  B01J35/00 ,  B01J37/10

CPC classification number: C07D301/36 ,  B01J23/06 ,  B01J27/18 ,  B01J29/7088 ,  B01J29/89 ,  B01J35/00 ,  B01J35/0006 ,  B01J35/023 ,  B01J35/026 ,  B01J37/0009 ,  B01J37/0045 ,  B01J37/0201 ,  B01J37/10 ,  B01J2229/186 ,  B01J2229/42 ,  C07D301/12 ,  C07D303/04 ,  Y02P20/52

Abstract: A continuous process for the preparation of propylene oxide, comprising (i) providing a liquid feed stream comprising propene, hydrogen peroxide, acetonitrile, water, dissolved potassium dihydrogen phosphate, and optionally propane; (ii) passing the liquid feed stream provided in (i) into an epoxidation reactor comprising a catalyst comprising a titanium zeolite of structure type MWW, and subjecting the liquid feed stream to epoxidation reaction conditions; (iii) removing an effluent stream from the epoxidation reactor; wherein the concentration of the dissolved potassium dihydrogen phosphate in the liquid feed stream is at least 10% of the solubility limit of the potassium dihydrogen phosphate in the liquid feed stream.

Abstract translation: 一种用于制备环氧丙烷的连续方法，包括（i）提供包含丙烯，过氧化氢，乙腈，水，溶解的磷酸二氢钾和任选的丙烷的液体进料流; （ii）将（i）中提供的液体进料流送入包含包含结构类型MWW的钛沸石的催化剂的环氧化反应器中，并使液体进料流进行环氧化反应条件; （iii）从环氧化反应器中除去流出物流; 其中在液体进料流中溶解的磷酸二氢钾的浓度是磷酸二氢钾在液体进料流中的溶解度极限的至少10％。

公开(公告)号：EP3024578A1

公开(公告)日：2016-06-01

申请号：EP14739185.8

申请日：2014-07-16

Applicant: BASF SE ,  Dow Global Technologies LLC

Inventor： RIEDEL, Dominic ,  TELES, Joaquim Henrique ,  WEGERLE, Ulrike ,  PARVULESCU, Andrei-Nicolae ,  SCHRÖDER, Alexander ,  SPISKE, Luise ,  URBANCZYK, Daniel ,  MÜLLER, Ulrich ,  WITZL, Werner ,  WEIDENBACH, Meinolf

IPC: B01J29/89 ,  B01J37/02 ,  C07D301/12 ,  C07D301/36 ,  C07D303/04 ,  B01J29/70 ,  B01J37/10 ,  B01J37/00 ,  B01J35/00

CPC classification number: C07D301/12 ,  B01J27/1806 ,  B01J27/188 ,  B01J27/232 ,  B01J29/7088 ,  B01J29/86 ,  B01J29/89 ,  B01J31/04 ,  B01J35/002 ,  B01J35/023 ,  B01J37/0045 ,  B01J2229/183 ,  B01J2229/186 ,  B01J2229/37 ,  B01J2229/40 ,  B01J2229/42 ,  C01B39/026 ,  C01B39/08 ,  C01B39/085 ,  C01B39/12 ,  C01B39/48 ,  C07D301/00 ,  C07D301/36 ,  C07D303/04 ,  Y02P20/52

Abstract: A catalytic system containing a titanium zeolite of structure type MWW optionally containing zinc and containing at least one of an inorganic potassium salt and an organic potassium salt is provided. The catalyst system is useful in the preparation of propylene oxide.

Abstract translation: 包括（i）提供包含丙烯，过氧化氢，乙腈，水，任选的丙烷和至少一种溶解的钾盐的液体进料物流; （ii）使（i）中提供的进料流进入包含催化剂的环氧化反应器中，所述催化剂包含结构类型MWW的钛沸石，并使进料流在环氧化反应器中经受环氧化反应条件，获得包含环氧丙烷， 乙腈，水，至少一种钾盐，任选的丙烯和任选的丙烷; （iii）从环氧化反应器中除去流出物流，所述流出物流包含环氧丙烷，乙腈，水，至少一种钾盐，任选的丙烯和任选的丙烷的至少一部分。

公开(公告)号：EP2621935B1

公开(公告)日：2016-05-25

申请号：EP11828228.4

申请日：2011-09-06

Applicant: BASF SE

Inventor： LEUNG, Emi ,  MÜLLER, Ulrich ,  TRUKHAN, Natalia ,  MATTENHEIMER, Hendrik ,  COX, Gerhard ,  BLEI, Stefan

IPC: C07F5/06 ,  B01J20/22

CPC classification number: C07F5/069

公开(公告)号：EP2978528A1

公开(公告)日：2016-02-03

申请号：EP14706827.4

申请日：2014-02-26

Applicant: BASF SE

Inventor： FEYEN, Mathias ,  SCHAACK, Bernd Bastian ,  MÜLLER, Ulrich ,  HEIDEMANN, Thomas ,  WILL, Veronika ,  SENK, Rainer

IPC: B01J37/02 ,  B01J37/18 ,  B01J29/48 ,  C07C2/76 ,  C07C15/04

CPC classification number: C07C2/76 ,  B01J29/405 ,  B01J29/42 ,  B01J29/46 ,  B01J29/48 ,  B01J29/90 ,  B01J33/00 ,  B01J38/10 ,  B01J2229/123 ,  B01J2229/186 ,  B01J2229/32 ,  C07C2527/24 ,  C07C2529/46 ,  C07C2529/48 ,  Y02P20/52 ,  Y02P20/584 ,  C07C15/04

Abstract: The invention concerns a method of producing a passivated catalyst containing a zeolite and at least one active metal, characterized in that the catalyst is held in a fluidized bed where it is passivated with a silicon compound.

公开(公告)号：EP2948520A1

公开(公告)日：2015-12-02

申请号：EP14700507.8

申请日：2014-01-15

Applicant: Wintershall Holding GmbH ,  BASF SE

Inventor： KIMURA, Riichiro ,  MAURER, Stefan ,  PARVULESCU, Andrei-Nicolae ,  SIGGEL, Lorenz ,  MÜLLER, Ulrich ,  FRECHEN, Thomas ,  HINRICHSEN, Bernd

IPC: C09K8/58 ,  A61K8/34 ,  B01J13/16 ,  C09K8/26

CPC classification number: C09K8/58 ,  C09K8/265 ,  E21B43/16

Abstract: The present invention relates to a process for recovering oil from a subterranean formation by injecting both solid particles and water into the formation. An oil-in-water emulsion that is stabilized by solid particles is formed in the pores of the formation. This emulsion is recovered from the subterranean formation.

公开(公告)号：EP2914584A2

公开(公告)日：2015-09-09

申请号：EP13788949.9

申请日：2013-11-05

Applicant: BASF SE

Inventor： VAUTRAVERS, Nicolas ,  TELES, Joaquim Henrique ,  PARVULESCU, Andrei-Nicolae ,  MÜLLER, Ulrich

IPC: C07D309/30 ,  C07D313/00 ,  C07D313/04 ,  C07C51/285 ,  C07C57/03 ,  C01B39/02 ,  C01B39/12 ,  C07B41/12 ,  C07C45/51 ,  C07C47/21

CPC classification number: C01B39/026 ,  C01B39/12 ,  C07B41/12 ,  C07C45/54 ,  C07C51/285 ,  C07D309/30 ,  C07D313/04 ,  C07C57/03 ,  C07C47/21

Abstract: A process for the oxidation of an organic carbonyl compound comprising reacting the organic carbonyl compound, optionally in the presence of a solvent, with hydrogen peroxide in the presence of a catalyst comprising a tin-containing zeolitic material having an MWW-type framework structure.

Abstract translation: 一种有机羰基化合物的氧化方法，包括有机羰基化合物，任选在溶剂存在下，在含有具有MWW型骨架结构的含锡沸石材料的催化剂存在下，与过氧化氢反应。

公开(公告)号：EP2909144A1

公开(公告)日：2015-08-26

申请号：EP13774183.1

申请日：2013-10-09

Applicant: BASF SE

Inventor： MAURER, Stefan ,  ÖZKIRIM, Faruk ,  PARVULESCU, Andrei-Nicolae ,  YANG, Jeff ,  MÜLLER, Ulrich

IPC: C01B39/02 ,  B01J21/00

CPC classification number: C01B39/026 ,  B01J29/40 ,  B01J29/70 ,  B01J29/7007 ,  B01J29/7015 ,  B01J29/7038 ,  B01J35/1014 ,  B01J2229/38 ,  C01B39/36 ,  C01B39/46

Abstract: A process for the post-treatment of a zeolitic material, the process comprising (i) providing a zeolitic material, wherein the framework structure of the zeolitic material comprises YO2 and X2O3, wherein Y is a tetravalent element and X is a trivalent element; (ii) subjecting the zeolitic material provided in (i) to a method comprising (a) treating the zeolitic material with an aqueous solution having a pH of at most 5, (b) treating the zeolitic material obtained from (a) with a liquid aqueous system having a pH in the range of 5.5 to 8 and a temperature of at least 75° C.; wherein in (ii) and after (b), the zeolitic material is optionally subjected to at least one further treatment according to (a) and/or at least one further treatment according to (b).

公开(公告)号：EP2909143A1

公开(公告)日：2015-08-26

申请号：EP13774182.3

申请日：2013-10-09

Applicant: BASF SE

Inventor： PARVULESCU, Andrei-Nicolae ,  Dr. YANG, Jeff, Phill ,  MAURER, Stefan ,  GAAB, Manuela ,  SEIDEL, Karsten ,  GERLACH, Olga ,  MÜLLER, Ulrich

IPC: C01B39/02 ,  B01J21/00

CPC classification number: C01B39/026 ,  B01J29/7007 ,  B01J35/1014 ,  B01J2229/38 ,  C01B39/46

Abstract: A process for the post-treatment of a zeolitic material having a BEA framework structure, the process comprising (i) providing a zeolitic material having a BEA framework structure, wherein the framework structure of the zeolitic material comprises X2O3 and YO2, wherein Y is a tetravalent element and X is a trivalent element and wherein the molar ratio X2O3:YO2 is greater than 0.02:1; (ii) treating the zeolitic material provided in (i) with a liquid solvent system thereby obtaining a zeolitic material having a molar ratio X2O3:YO2 of at most 0.02:1, and at least partially separating the zeolitic material from the liquid solvent system; (iii) treating the zeolitic material obtained from (ii) with a liquid aqueous system having a pH in the range of 5.5 to 8 and a temperature of at least 75° C.

公开(公告)号：EP2909141A1

公开(公告)日：2015-08-26

申请号：EP13773807.6

申请日：2013-10-09

Applicant: BASF SE

Inventor： PARVULESCU, Andrei-Nicolae ,  YANG, Jeff ,  MAURER, Stefan ,  GAAB, Manuela ,  SEIDEL, Karsten ,  GERLACH, Olga ,  MÜLLER, Ulrich

IPC: C01B37/00 ,  C01B39/02 ,  C01B39/12

CPC classification number: C01B37/007 ,  B01J29/7038 ,  C01B39/026 ,  C01B39/12

Abstract: A process for the post-treatment of a zeolitic material having an MWW framework structure, the process comprising (i) providing a zeolitic material having an MWW framework structure, wherein the framework structure of the zeolitic material comprises X
2 O
3 and YO
2 , wherein Y is a tetravalent element and X is a trivalent element and wherein the molar ratio X
2 O
3 : YO
2 is greater than 0.02 : 1; (ii) treating the zeolitic material provided in (i) with a liquid solvent system thereby obtaining a zeolitic material having a molar ratio X
2 O
3 : YO
2 of at most 0.02 : 1, and at least partially separating the zeolitic material from the liquid solvent system; (iii) treating the zeolitic material obtained from (ii) with a liquid aqueous system having a pH in the range of 5.5 to 8 and a temperature of at least 75 °C.

Abstract translation: 一种用于后处理具有MWW骨架结构的沸石材料的方法，所述方法包括（i）提供具有MWW骨架结构的沸石材料，其中所述沸石材料的骨架结构包含X 2 O 3和YO 2，其中 Y是四价元素，X是三价元素，并且其中X 2 O 3 :YO 2的摩尔比大于0.02:1; （ii）用液体溶剂体系处理（i）中提供的沸石材料，由此获得具有至多0.02：1的摩尔比X 2 O 3 :YO 2的沸石材料，并且至少部分地将沸石材料与液体分离 溶剂体系; （iii）用具有5.5至8范围内的pH和至少75℃的温度的液体含水体系处理由（ii）获得的沸石材料。