Abstract:
The invention concerns a method of producing a passivated catalyst containing a zeolite and at least one active metal, characterized in that the catalyst is held in a fluidized bed where it is passivated with a silicon compound.
Abstract:
A method for producing an aromatic hydrocarbon or a mixture of aromatic hydrocarbons from a low molecular hydrocarbon or a mixture of low molecular hydrocarbons, wherein, in a first step, a low molecular hydrocarbon or a mixture of low molecular hydrocarbons is converted to a mixture of aromatic hydrocarbons by way of a catalytic dehydroaromatization reaction with hydrogen as a byproduct, separating the mixture of aromatic hydrocarbons from hydrogen and nonaromatic hydrocarbons in a second step, and, in a third step, feeding the mixture of aromatic hydrocarbons into an aromatic hydrocarbons separation unit, e.g. into the aromatic hydrocarbons separation unit of a catalytic reforming plant, in particular into the aromatic hydrocarbons separation unit of a hydrocarbon steamcracker plant.
Abstract:
The present invention relates to a process for the preparation of a zeolitic material having a CHA-type framework structure comprising YO2 and X2O3, wherein said process comprises the steps of: (1) providing a mixture comprising one or more sources for YO2, one or more sources for X2O3, one or more tetraalkylammonium cation R1R2R3R4N+-containing compounds, and one or more tetraalkylammonium cation R5R6R7R8N+-containing compounds as structure directing agent; (2) crystallizing the mixture obtained in step (1) for obtaining a zeolitic material having a CHA-type framework structure; wherein Y is a tetravalent element and X is a trivalent element, wherein R1, R2, R3, R4, R5, R6, and R7 independently from one another stand for alkyl, and wherein R8 stands for cycloalkyl, as well as to zeolitic materials which may be obtained according to the inventive process and to their use.
Abstract:
The present invention relates to a process for the preparation of a zeolitic material having a CHA-type framework structure comprising YO2 and X2O3, wherein said process comprises the steps of: (1) providing a mixture comprising one or more sources for YO2, one or more sources for X2O3, one or more tetraalkylammonium cation R1R2R3R4N+-containing compounds, and one or more tetraalkylammonium cation R5R6R7R8N+-containing compounds as structure directing agent; (2) crystallizing the mixture obtained in step (1) for obtaining a zeolitic material having a CHA-type framework structure; wherein Y is a tetravalent element and X is a trivalent element, wherein R1, R2, R3, R4, R5, R6, and R7 independently from one another stand for alkyl, and wherein R8 stands for cycloalkyl, as well as to zeolitic materials which may be obtained according to the inventive process and to their use.
Abstract translation:本发明涉及一种用于具有CHA型骨架结构包含YO 2和X 2 O 3的沸石材料的制备方法,worin所述方法包括以下步骤:(1)提供包括用于YO 2的一个或多个源,一种或混合物 多个源为X 2 O 3,一种或多种四烷基铵阳离子R.sup.1R.sup.2R.sup.3R.sup.4N.sup +含化合物,和一种或多种四烷基铵阳离子R5R6R7R8N +含化合物作为结构导向剂; (2)结晶化获得具有CHA骨架型结构的沸石材料在步骤(1)中获得的混合物; worin Y是四价元素,X是三价元素,worin R1,R2,R3,R4,R5,R6,和R7彼此独立地立场烷基,和worin R8代表的环烷基,以及为沸石材料,其 可以得到gemäß到本发明的方法以及它们的用途。
Abstract:
The present invention relates to a method for the preparation of a treated zeolitic material having a BEA framework structure comprising the steps of: (i) providing a zeolitic material having a BEA framework structure, wherein the BEA framework structure comprises YO2 and X2O3, wherein Y is a tetravalent element, and X is a trivalent element, and wherein the zeolitic material having a BEA framework structure is obtainable and/or obtained from an organotemplate-free synthetic process; (ii) calcining the zeolitic material provided in step (i) at a temperature of 650° C. or more; and (iii) treating the calcined zeolitic material obtained from step (ii) with an aqueous solution having a pH of 5 or less, as well as to zeolitic materials per se preferably obtainable according to the inventive method and to their use, and to a process for converting oxygenates to olefins employing the inventive zeolitic materials.