摘要:
A copper chloride etching waste liquor is treated by a process comprising exposing the etching waste liquor to an atmosphere of 400 to 1,200 °C to generate cupric oxide and hydrogen chloride, separating and collecting the cupric oxide, dissolving the hydrogen chloride into water, and collecting the resulting hydrochloric acid, and an apparatus suitable for the process comprises a concentrating tower for concentrating the etching waste liquor, a roasting furnace for exposing the concentrate to a high-temperature atmosphere to generate a cupric oxide and a gas mixture containing hydrogen chloride, a cyclone, cooling tower and electrostatic precipitator for collecting the cupric oxide and for feeding the remaining gas mixture to the concentrating tower, a hydrochloric acid collecting tower for collecting hydrochloric acid from a gas mixture discharged from the concentrating tower, and a gas cleaning tower for neutralizing the exhaust gas discharged from the hydrochloric acid collecting tower.
摘要:
A solution containing iron chloride and manganese chloride, whose phosphorus content is not higher than 0.007 wt.% with respect to the total content of iron and manganese. A method for producing the said solution comprises the steps of dissolving manganese containing raw material in hydrochloric solution; oxidizing the solution; adjusting the pH of the solution to 2.5 ∼ 4.5; separating the insolubles from the solution. This solution can be utilized to produce a mixed powder of an iron oxide and a manganese oxide. And the mixed powder is useful for producing a high-quality soft ferrite.
摘要:
In a method for producing powdered iron oxide by oxidizing roasting an iron chloride solution, the pH-value of the crude iron chloride solution is adjusted to 2,5 to 4,5, the solution is subjected to a mechanical treatment in order to obtain a solution whose pH-value is not less than 1,5 and which contains insoluble Fe³⁺compounds in an amount of 0,01 to 0,1 % by weight, being calculated as Fe. The insolubles are separated from the solution and the resulting filtrate or purified solution is then roasted and oxidized in order to produce powdered iron oxide having a P content of not more than 0,005 % by weight.
摘要:
The present invention relates to a method for removing a silicic compound from the waste liquor of steel pickling. A filtering method using a filter fabric or biscuit plate is impractical as an industrial method because the filtering medium becomes clogged. The present invention is characterized by an adsorption method in which silicic compounds are adsorbed on adsorbent substrates (3) in an optional part of an adsorption bed. The present invention is characterized in that the waste liquor is passed through the adsorption bed for a two-month period or longer without clogging occurring.