摘要:
In the manufacturing method of hexafluorophosphate (MPF 6 : M = Li, Na, K, Rb, Cs, NH 4 , and Ag) of the present invention, at least a H x PO y F z aqueous solution, a hydrofluoric acid aqueous solution, and MF · r (HF) are used as raw materials (wherein, r ‰¥ 0, 0 ‰¤ x ‰¤ 3, 0 ‰¤ y ‰¤ 4, and 0 ‰¤ z ‰¤ 6). According to the above description, a manufacturing method of hexafluorophosphate can be provided which is capable of manufacturing hexafluorophosphate (GPF 6 : G = Li, Na, K, Rb, Cs, NH 4 , and Ag) at a low cost in which the raw materials can be easily obtained, the control of the reaction is possible, and the workability is excellent.
摘要:
A solid solution material of rare earth element fluoride (a polycrystl and/or a single crystal), characterized in that it comprises a combination of a plurality of rare earth element fluorides exhibiting phase transition and having different ionic radii and has no phase transition; a rare earth element fluoride solid solution material (a polycrystl and/or a single crystal), characterized in that it is represented by (REyRE'1-y)F3 (0.0000
摘要:
The invention is directed to a carbon material dispersion, including: a fluorinated carbon material having a fluorinated surface formed by bringing a treatment gas with a fluorine concentration of 0.01 to 100 vol.-% into contact with a carbon material under conditions at 150 to 600 °C; and a dispersion medium in which the fluorinated carbon material is dispersed.
摘要:
An object of the invention is to provide a process for preparing a fluorine compound, which can easily provide the objective fluorine compound using an oxygen-containing compound as a raw material without forming water as impurities as a by-product. The process for preparing a fluorine compound according to the invention includes reacting an oxygen-containing compound, which is at least one kind selected from the group consisting of oxides, hydroxides, hydrates, carbonic acid compounds, hydrogencarbonic acid compounds, boric acid compounds, sulfuric acid compounds, sulfurous acid compounds, phosphorous acid compounds and phosphoric acid compounds of at least any one kind selected from the group consisting of metal elements, H, B, C, N, Si, P, S, As, Se, Te and halogens, at least with carbonyl fluoride to form at least a fluorine compound and carbon dioxide without forming water as a by-product.
摘要:
An object of the present invention is to provide a method of manufacturing phosphorus pentafluoride and hexafluorophosphate, that can suppress the manufacturing cost and also can manufacture high-quality phosphorus pentafluoride from an inexpensive and low-quality raw material. The present invention relates to a method of manufacturing phosphorus pentafluoride, wherein a raw material which comprises at least phosphorus atoms and fluorine atoms is brought into contact with a carrier gas, thereby a phosphorus pentafluoride is extracted and separated into the carrier gas. The present invention relates to a method of manufacturing hexafluorophosphate, comprising the step of: reacting fluoride with phosphorus pentafluoride obtained by the method of manufacturing phosphorus pentafluoride according to the following chemical reaction scheme, €ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒsPF 5 + AF s †’ A(PF 6 ) s wherein s is in the range of 1 ‰¤ s ‰¤ 3, and A is at least one member selected from the group consisting of Li, Na, K, Rb, Cs, NH 4 , Ag, Mg, Ca, Ba, Zn, Cu, Pb, Al and Fe.
摘要:
The invention aims at providing, without using an expensive and rare material, platinum black which is effectively inhibited from being poisoned with CO, H2S, SO4, or HCHO and a method for fluorination of platinum black. The platinum black is characterized by fluorine adsorbed on the surface thereof. The method for fluorination of platinum black is characterized by allowing platinum black to stand in an inert gas/fluorine mixed gas atmosphere in a chamber under a reduced pressure to make fluorine adsorbed on the surface of the platinum black.