公开(公告)号：EP2225030A1

公开(公告)日：2010-09-08

申请号：EP08864424.0

申请日：2008-12-10

Applicant: BASF SE

Inventor： KUBANEK, Petr ,  MÄGERLEIN, Wolfgang ,  SCHWAB, Ekkehard ,  MELDER, Johann-Peter ,  JULIUS, Manfred

IPC: B01J23/835 ,  B01J23/843 ,  B01J37/03 ,  B01J37/18 ,  C07C209/16 ,  C07C213/02 ,  C07D295/023

CPC classification number: B01J23/835 ,  B01J23/002 ,  B01J23/8435 ,  B01J23/8437 ,  B01J37/03 ,  B01J37/18 ,  B01J2523/00 ,  C07C209/16 ,  C07C213/02 ,  C07D295/023 ,  Y02P20/582 ,  B01J2523/17 ,  B01J2523/44 ,  B01J2523/48 ,  B01J2523/842 ,  B01J2523/845 ,  B01J2523/847 ,  B01J2523/53 ,  B01J2523/43 ,  C07C217/08

Abstract: The invention relates to a method for producing an amine by reacting a primary or secondary alcohol, aldehyde and/or ketone with hydrogen and a nitrogen compound, selected from the group including ammonia, primary and secondary amines, in the presence of a zirconium dioxide-containing, copper-containing and nickel-containing catalyst, the catalytically active mass of the catalyst prior to its reduction with hydrogen containing oxygen-containing compounds of zirconium, copper, nickel, 0.2 to 40% by weight of oxygen-containing compounds of cobalt, calculated as CoO, 0.1 to 5% by weight of oxygen-containing compounds of iron, calculated as Fe2O3, and 0.1 to 5% by weight of oxygen-containing compounds of lead, tin, bismuth and/or antimony, each calculated as PbO, SnO, Bi2O3 or Sb2O3. The invention also relates to catalysts of the above type.

Abstract translation: 本发明涉及一种通过使伯或仲醇，醛和/或酮与氢和选自氨，伯胺和仲胺的氮化合物在二氧化锆 - 二氧化锆存在下反应来制备胺的方法， 含铜含镍含镍催化剂，催化剂的催化活性物质在用含氢的含氧化合物锆，铜，镍，0.2至40重量％的含氧化合物钴， （以CoO计），0.1至5重量％的以Fe 2 O 3计的铁的含氧化合物和0.1至5重量％的铅，锡，铋和/或锑的含氧化合物，各自以PbO计算， SnO，Bi2O3或Sb2O3。 本发明还涉及上述类型的催化剂。

公开(公告)号：EP2506965B1

公开(公告)日：2016-11-09

申请号：EP10784513.3

申请日：2010-11-29

Applicant: BASF SE

Inventor： KUBANEK, Petr ,  MÄGERLEIN, Wolfgang ,  MELDER, Johann-Peter ,  HEIDEMANN, Thomas

IPC: B01J37/03 ,  B01J37/18 ,  B01J23/83 ,  B01J23/835 ,  C07C209/26 ,  C07C213/02 ,  C07D295/088 ,  C07C209/16

CPC classification number: B01J23/83 ,  B01J23/835 ,  B01J37/031 ,  B01J37/18 ,  C07C209/16 ,  C07C209/26 ,  C07C213/02 ,  C07D295/088 ,  C07C217/08

公开(公告)号：EP2432815B1

公开(公告)日：2013-10-23

申请号：EP10723038.5

申请日：2010-05-19

Applicant: BASF SE

Inventor： ELING, Berend ,  GÖTTKE, Stephan ,  BUYLINCKX, Ben ,  MÄGERLEIN, Wolfgang

IPC: C08G18/32 ,  C08G18/48 ,  C08G18/50 ,  C09D175/02 ,  C08G18/10

CPC classification number: C08G18/4866 ,  C08G18/10 ,  C08G18/324 ,  C08G18/4825 ,  C08G18/5024 ,  C09D175/02 ,  C08G18/6618 ,  C08G18/6685

公开(公告)号：EP2513037A1

公开(公告)日：2012-10-24

申请号：EP10787796.1

申请日：2010-12-13

Applicant: BASF SE

Inventor： MÄGERLEIN, Wolfgang ,  MELDER, Johann-Peter ,  PASTRE, Jörg ,  EBERHARDT, Jan ,  KRUG, Thomas ,  KREITSCHMANN, Mirko

IPC: C07C209/28 ,  C07C215/10 ,  C07C215/12

CPC classification number: C07C215/12 ,  C07C213/08

Abstract: The invention relates to a method for producing ethanolamines by means of reacting glycol aldehyde with monoethanolamine and/or diethanolamine in the presence of a catalyst.

公开(公告)号：EP2225027B1

公开(公告)日：2012-05-23

申请号：EP08863967.9

申请日：2008-12-10

Applicant: BASF SE

Inventor： KUBANEK, Petr ,  MÄGERLEIN, Wolfgang ,  SCHWAB, Ekkehard ,  MELDER, Johann-Peter ,  JULIUS, Manfred

IPC: B01J23/76 ,  B01J23/835 ,  B01J23/843 ,  B01J23/883 ,  B01J37/03 ,  B01J37/18 ,  C07C209/16 ,  C07C213/02 ,  C07D295/023

CPC classification number: B01J23/883 ,  B01J23/002 ,  B01J23/76 ,  B01J23/835 ,  B01J23/8435 ,  B01J23/8437 ,  B01J37/03 ,  B01J37/18 ,  B01J2523/00 ,  C07C209/16 ,  C07C213/02 ,  C07D295/023 ,  Y02P20/582 ,  B01J2523/44 ,  B01J2523/48 ,  B01J2523/842 ,  B01J2523/847 ,  B01J2523/68 ,  B01J2523/51 ,  B01J2523/43 ,  B01J2523/53 ,  B01J2523/54

Abstract: The invention relates to a method for producing an amine by reacting a primary or secondary alcohol, aldehyde and/or ketone with hydrogen and a nitrogen compound, selected from the group including ammonia, primary and secondary amines, in the presence of a zirconium dioxide-containing and nickel-containing catalyst, the catalytically active mass of the catalyst prior to its reduction with hydrogen containing oxygen-containing compounds of zirconium, nickel and iron and 0.2 to 5.5% by weight of oxygen-containing compounds of tin, lead, bismuth, molybdenum, antimony and/or phosphorous, each calculated as SnO, PbO, Bi2O3, MoO3, Sb2O3 or H3PO4. The invention also relates to catalysts of the above type.

公开(公告)号：EP2225031A1

公开(公告)日：2010-09-08

申请号：EP08864035.4

申请日：2008-12-10

Applicant: BASF SE

Inventor： KUBANEK, Petr ,  MÄGERLEIN, Wolfgang ,  SCHWAB, Ekkehard ,  MELDER, Johann-Peter ,  JULIUS, Manfred

IPC: B01J23/84 ,  B01J27/188 ,  B01J37/03 ,  B01J37/18 ,  C07C209/16 ,  C07C213/02 ,  C07D295/023

CPC classification number: B01J27/188 ,  B01J23/002 ,  B01J23/84 ,  B01J37/03 ,  B01J37/18 ,  B01J2523/00 ,  C07C209/16 ,  C07C213/02 ,  C07D295/023 ,  B01J2523/17 ,  B01J2523/48 ,  B01J2523/51 ,  B01J2523/69 ,  B01J2523/845 ,  B01J2523/847 ,  C07C217/08

Abstract: Disclosed is a method for producing an amine by reacting a primary or secondary alcohol, aldehyde, and/or ketone with hydrogen and a nitrogen compound selected from among the group comprising ammonia and primary and secondary amines in the presence of a catalyst containing zirconium dioxide, copper, and nickel. Before being reduced with hydrogen, the catalytically active material of the catalyst contains oxygen-containing compounds of zirconium, copper, and nickel, 1.0 to 5.0 percent by weight of oxygen-containing compounds of cobalt, calculated as CoO, and 0.2 to 5.0 percent by weight of a polyoxometallate. Also disclosed are catalysts as defined above.

公开(公告)号：EP2506966B1

公开(公告)日：2017-08-16

申请号：EP10784512.5

申请日：2010-11-29

Applicant: BASF SE

Inventor： KUBANEK, Petr ,  MÄGERLEIN, Wolfgang ,  MELDER, Johann-Peter ,  HEIDEMANN, Thomas

IPC: B01J37/03 ,  B01J37/18 ,  B01J23/835 ,  C07C213/02 ,  C07D295/03 ,  C07D295/027

CPC classification number: C07C213/02 ,  B01J23/835 ,  B01J37/031 ,  B01J37/035 ,  B01J37/18 ,  C07D295/027 ,  C07D295/03 ,  Y02P20/582 ,  C07C217/08

公开(公告)号：EP2688861B1

公开(公告)日：2016-08-17

申请号：EP12710259.8

申请日：2012-03-21

Applicant: BASF SE

Inventor： WIGBERS, Christof, Wilhelm ,  MÜLLER, Christoph ,  MÄGERLEIN, Wolfgang ,  KUBANEK, Petr ,  HEIDEMANN, Thomas ,  MELDER, Johann-Peter ,  KRUG, Thomas ,  BEY, Oliver

IPC: C07C209/48

CPC classification number: C07C209/48 ,  C07C211/11 ,  C07C211/36

公开(公告)号：EP2225029B1

公开(公告)日：2016-08-03

申请号：EP08863552.9

申请日：2008-12-10

Applicant: BASF SE

Inventor： KUBANEK, Petr ,  MÄGERLEIN, Wolfgang ,  SCHWAB, Ekkehard ,  MELDER, Johann-Peter ,  JULIUS, Manfred

IPC: B01J23/835 ,  B01J37/03 ,  B01J37/18 ,  C07C213/02 ,  C07D295/023 ,  C07C209/16

CPC classification number: B01J23/835 ,  B01J23/002 ,  B01J37/03 ,  B01J37/18 ,  B01J2523/00 ,  C07C209/16 ,  C07C213/02 ,  C07D295/02 ,  C07D295/06 ,  C07C217/08

公开(公告)号：EP2782898A1

公开(公告)日：2014-10-01

申请号：EP12788179.5

申请日：2012-11-13

Applicant: BASF SE

Inventor： ASPRION, Norbert ,  JULIUS, Manfred ,  BEY, Oliver ,  WERLAND, Stefanie ,  STEIN, Frank ,  KUMMER, Matthias ,  MÄGERLEIN, Wolfgang ,  MELDER, Johann-Peter ,  HUYGHE, Kevin ,  MOORS, Maarten

IPC: C07C209/16 ,  C07C211/05 ,  C07C211/06

CPC classification number: C07C209/16 ,  C07C29/145 ,  C07C31/10 ,  C07C211/05 ,  C07C211/06

Abstract: Method for producing ethylamines and monoisopropylamine (MIPA), in which bioethanol is reacted with ammonia in the presence of hydrogen and a heterogeneous catalyst to form ethylamines, wherein the bioethanol contains sulphur and/or sulphur-containing compounds of ≥ 0.1 ppm by weight (calculated S), and then in the presence of the same catalyst, isopropanol is reacted with ammonia in the presence of hydrogen to form MIPA.