公开(公告)号：EP2513037B1

公开(公告)日：2014-04-02

申请号：EP10787796.1

申请日：2010-12-13

Applicant: BASF SE

Inventor： MÄGERLEIN, Wolfgang ,  MELDER, Johann-Peter ,  PASTRE, Jörg ,  EBERHARDT, Jan ,  KRUG, Thomas ,  KREITSCHMANN, Mirko

IPC: C07C209/28 ,  C07C215/10 ,  C07C215/12

CPC classification number: C07C215/12 ,  C07C213/08

公开(公告)号：EP2506965A1

公开(公告)日：2012-10-10

申请号：EP10784513.3

申请日：2010-11-29

Applicant: BASF SE

Inventor： KUBANEK, Petr ,  MÄGERLEIN, Wolfgang ,  MELDER, Johann-Peter ,  HEIDEMANN, Thomas

IPC: B01J21/06 ,  C07C209/16 ,  C07C211/10

CPC classification number: B01J23/83 ,  B01J23/835 ,  B01J37/031 ,  B01J37/18 ,  C07C209/16 ,  C07C209/26 ,  C07C213/02 ,  C07D295/088 ,  C07C217/08

Abstract: The invention relates to a method for producing an amine by reacting a primary or secondary alcohol, aldehyde and/or ketone with hydrogen and a nitrogen compound, selected from the group containing ammonia and primary and secondary amines in the presence of a supported catalyst containing copper, nickel and cobalt. According to the invention, prior to the reduction of the catalyst using hydrogen, the catalytically active mass of said catalyst contains oxygen-containing compounds of aluminium, copper, nickel, cobalt and tin and between 0.2 and 5.0 wt. % of oxygen-containing compounds of yttrium, lanthanum, cerium and/or hafnium, each of which is calculated as Y
2 O
3, La
2 O
3, Ce
2 O
3 and Hf
2 O
3. The invention also relates to catalysts defined as above.

公开(公告)号：EP2225027A1

公开(公告)日：2010-09-08

申请号：EP08863967.9

申请日：2008-12-10

Applicant: BASF SE

Inventor： KUBANEK, Petr ,  MÄGERLEIN, Wolfgang ,  SCHWAB, Ekkehard ,  MELDER, Johann-Peter ,  JULIUS, Manfred

IPC: B01J23/76 ,  B01J23/835 ,  B01J23/843 ,  B01J23/883 ,  B01J37/03 ,  B01J37/18 ,  C07C209/16 ,  C07C213/02 ,  C07D295/023

CPC classification number: B01J23/883 ,  B01J23/002 ,  B01J23/76 ,  B01J23/835 ,  B01J23/8435 ,  B01J23/8437 ,  B01J37/03 ,  B01J37/18 ,  B01J2523/00 ,  C07C209/16 ,  C07C213/02 ,  C07D295/023 ,  Y02P20/582 ,  B01J2523/44 ,  B01J2523/48 ,  B01J2523/842 ,  B01J2523/847 ,  B01J2523/68 ,  B01J2523/51 ,  B01J2523/43 ,  B01J2523/53 ,  B01J2523/54

Abstract: The invention relates to a method for producing an amine by reacting a primary or secondary alcohol, aldehyde and/or ketone with hydrogen and a nitrogen compound, selected from the group including ammonia, primary and secondary amines, in the presence of a zirconium dioxide-containing and nickel-containing catalyst, the catalytically active mass of the catalyst prior to its reduction with hydrogen containing oxygen-containing compounds of zirconium, nickel and iron and 0.2 to 5.5% by weight of oxygen-containing compounds of tin, lead, bismuth, molybdenum, antimony and/or phosphorous, each calculated as SnO, PbO, Bi2O3, MoO3, Sb2O3 or H3PO4. The invention also relates to catalysts of the above type.

Abstract translation: 本发明涉及一种通过使伯或仲醇，醛和/或酮与氢和选自氨，伯胺和仲胺的氮化合物在二氧化锆 - 二氧化锆存在下反应来制备胺的方法， 含镍和镍的催化剂，催化剂的催化活性物质在用含氢的含锆化合物锆和镍和铁以及0.2-5.5重量％的含锡，铅，铋， 钼，锑和/或磷，各自计算为SnO，PbO，Bi 2 O 3，MoO 3，Sb 2 O 3或H 3 PO 4。 本发明还涉及上述类型的催化剂。

公开(公告)号：EP2513036B1

公开(公告)日：2019-04-17

申请号：EP10787811.8

申请日：2010-12-14

Applicant: BASF SE

Inventor： MÄGERLEIN, Wolfgang ,  MELDER, Johann-Peter ,  PASTRE, Jörg ,  EBERHARDT, Jan ,  KRUG, Thomas ,  KREITSCHMANN, Mirko

IPC: C07C209/26 ,  C07C213/00 ,  C07C211/10 ,  C07C215/08

公开(公告)号：EP2782898B1

公开(公告)日：2015-10-21

申请号：EP12788179.5

申请日：2012-11-13

Applicant: BASF SE

Inventor： ASPRION, Norbert ,  JULIUS, Manfred ,  BEY, Oliver ,  WERLAND, Stefanie ,  STEIN, Frank ,  KUMMER, Matthias ,  MÄGERLEIN, Wolfgang ,  MELDER, Johann-Peter ,  HUYGHE, Kevin ,  MOORS, Maarten

IPC: C07C209/16 ,  C07C211/05 ,  C07C211/06 ,  C07C29/145

CPC classification number: C07C209/16 ,  C07C29/145 ,  C07C31/10 ,  C07C211/05 ,  C07C211/06

公开(公告)号：EP2513036A1

公开(公告)日：2012-10-24

申请号：EP10787811.8

申请日：2010-12-14

Applicant: BASF SE

Inventor： MÄGERLEIN, Wolfgang ,  MELDER, Johann-Peter ,  PASTRE, Jörg ,  EBERHARDT, Jan ,  KRUG, Thomas ,  KREITSCHMANN, Mirko

IPC: C07C209/26 ,  C07C213/02 ,  C07C211/10 ,  C07C215/08

CPC classification number: C07C209/26 ,  C07C213/00 ,  C07C215/08 ,  C07C211/10

Abstract: The present invention relates to a method for reacting glycolaldehyde with an aminizing agent in the presence of hydrogen and a catalyst, the catalyst being activated by reducing a catalyst precursor or by reducing a passivated catalyst, characterized in that the reacting takes place in the presence of a solvent and that the glycolaldehyde is brought into contact with the activated catalyst.

公开(公告)号：EP2225030B1

公开(公告)日：2012-04-18

申请号：EP08864424.0

申请日：2008-12-10

Applicant: BASF SE

Inventor： KUBANEK, Petr ,  MÄGERLEIN, Wolfgang ,  SCHWAB, Ekkehard ,  MELDER, Johann-Peter ,  JULIUS, Manfred

IPC: B01J23/835 ,  B01J23/843 ,  B01J37/03 ,  B01J37/18 ,  C07C209/16 ,  C07C213/02 ,  C07D295/023

CPC classification number: B01J23/835 ,  B01J23/002 ,  B01J23/8435 ,  B01J23/8437 ,  B01J37/03 ,  B01J37/18 ,  B01J2523/00 ,  C07C209/16 ,  C07C213/02 ,  C07D295/023 ,  Y02P20/582 ,  B01J2523/17 ,  B01J2523/44 ,  B01J2523/48 ,  B01J2523/842 ,  B01J2523/845 ,  B01J2523/847 ,  B01J2523/53 ,  B01J2523/43 ,  C07C217/08

Abstract: The invention relates to a method for producing an amine by reacting a primary or secondary alcohol, aldehyde and/or ketone with hydrogen and a nitrogen compound, selected from the group including ammonia, primary and secondary amines, in the presence of a zirconium dioxide-containing, copper-containing and nickel-containing catalyst, the catalytically active mass of the catalyst prior to its reduction with hydrogen containing oxygen-containing compounds of zirconium, copper, nickel, 0.2 to 40% by weight of oxygen-containing compounds of cobalt, calculated as CoO, 0.1 to 5% by weight of oxygen-containing compounds of iron, calculated as Fe2O3, and 0.1 to 5% by weight of oxygen-containing compounds of lead, tin, bismuth and/or antimony, each calculated as PbO, SnO, Bi2O3 or Sb2O3. The invention also relates to catalysts of the above type.

公开(公告)号：EP3186221A1

公开(公告)日：2017-07-05

申请号：EP15757468.2

申请日：2015-08-25

Applicant: BASF SE

Inventor： WIGBERS, Christof, Wilhelm ,  MÄGERLEIN, Wolfgang ,  KRUG, Thomas ,  MELDER, Johann-Peter ,  HEIDEMANN, Thomas ,  STEIN, Bernd

IPC: C07C209/48 ,  C07C211/11 ,  C07C211/09

CPC classification number: C07C209/48 ,  B01J23/75 ,  B01J23/78 ,  B01J35/0006 ,  B01J35/002 ,  B01J37/18 ,  C07C2523/75 ,  Y02P20/582 ,  C07C211/11 ,  C07C211/09 ,  C07C211/12 ,  C07C211/18

Abstract: The invention relates to a method for producing primary amines, characterized in that at least one nitrile is hydrogenated in a device (V1) in the presence of a cobalt-based full contact catalyst while obtaining at least one primary amine, at least one compound (I) being added repeatedly or continuously to the device (V1) and said compound (I) comprising at least one component selected from the group including alkali metal, alkaline-earth metal or rare earth metal.

Abstract translation: 本发明涉及一种生产伯胺的方法，其特征在于至少一种腈在钴基全接触催化剂存在下在装置（V1）中氢化，同时获得至少一种伯胺，至少一种化合物（ I）反复或连续添加到装置（V1）中并且所述化合物（I）包含至少一种选自碱金属，碱土金属或稀土金属的组分。

公开(公告)号：EP2688861A1

公开(公告)日：2014-01-29

申请号：EP12710259.8

申请日：2012-03-21

Applicant: BASF SE

Inventor： WIGBERS, Christof, Wilhelm ,  MÜLLER, Christoph ,  MÄGERLEIN, Wolfgang ,  KUBANEK, Petr ,  HEIDEMANN, Thomas ,  MELDER, Johann-Peter ,  KRUG, Thomas ,  BEY, Oliver

IPC: C07C209/48

CPC classification number: C07C209/48 ,  C07C211/11 ,  C07C211/36

Abstract: The invention relates to a method for hydrogenating nitriles with hydrogen in the presence of a catalyst in a reactor, said catalyst being arranged in a fixed bed. The invention is characterized in that the cross-sectional load in the reactor ranges from 5 kg/(m
2 s) to 50 kg/(m
2 s). The invention further relates to a method for producing secondary products of isophorondiamine (IPDA) or N,N-dimethylaminopropylamine (DMAPA) from amines produced according to the invention.

公开(公告)号：EP2234717A1

公开(公告)日：2010-10-06

申请号：EP08865518.8

申请日：2008-12-10

Applicant: BASF SE

Inventor： KUBANEK, Petr ,  MÄGERLEIN, Wolfgang ,  SCHWAB, Ekkehard ,  MELDER, Johann-Peter ,  JULIUS, Manfred

IPC: B01J23/835 ,  B01J23/84 ,  B01J23/843 ,  B01J23/847 ,  B01J37/03 ,  B01J37/18 ,  B01J23/825 ,  C07C209/16 ,  C07C213/02 ,  C07D295/023

CPC classification number: B01J27/1853 ,  B01J23/002 ,  B01J23/755 ,  B01J23/825 ,  B01J23/835 ,  B01J23/84 ,  B01J23/8435 ,  B01J23/8474 ,  B01J27/055 ,  B01J37/03 ,  B01J37/18 ,  B01J2523/00 ,  C07C209/16 ,  C07C209/78 ,  C07C213/02 ,  C07D295/023 ,  Y02P20/582 ,  B01J2523/17 ,  B01J2523/48 ,  B01J2523/56 ,  B01J2523/845 ,  B01J2523/847 ,  B01J2523/44 ,  B01J2523/53 ,  C07C211/10 ,  C07C217/08

Abstract: Disclosed is a method for producing an amine by reacting a primary or secondary alcohol, aldehyde, and/or ketone with hydrogen and a nitrogen compound selected from among the group comprising ammonia and primary and secondary amines in the presence of a catalyst containing zirconium dioxide, copper, and nickel. Before being reduced with hydrogen, the catalytically active material of the catalyst contains oxygen-containing compounds of zirconium, copper, and nickel, 1.0 to 5.0 percent by weight of oxygen-containing compounds of cobalt, calculated as CoO, and 0.2 to 5.0 percent by weight of oxygen-containing compounds of vanadium, niobium, sulfur, phosphorus, gallium, boron, tungsten, lead, and/or antimony, which are respectively calculated as V2O5, Nb2O5, H2SO4, H3PO4, Ga2O3, B2O3, WO3, PbO, or Sb2O3. Also disclosed are catalysts as defined above.

Abstract translation: 本发明公开了一种通过使伯或仲醇，醛和/或酮与氢和选自氨和伯胺和仲胺的氮化合物在含有二氧化锆的催化剂存在下反应来制备胺的方法， 铜和镍。 在用氢气还原之前，催化剂的催化活性材料含有锆，铜和镍的含氧化合物，以CoO计为1.0-5.0重量％的含钴含氧化合物，以及0.2-5.0重量％ 钒，铌，硫，磷，镓，硼，钨，铅和/或锑的含氧化合物的重量分别计算为V2O5，Nb2O5，H2SO4，H3PO4，Ga2O3，B2O3，WO3，PbO或 三氧化二锑。 还公开了如上定义的催化剂。