公开(公告)号：EP3174634A1

公开(公告)日：2017-06-07

申请号：EP15738955.2

申请日：2015-07-24

申请人： Treibacher Industrie AG

发明人： HENSGEN, Lars ,  SCHERMANZ, Karl ,  STÖWE, Klaus ,  WOLF, Viktor

IPC分类号： B01J23/18 ,  B01J35/00 ,  B01J37/03 ,  B01J37/08 ,  B01J37/10 ,  B01J23/843

CPC分类号： B01J23/8437 ,  B01D53/8687 ,  B01D53/944 ,  B01D2255/2022 ,  B01D2255/2042 ,  B01D2255/2045 ,  B01D2255/2047 ,  B01D2255/206 ,  B01D2255/2061 ,  B01D2255/2063 ,  B01D2255/2065 ,  B01D2255/2066 ,  B01D2255/2068 ,  B01D2255/20715 ,  B01D2255/20738 ,  B01D2255/2092 ,  B01D2255/2096 ,  B01D2255/2098 ,  B01D2255/40 ,  B01D2255/915 ,  B01D2258/0283 ,  B01J23/18 ,  B01J23/8435 ,  B01J35/002 ,  B01J37/036 ,  B01J37/04 ,  B01J37/08 ,  B01J37/082 ,  B01J37/10 ,  B01J2523/00 ,  F01N3/035 ,  B01J2523/13 ,  B01J2523/3712 ,  B01J2523/54 ,  B01J2523/12 ,  B01J2523/24 ,  B01J2523/3718 ,  B01J2523/842

摘要： wherein M stands for one or more elements from the group of alkaline metals, except sodium, N is Bi and/or Sb, D is present, or is not present, and if present is selected from one or more of Mg, Ca, Sr, Ba; Y, La, Pr, Nd, Sm, Gd, Er; Fe, Zr, Nb, Al; a is a number within the range of 0

摘要翻译： 式（I）Ce1-ab-cNaMbDcOx的组合物，其中M代表来自除钠之外的碱金属组中的一种或多种元素，N是Bi和/或Sb，D是存在或不存在，并且如果 存在选自Mg，Ca，Sr，Ba中的一种或多种; Y，La，Pr，Nd，Sm，Gd，Er; Fe，Zr，Nb，Al; a是0

公开(公告)号：EP3024572A1

公开(公告)日：2016-06-01

申请号：EP14739306.0

申请日：2014-06-17

申请人： Clariant Corporation

发明人： SHEN, Wenqin ,  PETZOLD, Franz G. ,  LIBBY, Karen ,  TURBEVILLE, Wayne

IPC分类号： B01J21/06 ,  B01J35/10 ,  B01J35/00 ,  B01J37/03 ,  B01J37/08 ,  B01J23/34 ,  B01J23/889 ,  B01J23/755 ,  B01J23/843 ,  B01J23/46 ,  B01J23/72 ,  C12P19/02 ,  C07C29/149

CPC分类号： B01J23/8892 ,  B01J21/066 ,  B01J23/34 ,  B01J23/462 ,  B01J23/6562 ,  B01J23/72 ,  B01J23/755 ,  B01J23/8435 ,  B01J35/002 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1038 ,  B01J37/031 ,  B01J37/08 ,  C07C29/00 ,  C07C29/132 ,  C07C29/149 ,  C07C29/172 ,  C07C29/60 ,  C12P19/02 ,  Y02P20/52 ,  C07C31/202 ,  C07C31/205 ,  C07C31/225 ,  C07C31/26

摘要： The present disclosure relates generally to catalyst support materials, catalysts and methods for using them, such as methods for converting sugars, sugar alcohols, glycerol, and bio-renewable organic acids to commercially-valuable chemicals and intermediates. One aspect of the invention is catalyst support material including ZrO
2 and one or more oxides of manganese (MnO
x ), the catalyst support material being at least about 50 wt% ZrO
2 and MnO
x . In certain embodiments, the weight ratio of ZrO
2 to MnO
x is within the range of about 1:1 to about 30:1; and/or the catalyst support material is substantially free of any binder, extrusion aid or additional stabilizing agent

摘要翻译： 本公开一般涉及催化剂载体材料，催化剂和使用它们的方法，例如将糖，糖醇，甘油和生物可再生有机酸转化为商业上有价值的化学品和中间体的方法。 本发明的一个方面是包含ZrO 2和一种或多种锰的氧化物（MnO x）的催化剂载体材料，所述催化剂载体材料为至少约50重量％的ZrO 2和MnO x。 在某些实施方案中，ZrO 2与MnO x的重量比在约1：1至约30：1的范围内; 和/或催化剂载体材料基本上不含任何粘合剂，挤出助剂或另外的稳定剂

公开(公告)号：EP2961525A1

公开(公告)日：2016-01-06

申请号：EP14709007.0

申请日：2014-02-13

申请人： Clariant Corporation

发明人： MILLER, Aaron ,  RAGHUNATH, Malati ,  SOKOLOVSKII, Valery ,  LUGMAIR, Claus ,  VOLPE, Anthony ,  SHEN, Wenqin ,  TURBEVILLE, Wayne

IPC分类号： B01J21/06 ,  B01J23/843 ,  B01J23/89 ,  B01J23/835 ,  B01J23/83 ,  B01J23/889 ,  B01J21/18 ,  B01J37/02

CPC分类号： B01J23/8993 ,  B01J21/066 ,  B01J21/18 ,  B01J21/185 ,  B01J23/755 ,  B01J23/83 ,  B01J23/835 ,  B01J23/8435 ,  B01J23/8437 ,  B01J23/866 ,  B01J23/868 ,  B01J23/8892 ,  B01J23/8926 ,  B01J35/023 ,  B01J37/0201 ,  B01J37/18 ,  B82Y30/00 ,  C07C29/00 ,  C07C29/60 ,  Y02P20/52 ,  C07C31/202 ,  C07C31/205

摘要： Ethylene glycol and propylene glycol may be made by hydrogenolysis of a polyol comprising the steps of reacting a polyol with hydrogen in the presence of a hydrogenolysis catalyst. The hydrogenolysis comprises nickel, one or more promoter, and one or more support. The promoter is selected from bismuth, silver, tin, antimony, gold, lead, thallium, cerium, lanthanum, and manganese. The support is selected from zirconia and carbon. A zirconia support comprises a zirconia textual promoter, which is selected from Cr, Mo, W, Nb, Ce, Ca, Mg, La, Pr, Nd, Al, and P. If the support comprises carbon, then the promoter is selected from bismuth and antimony. In another embodiment, if the support comprises carbon, then both the promoter is selected from bismuth and antimony, and the catalyst comprises copper. In another embodiment, the catalyst additionally comprises copper.

摘要翻译： 乙二醇和丙二醇可以通过多元醇的氢解来制备，包括在氢解催化剂存在下使多元醇与氢反应的步骤。 氢解包括镍，一种或多种促进剂和一种或多种载体。 促进剂选自铋，银，锡，锑，金，铅，铊，铈，镧和锰。 载体选自氧化锆和碳。 氧化锆载体包含选自Cr，Mo，W，Nb，Ce，Ca，Mg，La，Pr，Nd，Al和P的氧化锆文本促进剂。如果载体包含碳，则促进剂选自 铋和锑。 在另一个实施方案中，如果载体包含碳，则促进剂均选自铋和锑，并且催化剂包含铜。 在另一个实施方案中，催化剂另外包含铜。

公开(公告)号：EP2061747B1

公开(公告)日：2013-04-17

申请号：EP07765786.4

申请日：2007-07-04

申请人： BASF SE

发明人： KUBANEK, Petr ,  HOFFER, Bram Willem ,  SCHWAB, Ekkehard ,  MELDER, Johann-Peter ,  EVERS, Holger ,  GERLACH, Till

IPC分类号： C07C211/10 ,  C07C215/08 ,  C07C217/08 ,  C07D295/023 ,  B01J23/89 ,  B01J23/825 ,  B01J23/835 ,  B01J23/843 ,  C07C209/16 ,  C07C209/26 ,  C07C213/02 ,  C07D295/02 ,  B01J37/03

CPC分类号： C07C209/16 ,  B01J23/825 ,  B01J23/835 ,  B01J23/8435 ,  B01J23/8437 ,  B01J37/0009 ,  B01J37/03 ,  B01J37/14 ,  B01J37/18 ,  C07C209/26 ,  C07C213/02 ,  C07D295/02 ,  C07D295/023 ,  C07C211/10 ,  C07C215/08 ,  C07C217/08

公开(公告)号：EP2100663B1

公开(公告)日：2012-05-02

申请号：EP09003460.4

申请日：2009-03-10

申请人： Dia-Nitrix Co., Ltd.

发明人： Miyaki, Kenichi ,  Yanagita, Motoo ,  Watanabe, Hirokazu ,  Karasuda, Takashi

IPC分类号： B01J23/843 ,  B01J23/887 ,  B01J21/08 ,  B01J27/043 ,  B01J27/14 ,  C07C253/26 ,  B01J23/00

CPC分类号： C07C253/26 ,  B01J21/08 ,  B01J23/002 ,  B01J23/8877 ,  B01J23/8878 ,  B01J23/8885 ,  B01J23/8898 ,  B01J27/0576 ,  B01J27/187 ,  B01J27/188 ,  B01J27/19 ,  B01J37/0045 ,  B01J2523/00 ,  Y02P20/52 ,  B01J2523/17 ,  B01J2523/305 ,  B01J2523/41 ,  B01J2523/51 ,  B01J2523/53 ,  B01J2523/54 ,  B01J2523/64 ,  B01J2523/68 ,  B01J2523/69 ,  B01J2523/842 ,  B01J2523/845 ,  B01J2523/847 ,  B01J2523/14 ,  B01J2523/22 ,  B01J2523/55 ,  B01J2523/72 ,  B01J2523/11 ,  B01J2523/67 ,  B01J2523/13 ,  B01J2523/3706 ,  B01J2523/27 ,  B01J2523/31 ,  B01J2523/48 ,  C07C255/08

公开(公告)号：EP2234717A1

公开(公告)日：2010-10-06

申请号：EP08865518.8

申请日：2008-12-10

申请人： BASF SE

发明人： KUBANEK, Petr ,  MÄGERLEIN, Wolfgang ,  SCHWAB, Ekkehard ,  MELDER, Johann-Peter ,  JULIUS, Manfred

IPC分类号： B01J23/835 ,  B01J23/84 ,  B01J23/843 ,  B01J23/847 ,  B01J37/03 ,  B01J37/18 ,  B01J23/825 ,  C07C209/16 ,  C07C213/02 ,  C07D295/023

CPC分类号： B01J27/1853 ,  B01J23/002 ,  B01J23/755 ,  B01J23/825 ,  B01J23/835 ,  B01J23/84 ,  B01J23/8435 ,  B01J23/8474 ,  B01J27/055 ,  B01J37/03 ,  B01J37/18 ,  B01J2523/00 ,  C07C209/16 ,  C07C209/78 ,  C07C213/02 ,  C07D295/023 ,  Y02P20/582 ,  B01J2523/17 ,  B01J2523/48 ,  B01J2523/56 ,  B01J2523/845 ,  B01J2523/847 ,  B01J2523/44 ,  B01J2523/53 ,  C07C211/10 ,  C07C217/08

摘要： Disclosed is a method for producing an amine by reacting a primary or secondary alcohol, aldehyde, and/or ketone with hydrogen and a nitrogen compound selected from among the group comprising ammonia and primary and secondary amines in the presence of a catalyst containing zirconium dioxide, copper, and nickel. Before being reduced with hydrogen, the catalytically active material of the catalyst contains oxygen-containing compounds of zirconium, copper, and nickel, 1.0 to 5.0 percent by weight of oxygen-containing compounds of cobalt, calculated as CoO, and 0.2 to 5.0 percent by weight of oxygen-containing compounds of vanadium, niobium, sulfur, phosphorus, gallium, boron, tungsten, lead, and/or antimony, which are respectively calculated as V2O5, Nb2O5, H2SO4, H3PO4, Ga2O3, B2O3, WO3, PbO, or Sb2O3. Also disclosed are catalysts as defined above.

摘要翻译： 本发明公开了一种通过使伯或仲醇，醛和/或酮与氢和选自氨和伯胺和仲胺的氮化合物在含有二氧化锆的催化剂存在下反应来制备胺的方法， 铜和镍。 在用氢气还原之前，催化剂的催化活性材料含有锆，铜和镍的含氧化合物，以CoO计为1.0-5.0重量％的含钴含氧化合物，以及0.2-5.0重量％ 钒，铌，硫，磷，镓，硼，钨，铅和/或锑的含氧化合物的重量分别计算为V2O5，Nb2O5，H2SO4，H3PO4，Ga2O3，B2O3，WO3，PbO或 三氧化二锑。 还公开了如上定义的催化剂。

公开(公告)号：EP2225030A1

公开(公告)日：2010-09-08

申请号：EP08864424.0

申请日：2008-12-10

申请人： BASF SE

发明人： KUBANEK, Petr ,  MÄGERLEIN, Wolfgang ,  SCHWAB, Ekkehard ,  MELDER, Johann-Peter ,  JULIUS, Manfred

IPC分类号： B01J23/835 ,  B01J23/843 ,  B01J37/03 ,  B01J37/18 ,  C07C209/16 ,  C07C213/02 ,  C07D295/023

CPC分类号： B01J23/835 ,  B01J23/002 ,  B01J23/8435 ,  B01J23/8437 ,  B01J37/03 ,  B01J37/18 ,  B01J2523/00 ,  C07C209/16 ,  C07C213/02 ,  C07D295/023 ,  Y02P20/582 ,  B01J2523/17 ,  B01J2523/44 ,  B01J2523/48 ,  B01J2523/842 ,  B01J2523/845 ,  B01J2523/847 ,  B01J2523/53 ,  B01J2523/43 ,  C07C217/08

摘要： The invention relates to a method for producing an amine by reacting a primary or secondary alcohol, aldehyde and/or ketone with hydrogen and a nitrogen compound, selected from the group including ammonia, primary and secondary amines, in the presence of a zirconium dioxide-containing, copper-containing and nickel-containing catalyst, the catalytically active mass of the catalyst prior to its reduction with hydrogen containing oxygen-containing compounds of zirconium, copper, nickel, 0.2 to 40% by weight of oxygen-containing compounds of cobalt, calculated as CoO, 0.1 to 5% by weight of oxygen-containing compounds of iron, calculated as Fe2O3, and 0.1 to 5% by weight of oxygen-containing compounds of lead, tin, bismuth and/or antimony, each calculated as PbO, SnO, Bi2O3 or Sb2O3. The invention also relates to catalysts of the above type.

摘要翻译： 本发明涉及一种通过使伯或仲醇，醛和/或酮与氢和选自氨，伯胺和仲胺的氮化合物在二氧化锆 - 二氧化锆存在下反应来制备胺的方法， 含铜含镍含镍催化剂，催化剂的催化活性物质在用含氢的含氧化合物锆，铜，镍，0.2至40重量％的含氧化合物钴， （以CoO计），0.1至5重量％的以Fe 2 O 3计的铁的含氧化合物和0.1至5重量％的铅，锡，铋和/或锑的含氧化合物，各自以PbO计算， SnO，Bi2O3或Sb2O3。 本发明还涉及上述类型的催化剂。

公开(公告)号：EP3927686A1

公开(公告)日：2021-12-29

申请号：EP20712767.1

申请日：2020-02-21

申请人： Ascend Performance Materials Operations LLC

发明人： CHI, Y.T. ,  MOFFATT, Scott ,  TJADEN, John ,  LOYD, Chelsea ,  ABLES, Lori

IPC分类号： C07C253/26 ,  B01J23/18 ,  B01J23/843 ,  C07C255/03

公开(公告)号：EP2873458A4

公开(公告)日：2015-11-04

申请号：EP13816830

申请日：2013-07-11

申请人： SHANGHAI BI KE CLEAN ENERGY TECHNOLOGY CO LTD

发明人： RUI GUO ,  GAN YONGSHENG ,  ZHANG SIMON ,  LUO YANNING

IPC分类号： B01J23/889 ,  B01J23/78 ,  B01J23/80 ,  B01J23/83 ,  B01J23/843 ,  B01J23/847 ,  B01J23/86 ,  B01J35/08 ,  B01J37/03 ,  B01J37/06 ,  C07C5/48 ,  C07C11/16

CPC分类号： B01J35/08 ,  B01J23/002 ,  B01J23/78 ,  B01J23/80 ,  B01J23/83 ,  B01J23/8437 ,  B01J23/8472 ,  B01J23/862 ,  B01J23/868 ,  B01J23/8892 ,  B01J23/8898 ,  B01J37/0009 ,  B01J37/0018 ,  B01J37/0045 ,  B01J37/0063 ,  B01J37/031 ,  B01J37/06 ,  B01J37/08 ,  B01J37/12 ,  B01J2523/00 ,  C07C5/48 ,  C07C2521/10 ,  C07C2523/02 ,  C07C2523/06 ,  C07C2523/18 ,  C07C2523/28 ,  C07C2523/34 ,  C07C2523/745 ,  C07C2523/75 ,  C07C2523/755 ,  C07C2523/78 ,  C07C2523/80 ,  C07C2523/83 ,  C07C2523/843 ,  C07C2523/847 ,  C07C2523/86 ,  C07C2523/889 ,  C07C11/167 ,  B01J2523/27 ,  B01J2523/72 ,  B01J2523/842 ,  B01J2523/845 ,  B01J2523/17 ,  B01J2523/25 ,  B01J2523/22 ,  B01J2523/54 ,  B01J2523/847 ,  B01J2523/23 ,  B01J2523/43 ,  B01J2523/3706 ,  B01J2523/24 ,  B01J2523/48 ,  B01J2523/68 ,  B01J2523/67 ,  B01J2523/55

摘要： The invention relates to a catalyst for preparation of butadiene by oxydehydrogenation of butene in a fluidized bed reactor, a method of preparing the same, and use of the same, wherein the method comprises: reacting a metal precursor with an alkaline substance to obtain a slurry containing insoluble compound, followed by filtering and washing the slurry; adding a binder and deionized water, followed by agitation to regulate the solid content of the slurry to 10-50%; subjecting the slurry to spray drying granulation, wherein the temperature at the feed port is controlled between 200-400°C, and the temperature at the discharge port is controlled between 100-160°C, to obtain catalyst microspheres; and drying the catalyst microspheres at 80-200°C for 1-24h, and then calcining the catalyst microspheres at 500-900°C for 4-24h to obtain a catalyst having a general formula of FeX a Y b Z c O d , comprising Fe, Mg, Zn, Bi, Mo, Mn, Ni, Co, Ba, Ca, and other metals. The catalyst microspheres prepared according to the invention exhibits high mobility, desirable particle size distribution, extremely high mechanical strength and catalytic activity, is applicable to industrial production of butadiene by oxydehydrogenation of butene in a fluidized bed. When this catalyst is used to prepare butadiene by oxydehydrogenation of butene, the yield of butadiene is 76-86%, and the selectivity to butadiene is 94-97%.

公开(公告)号：EP2873458A1

公开(公告)日：2015-05-20

申请号：EP13816830.7

申请日：2013-07-11

申请人： Shanghai Bi Ke Clean Energy Technology Co. Ltd

发明人： RUI, Guo ,  GAN, Yongsheng ,  ZHANG, Simon ,  LUO, Yanning

IPC分类号： B01J23/889 ,  B01J23/78 ,  B01J23/843 ,  B01J23/83 ,  B01J23/80 ,  B01J23/86 ,  B01J23/847 ,  B01J35/08 ,  C07C11/16 ,  C07C5/48

CPC分类号： B01J35/08 ,  B01J23/002 ,  B01J23/78 ,  B01J23/80 ,  B01J23/83 ,  B01J23/8437 ,  B01J23/8472 ,  B01J23/862 ,  B01J23/868 ,  B01J23/8892 ,  B01J23/8898 ,  B01J37/0009 ,  B01J37/0018 ,  B01J37/0045 ,  B01J37/0063 ,  B01J37/031 ,  B01J37/06 ,  B01J37/08 ,  B01J37/12 ,  B01J2523/00 ,  C07C5/48 ,  C07C2521/10 ,  C07C2523/02 ,  C07C2523/06 ,  C07C2523/18 ,  C07C2523/28 ,  C07C2523/34 ,  C07C2523/745 ,  C07C2523/75 ,  C07C2523/755 ,  C07C2523/78 ,  C07C2523/80 ,  C07C2523/83 ,  C07C2523/843 ,  C07C2523/847 ,  C07C2523/86 ,  C07C2523/889 ,  C07C11/167 ,  B01J2523/27 ,  B01J2523/72 ,  B01J2523/842 ,  B01J2523/845 ,  B01J2523/17 ,  B01J2523/25 ,  B01J2523/22 ,  B01J2523/54 ,  B01J2523/847 ,  B01J2523/23 ,  B01J2523/43 ,  B01J2523/3706 ,  B01J2523/24 ,  B01J2523/48 ,  B01J2523/68 ,  B01J2523/67 ,  B01J2523/55

摘要： The invention relates to a catalyst for preparation of butadiene by oxydehydrogenation of butene in a fluidized bed reactor, a method of preparing the same, and use of the same, wherein the method comprises: reacting a metal precursor with an alkaline substance to obtain a slurry containing insoluble compound, followed by filtering and washing the slurry; adding a binder and deionized water, followed by agitation to regulate the solid content of the slurry to 10-50%; subjecting the slurry to spray drying granulation, wherein the temperature at the feed port is controlled between 200-400°C, and the temperature at the discharge port is controlled between 100-160°C, to obtain catalyst microspheres; and drying the catalyst microspheres at 80-200°C for 1-24h, and then calcining the catalyst microspheres at 500-900°C for 4-24h to obtain a catalyst having a general formula of FeX a Y b Z c O d , comprising Fe, Mg, Zn, Bi, Mo, Mn, Ni, Co, Ba, Ca, and other metals. The catalyst microspheres prepared according to the invention exhibits high mobility, desirable particle size distribution, extremely high mechanical strength and catalytic activity, is applicable to industrial production of butadiene by oxydehydrogenation of butene in a fluidized bed. When this catalyst is used to prepare butadiene by oxydehydrogenation of butene, the yield of butadiene is 76-86%, and the selectivity to butadiene is 94-97%.

摘要翻译： 本发明涉及催化剂制备的丁二烯通过丁烯的氧化脱氢在流化床反应器中，制备所述相同的方法，并使用相同的的，worin该方法包括：在碱性物质反应与金属前体以获得浆料 含有不溶性化合物，然后过滤并洗涤该浆料; 添加粘合剂和去离子水，随后搅拌，以调节浆料10-50％的固体含量; 对所述浆料进行喷雾干燥制粒，worin在进料口的温度是200-400℃之间的控制，并在排出口温度100-160℃之间的控制，以获得催化剂微球; 和干燥在80-200℃下的催化剂微球1-24h，然后在500-900℃下煅烧该催化剂微球4-24h以获得具有一个FEX Y B z对于C O D用的通式的催化剂， 包括铁，镁，锌，铋，钼，锰，镍，钴，钡，钙，和其他金属。 雅丁准备本发明的催化剂微球表现出高流动性，合乎需要的颗粒尺寸分布，非常高的机械强度和催化活性，适用于在流化床的工业生产丁二烯通过丁烯氧化脱氢。 当此所使用的丁烯氧化脱氢制备催化剂丁二烯，丁二烯的产率是76-86％，和丁二烯选择性是94-97％。