Mixed transition metal catalyst systems for olefin polymerization
    18.
    发明公开
    Mixed transition metal catalyst systems for olefin polymerization 失效
    烯烃聚合反应体系

    公开(公告)号:EP1059311A2

    公开(公告)日:2000-12-13

    申请号:EP00120235.7

    申请日:1997-06-17

    IPC分类号: C08F10/02 C08F4/70 C08F4/64

    摘要: The invention encompasses a mixed transition metal olefin polymerization catalyst system suitable for the polymerization of olefin monomers comprising one late transition metal catalyst system and at least one different catalyst system selected from the group consisting of late transition metal catalyst systems, transition metal metallocene catalyst systems or Ziegler-Natta catalyst systems. Preferred embodiments include at least one late transition metal catalyst system comprising a Group 9, 10, or 11 metal complex stabilized by a bidentate ligand structure and at least one transition metal metallocene catalyst system comprising a Group 4 metal complex stabilized by at least one ancillary cyclopentadienyl ligand. The polymerization process for olefin monomers comprises contacting one or more olefins with these catalyst systems under polymerization conditions.

    摘要翻译: 本发明包括适用于烯烃单体的聚合的混合过渡金属烯烃聚合催化剂体系,所述烯烃单体包括一个后过渡金属催化剂体系和至少一种不同的催化剂体系,所述催化剂体系选自后过渡金属催化剂体系,过渡金属茂金属催化剂体系或 齐格勒 - 纳塔催化剂体系。 优选的实施方案包括至少一种后过渡金属催化剂体系,其包含通过二齿配体结构稳定的第9,10或11族金属络合物和至少一种过渡金属茂金属催化剂体系,其包含由至少一个辅助环戊二烯 配体。 烯烃单体的聚合方法包括在聚合条件下使一种或多种烯烃与这些催化剂体系接触。