POLYESTER HYBRID RESINS
    13.
    发明授权
    POLYESTER HYBRID RESINS 有权
    聚酯混合树脂

    公开(公告)号:EP2190898B1

    公开(公告)日:2011-03-09

    申请号:EP08803451.7

    申请日:2008-09-01

    IPC分类号: C08G18/68

    摘要: This invention relates to a polyester urethane hybrid resin casting resin composition which comprises a mixture ABCD of an unsaturated polyester ABC which has moieties derived from at least one alcohol A, moieties derived from a mixture B of carboxylic acids, wherein at least 10 % of the mass of at least one of the said carboxylic acids B or of the said alcohols A have at least one olefinic unsaturation in their molecules, and moieties derived from a monoepoxide C having at least four carbon atoms, which polyester ABC is dissolved in a compound D, and which has at least one olefinic unsaturation and which is radically copolymerisable with the unsaturated polyester oligomer ABC and a second liquid component EF comprising a polyfunctional isocyanate E and a radical initiator F, a process for its production, and a method of use thereof to form large moulded parts.

    CROSSLINKABLE AND FOAMING POLYESTER-POLYURETHANE (HYBRID) RESIN MOULDING COMPOSITIONS, WITH FOAMING CHARACTERISTICS FOR CLOSED MOULD APPLICATIONS
    17.
    发明公开
    CROSSLINKABLE AND FOAMING POLYESTER-POLYURETHANE (HYBRID) RESIN MOULDING COMPOSITIONS, WITH FOAMING CHARACTERISTICS FOR CLOSED MOULD APPLICATIONS 有权
    与SCHÄUMUNGSCHARAKTERISITIKA联网和发泡聚酯型聚氨酯(混合)的树脂模塑料用于紧密表单应用程序

    公开(公告)号:EP2201056A1

    公开(公告)日:2010-06-30

    申请号:EP08802709.9

    申请日:2008-09-29

    申请人: Cray Valley Ltd

    IPC分类号: C08G18/63 C08G18/68

    摘要: It concerns a crosslinkable and foaming polyester-polyurethane resin moulding composition, comprising : an A component, comprising : A1) at least one poly-functional isocyanate compound, and A2) at least one free radical polymerisation initiator a B component, comprising by weight : B1) 100 parts of at least one polyol resin comprising : - B11) 50 to 80 parts of at least one ethylenically unsaturated polyester polyol - B12) 20 to 50 parts of at least one ethylenically unsaturated monomer, with, B11), being the reaction product of : a) an acid component comprising : a1 ) at least one ethylenically unsaturated diacid, and a2) at least one saturated diacid with a1/a2 molar ratio so varying to have an unsaturation content in B11) from 0.25/1 to 5/1, and, b) a diol component in excess with respect to component a) B2) from 0.01 to 1.1 parts of water, B3) optionally, up to 35% of at least one hydroxy alkyl (meth)acrylate, B4) at least one catalyst of the isocyanate / hydroxyl reaction, B5) at least one accelerator for the free radical initiator decomposition, B6) at least one foam stabiliser, B7) optionally, fillers and/or other additives the said composition being free of any primary or of secondary amine and of any polyol of low Mw chain extender. The invention further relates to a process of preparation and specific uses in light weight articles in sanitary, building or automotive uses.