摘要:
The invention relates to the preparation of alkylated phenols. More specifically, the invention relates to an improved process for the manufacture of 2-secondary-alkyl-4,5-di-normal-alkylphenols.
摘要:
Disclosed herein are highly stable styrenated phenolic compositions that are liquids at room temperature, and polymer articles and lubricant compositions containing such styrenated phenolic compositions. Also disclosed are processes for forming such styrenated phenolic compositions, which processes afford distyrenated phenolics assaying at 70% minimum by total GC area, comprising reacting styrene with one or more phenolics, e.g., at least one of phenol, p-cresol and/or o-cresol, in the presence of an acid catalyst, preferably a sulfonic acid catalyst, at elevated temperature, wherein the resulting product mixture comprises one or more monostyrenated phenolics, one or more distyrenated phenolics, and one or more tristyrenated phenolics.
摘要:
The present invention relates to a method for the production of dronabinol ((6aR-trans)-6a,7,8,10a-tetrahydro-6,6,9-trimethyl-3-pentyl-6H- dibenzo[b,d]pyran-1-ol, Δ9-tetrahydrocannabinol (Δ9-THC)) from cannabidiol (CBD) by the cyclisation of cannabidiol (CBD) (2-[1 R-3-methyl-6-(1-methylethenyl)-2-cyclohexen-1-yl]-5-pentyl-1,3-benzoldiol) to Δ9-THC. The method according to the invention is characterised in that cannabidiol (CBD) is provided in an organic solvent and is cyclised to Δ9-THC by heating, in the presence of a molecular sieve. It was ascertained that, in the method according to the invention, in addition to the previously described drying properties, the molecular sieve also has good catalytic properties, which play an important part in the above reaction. As a rule, cyclisation carried out in the presence of a Lewis acid catalyst alone is markedly slower and yields less Δ9-THC than cyclisation carried out in the presence of a molecular sieve.
摘要:
The specification provides a method for producing p-cumylphenol phenol by reacting phenol with α-methylstyrene in the presence of a highly efficient heterogeneous aluminum zirconium catalyst.
摘要:
The invention relates to a method for the production of polyisobutenylphenoles by alkylation of an aromatic hydroxy compound with substantially singly ethylenically unsaturated and substantially homopolymer polyisobutenes in the presence of a Lewis-acid alkylation catalyst, characterised in that, ether is used as an additional co-catalyst, whereby in the case of BF3 the ether has a molecular weight as a Lewis-acid of at least 102 g/mol.
摘要:
Method for preparing and purifying 3-(4-hydroxyphenyl)-1,1,3-trimethylindan-5-ol by isomerizing isopropenylphenol, dimers and oligomers thereof or mixtures thereof, then distilling the reaction mixture.
摘要:
A method for C-alkylating a hydroxylated aromatic compound having at least one hydrogen atom in the ortho or para position relative to the hydroxyl grouping, wherein the aromatic compound is exposed to a proton acid and a compound causing the formation of a carbo-cation in the presence of the acid, and the reaction is performed in the presence of a solvent consisting of a water-alcohol pair.