公开(公告)号：EP2782948B1

公开(公告)日：2016-06-08

申请号：EP12787025.1

申请日：2012-11-19

Applicant: BASF SE

Inventor： STRAUTMANN, Julia ,  SCHAUB, Thomas ,  HÜFFER, Stephan ,  MAAS, Steffen ,  WOOD, Claudia

IPC: C08G73/02

CPC classification number: C07C209/14 ,  C08G73/0213 ,  C09J179/02

公开(公告)号：EP2683680B1

公开(公告)日：2015-06-17

申请号：EP12706272.7

申请日：2012-03-01

Applicant: BASF SE

Inventor： SCHAUB, Thomas ,  BUSCHHAUS, Boris ,  BRINKS, Marion, Kristina ,  SCHELWIES, Mathias ,  PACIELLO, Rocco ,  MELDER, Johann-Peter ,  MERGER, Martin

IPC: C07C213/02 ,  C07D207/04 ,  C07D207/20 ,  C07D295/027

CPC classification number: C07C213/02 ,  C07D207/04 ,  C07D207/20 ,  C07D295/027 ,  C07C215/08 ,  C07C217/08

公开(公告)号：EP2683707B1

公开(公告)日：2015-05-13

申请号：EP12707090.2

申请日：2012-03-01

Applicant: BASF SE

Inventor： SCHAUB, Thomas ,  BUSCHHAUS, Boris ,  BRINKS, Marion Kristina ,  SCHELWIES, Mathias ,  PACIELLO, Rocco ,  MELDER, Johann-Peter ,  MERGER, Martin

IPC: C07D307/52 ,  C07C213/02

CPC classification number: C07C213/02 ,  C07D207/20 ,  C07D295/023 ,  C07D307/52 ,  C07C215/08 ,  C07C217/08 ,  C07C215/14

公开(公告)号：EP2655310B1

公开(公告)日：2014-11-05

申请号：EP11801704.5

申请日：2011-12-15

Applicant: BASF SE

Inventor： SCHAUB, Thomas ,  FRIES, Donata Maria ,  PACIELLO, Rocco ,  MOHL, Klaus-Dieter ,  SCHÄFER, Martin ,  RITTINGER, Stefan ,  DECKERT, Petra ,  BASSLER, Peter

IPC: C07C51/15 ,  C07C53/02

CPC classification number: C07C51/15 ,  Y02P20/582

公开(公告)号：EP2655310A1

公开(公告)日：2013-10-30

申请号：EP11801704.5

申请日：2011-12-15

Applicant: BASF SE

Inventor： SCHAUB, Thomas ,  FRIES, Donata Maria ,  PACIELLO, Rocco ,  MOHL, Klaus-Dieter ,  SCHÄFER, Martin ,  RITTINGER, Stefan ,  DECKERT, Petra ,  BASSLER, Peter

IPC: C07C51/15 ,  C07C53/02

CPC classification number: C07C51/15 ,  Y02P20/582

Abstract: The invention relates to a method for producing formic acid by reacting carbon dioxide (1) with hydrogen (2) in a hydrating reactor (I) in the presence of a catalyst comprising an element from the 8
th , 9
th , or 10
th group of the periodic system; a tertiary amine containing at least twelve carbon atoms per molecule; and a polar solvent comprising one or more monoalcohols selected from methanol, ethanol, propanols, and butanols, forming formic acid / amine adducts as intermediate products, which are subsequently thermally split, wherein a tertiary amine having a boiling point at least 5°C higher than formic acid is used, and wherein a reaction mixture comprising the polar solvent, the formic acid / amine adducts, the tertiary amine, and the catalyst forms from the reaction in the hydrating reactor (I) and is discharged as a discharge (3) from the reactor.

Abstract translation: 本发明涉及一种在含有第8,9或10族元素的催化剂存在下，在水合反应器（I）中使二氧化碳（1）与氢气（2）反应生产甲酸的方法， 周期系统; 每个分子含有至少12个碳原子的叔胺; 和包含一种或多种选自甲醇，乙醇，丙醇和丁醇的一元醇的极性溶剂，形成甲酸/胺加合物作为中间产物，随后将其热裂解，其中沸点至少高5℃的叔胺 （I）中的反应形成包含极性溶剂，甲酸/胺加合物，叔胺和催化剂的反应混合物并作为放电（3）排出， 来自反应堆。

公开(公告)号：EP2588439A1

公开(公告)日：2013-05-08

申请号：EP11726423.4

申请日：2011-06-21

Applicant: BASF SE

Inventor： SCHAUB, Thomas ,  FRIES, Donata Maria ,  PACIELLO, Rocco ,  MOHL, Klaus-Dieter ,  SCHÄFER, Martin ,  RITTINGER, Stefan ,  SCHNEIDER, Daniel

IPC: C07C51/00 ,  C07C53/02

CPC classification number: C07C51/00 ,  C07C53/02

Abstract: A process is proposed for preparing formic acid by reaction of carbon dioxide (1) with hydrogen (2) in a hydrogenation reactor (I) in the presence of a catalyst containing an element from group 8, 9 or 10 of the Periodic Table, of a tertiary amine containing at least 12 carbon atoms per molecule, and of a polar solvent comprising one or more monoalcohols selected from methanol, ethanol, propanols and butanols, to form formic acid/amine adducts as intermediates, which are subsequently cleaved thermally, the workup of the outputs (3) from the hydrogenation reactor (I) being performed with addition of water, and this increasing the partition coefficient of the catalyst between the upper phase (4) and the lower phase.

公开(公告)号：EP4547731A1

公开(公告)日：2025-05-07

申请号：EP23736117.5

申请日：2023-06-29

Applicant: BASF SE

Inventor： SCHAUB, Thomas ,  BRUCHMANN, Bernd ,  RODEWALD, Dieter ,  NICOLAS, Mathieu ,  FALCONNET, Alban

IPC: C08G63/08

公开(公告)号：EP4504827A1

公开(公告)日：2025-02-12

申请号：EP23715108.9

申请日：2023-03-28

Applicant: BASF SE

Inventor： SCHAUB, Thomas ,  SCHUETTE, Markus ,  HASHMI, A. Stephen K. ,  ZUBAR, Viktoriia ,  KLEIN, Philippe

IPC: C08J11/16 ,  C08J11/02 ,  C08J99/00 ,  B01J35/00

公开(公告)号：EP4359374A1

公开(公告)日：2024-05-01

申请号：EP22733380.4

申请日：2022-06-10

Applicant: BASF SE

Inventor： SCHAUB, Thomas ,  SHEVCHENKO, Grigory Andre ,  HASHMI, A. Stephen K. ,  SITTE, Nikolai Amadeus

IPC: C07C29/42 ,  C07C33/042

CPC classification number: C07C29/42

公开(公告)号：EP3921298A1

公开(公告)日：2021-12-15

申请号：EP20702649.3

申请日：2020-02-05

Applicant: BASF SE ,  Ruprecht-Karls-Universität Heidelberg

Inventor： SCHAUB, Thomas ,  JEVTOVIKJ, Ivana ,  HASHMI, A. Stephen K. ,  SEKINE, Kohei

IPC: C07C41/50 ,  C07C43/30