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    VERFAHREN ZUR HERSTELLUNG VON AMEISENSÄURE
    1.
    发明公开
    VERFAHREN ZUR HERSTELLUNG VON AMEISENSÄURE 审中-公开
    用于生产FORMIC

    公开(公告)号：EP2925715A1

    公开(公告)日：2015-10-07

    申请号：EP13789315.2

    申请日：2013-11-12

    申请人： BASF SE

    发明人： FRIES, Donata Maria ,  MOHL, Klaus-Dieter ,  SCHÄFER, Martin ,  SCHNEIDER, Daniel ,  BASSLER, Peter ,  RITTINGER, Stefan ,  TELES, Joaquim Henrique

    IPC分类号： C07C51/09 ,  C07C51/44

    CPC分类号： C07C51/02 ,  C07C51/09 ,  C07C51/44 ,  C07C53/02

    摘要： The invention relates to a method for obtaining formic acid by thermal separation of a stream containing formic acid and a tertiary amine (I), according to which method a liquid stream containing formic acid, methanol, water and tertiary amine (I) is produced in step (a) by bringing together methyl formate, water and tertiary amine (I), methanol is removed therefrom in step (b), and in step (c) formic acid is removed by distillation from the obtained liquid stream in a distillation device, wherein, when bringing together methyl formate, water and tertiary amine (l), methyl formate, water and optionally tertiary amine (I) are initially supplied in step (a1) in a molar ratio of 0 ≤ n(amine to a1) / n(methyl formate to a1) ≤ 0.1 and 70 to 100% of the possible hydrolysis equilibrium is adjusted, and subsequently in step (a2) tertiary amine (I) is supplied in a molar ratio of 0.1 ≤ n(amine to a2) / n(methyl formate to a1) ≤ 2 and the mixture is reacted.

    A PROCESS FOR PREPARING PROPYLENE OXIDE
    9.
    发明公开
    A PROCESS FOR PREPARING PROPYLENE OXIDE 审中-公开
    VERFAHREN ZUR HERSTELLUNG VON PROPYLENOXID

    公开(公告)号：EP3024579A1

    公开(公告)日：2016-06-01

    申请号：EP14739188.2

    申请日：2014-07-16

    申请人： BASF SE ,  Dow Global Technologies LLC

    发明人： TELES, Joaquim Henrique ,  SEELIG, Bianca ,  RIEDEL, Dominic ,  KAMPE, Philip ,  URBANCZYK, Daniel ,  WEBER, Markus ,  MÜLLER, Ulrich ,  PARVULESCU, Andrei-Nicolae ,  GUMLICH, Kai ,  BASSLER, Peter ,  BARTOSCH, Christian ,  JACUBINAS, Richard ,  WEIDENBACH, Meinolf ,  WITZL, Werner

    IPC分类号： B01J29/89 ,  B01J37/02 ,  C07D301/12 ,  B01J27/16

    CPC分类号： C07D301/12 ,  B01J27/18 ,  B01J27/188 ,  B01J29/7038 ,  B01J29/7088 ,  B01J35/002 ,  B01J35/1019 ,  B01J2229/186 ,  Y02P20/52

    摘要： A continuous process for the preparation of propylene oxide, comprising (i) providing a liquid feed stream comprising propene, hydrogen peroxide, acetonitrile, water, optionally propane, and at least one dissolved potassium salt of a phosphorus oxyacid wherein the molar ratio of potassium relative to phosphorus in the at least one potassium salt of a phosphorus oxyacid is in the range of from 0.6 to 1.4; (ii) passing the liquid feed stream provided in (i) into an epoxidation reactor comprising a catalyst comprising a titanium zeolite of structure type MWW comprising zinc, and subjecting the liquid feed stream to epoxidation reaction conditions in the epoxidation reactor, obtaining a reaction mixture comprising propylene oxide, acetonitrile, water, the at least one dissolved potassium salt of a phosphorus oxyacid, optionally propene, and optionally propane; (iii) removing an effluent stream from the epoxidation reactor, the effluent stream comprising propylene oxide, acetonitrile, water, at least a portion of the at least one dissolved potassium salt of a phosphorus oxyacid, optionally propene, and optionally propane.

    摘要翻译： 一种用于制备环氧丙烷的连续方法，包括（i）提供包含丙烯，过氧化氢，乙腈，水，任选的丙烷和至少一种溶解的含磷酸的钾盐的液体进料流，其中钾相对的摩尔比 至少一种含磷酸的钾盐中的磷在0.6至1.4的范围内; （ii）将（i）中提供的液体进料流送入包含催化剂的环氧化反应器中，所述催化剂包括含锌的结构型MVVW的钛沸石，并使该液体进料流在环氧化反应器中进行环氧化反应条件，得到反应混合物 包括环氧丙烷，乙腈，水，至少一种溶解的含磷酸的钾盐，任选的丙烯，以及任选的丙烷; （iii）从环氧化反应器中除去流出物流，流出物流包含环氧丙烷，乙腈，水，至少一部分溶解的磷酸钾盐，任选的丙烯和任选的丙烷。