Abstract:
Particulate sorbent compositions comprising zinc titanate support having thereon a substantially reduced valence promoter metal selected from the group consisting of cobalt, nickel, iron, manganese, copper, molybdenum, tungsten, silver, tin and vanadium or mixtures thereof provide a system for the desulfurization of a feed stream of cracked-gasolines or diesel fuels in a desulfurization zone by a process which comprises contacting such feed streams in a desulfurization zone with a particulate sorbent composition followed by separation of the resulting low sulfur-containing steam and sulfurized sorbent and thereafter regenerating and activating the separated sorbent before recycle of same to the desulfurization zone.
Abstract:
The present invention relates to a process for the synthesis of highly active modified carbon supported palladium catalyst by simultaneously impregnating activated carbon with a palladium precursor and an aluminium precursor. The carbon supported palladium catalyst is useful for the hydrodechlorination of dichlorodifluoromethane to produce difluoromethane.
Abstract:
Particulate sorbent compositions comprising zinc titanate support having thereon a substantially reduced valence promoter metal selected from the group consisting of cobalt, nickel, iron, manganese, copper, molybdenum, tungsten, silver, tin and vanadium or mixtures thereof provide a system for the desulfurization of a feed stream of cracked-gasolines or diesel fuels in a desulfurization zone by a process which comprises contacting such feed streams in a desulfurization zone with a particulate sorbent composition followed by separation of the resulting low sulfur-containing steam and sulfurized sorbent and thereafter regenerating and activating the separated sorbent before recycle of same to the desulfurization zone.
Abstract:
In the manufacturing process of the exhaust gas purifying catalyst (3), rhodium is supported by the base material using the rhodium carbonyl cluster solution in which rhodium carbonyl cluster is dissolved into methanol in the step of forming the upper catalytic layer (6) including rhodium and platinum as catalytic metals. By this, the dispersibility of rhodium in the base material is highly raised, and further rhodium is effectively restrained from being oxidized during the manufacturing process of the catalyst (3). Thus, according to the exhaust gas purifying catalyst (3), particularly, the purifying performance of NOx at both of lower exhaust gas temperature and higher exhaust gas temperature is highly improved.
Abstract:
A process is disclosed for producing hydrocarbons. The process involves contacting a feed stream comprising hydrogen and carbon monoxide with a catalyst in a reaction zone maintained at conversion-promoting conditions effective to produce an effluent stream comprising hydrocarbons. In accordance with this invention, the catalyst used in the process includes at least cobalt, rhenium, and a promoter selected from the group including boron, phosphorus, potassium, manganese, and vanadium. The catalyst may also comprise a support material selected from the group including silica, titania, titania/alumina, zirconia, alumina, aluminum fluoride, and fluorided aluminas.
Abstract:
Catalysts for the fluid-bed hydrodechlorination of carbon tetrachloride to chloroform having high catalytic stability and comprising platinum supported on microspheroidal gamma alumina, characterized in that the platinum is in the form of particles dispersed throughout the mass of the support.
Abstract:
This invention provides silica gel carrying a titanium oxide photocatalyst in a high concentration that improves performances in decomposing and removing smelly and toxic substances in the air, or organic solvents, agricultural chemicals, etc. in water, and that has properties excellent from the viewpoint of safety, economic efficiency, stability, and water-resistance (it does not break apart when it is put into water), by providing a concentration gradient of titanium oxide such that the concentration of titanium oxide near the surface of the silica gel is high and the concentration of titanium oxide of the central part of the silica gel is low, and a method for the preparation thereof. The silica gel carrying a titanium oxide photocatalyst in a high concentration of the present invention is characterized in that the concentration of the titanium oxide contained in the pores near the surface of the silica gel is 7 - 70% by weight, said silica gel having an average pore diameter of 6 - 100 nm, provided that the concentration gradient is provided such that the amount of the titanium oxide contained in the pores near the surface of the silica gel is 1.5 times or more than the amount of the titanium oxide contained in the pores near the central part of the silica gel.
Abstract:
There is provided a process for preparing a catalyst wherein the volatile content of an impregnated support is reduced in one or more steps, wherein at least one volatile content reduction step is performed in the presence of a sulfur containing compound.