摘要:
A method of selectively inhibiting pyruvic acid decomposition activity in microorganism cells containing tryptophanase or a treated product thereof, which comprises heat-treating said cells or the treated product thereof in the presence of an ammonium ion.
摘要:
A process for producing an indole by catalytic reaction of a 2-(o-aminoaryl)ethanol, said reaction being carried out by heating in a liquid phase in the presence of an alkali metal using a catalyst containing a metal selected from the group consisting of a platinum-group metal, nickel and copper. The process is industrially advantageous in that indoles are produced in high yield.
摘要:
he process for preparing a high-octane gasoline involves catalyzing a light hydrocarbon containing one or more C 2 -C 7 paraffins and/or C 2 -C 7 olefins with a crystalline aluminogallosilicate with the skeleton comprised of SiO 4 , AlO 4 and GaO 4 tetrahedra at temperatures ranging from 350°C to 650°C under a hydrogen partial pressure of not higher than 5 kg/cm 2 . The crystalline aluminogallosilicate to be used as the catalyst for the process has its skeleton comprised of SiO 4 , AlO 4 and Ga0 4 tetrahedra and having the following formula: wherein M is a metal selected from an alkaline metal, and alkaline earth metal and a mixture thereof, n is the valence of said metal, a is a positive number of (b + 1) ± 3.0, b is between 0.3 and 30, c is between 8 and 2,000, and d is between 1 and 200.
摘要:
A solid strong acid catalyst useful for hydrocarbon reactions, especially for the skeletal isomerization of paraffinic hydrocarbons is provided by supporting sulfate (S0 4 ) and at least one Group VIII metal on a support consisting of a hydroxide or oxide of a Group IV metal or Group III metal or a mixture thereof and then calcining and stabilizing the catalyst.
摘要:
Aromatic hydrocarbons are produced by catalytic conversion of aliphatic hydrocarbons using an aluminogallosilicate catalyst. A feed of the aliphatic hydrocarbon is mixed with a recycle gas and the mixture is contacted with the catalyst. The resultant conversion product is separated into a gas phase and a liquid phase containing aromatic hydrocarbons. The gas phase is separated into a hydrogen-rich gas and a methane- and/or ethane-rich gas while the liquid phase is separated into an aromatic hydrocarbon-containing product and a light hydrocarbon-containing gas. At least part of the methane- and/or ethane-rich gas and the light hydrocarbon-containing gas is recycled as the above recycle gas. The catalytic conversion is performed while increasing the reaction temperature as the process proceeds.
摘要:
A process for preparing pyruvate in high yield is disclosed, comprising reacting propylene glycol with molecular oxygen in an aqueous solution in the presence of a platinum catalyst containing a metallic component selected from the group consisting of lead, thallium, and cadmium while controlling the pH of the reaction mixture between 7 and 9. The crude pyruvate can be purified by treating with activated carbon in the presence of water.