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    VERFAHREN ZUR HERSTELLUNG VON CYCLOHEXAN MIT AUS EINEM STEAMCRACKVERFAHREN STAMMENDEN AUSGANGSMATERIALIEN
    4.
    发明公开
    VERFAHREN ZUR HERSTELLUNG VON CYCLOHEXAN MIT AUS EINEM STEAMCRACKVERFAHREN STAMMENDEN AUSGANGSMATERIALIEN 有权
    用于生产用蒸汽CYCLOHEXANE从裂缝过程中获得起始物

    公开(公告)号：EP2909159A2

    公开(公告)日：2015-08-26

    申请号：EP13776829.7

    申请日：2013-10-16

    申请人： BASF SE

    发明人： TSCHIRSCHWITZ, Steffen ,  WISSEL-STOLL, Kathrin ,  BÜRKLE, Jochen ,  KOSTOVA, Albena ,  SCHMITT, Markus ,  WLOKA, Veronika ,  DEUERLEIN, Stephan ,  BOSCH, Marco ,  OEHLENSCHLÄGER, Steffen ,  SCHREIBER, Michael ,  AVERLANT, Gauthier Luc Maurice ,  JONI, Joni ,  PROCHAZKA, Roman ,  BOCK, Martin ,  KINDLER, Alois ,  MALKOWSKY, Daniela ,  SPUHL, Katharina ,  BITTERLICH, Stefan ,  PFEIFFER, Daniel

    IPC分类号： C07C5/29 ,  C07C13/18

    CPC分类号： C07C5/10 ,  C07C5/29 ,  C07C2523/755 ,  C07C2527/125 ,  C07C2601/14 ,  C07C13/18

    摘要： The invention relates to a method for producing cyclohexane by isomerizing a hydrocarbon mixture (KG1) containing methylcyclopentane (MCP) in the presence of a catalyst. The catalyst is preferably an acidic ionic liquid. A flow (S1) originating from a steam cracking process is used as a starting material. The hydrocarbon mixture (KG1) is obtained from said stream (S1) in a device for removing aromatics. The hydrocarbon mixture has a reduced aromatic content in comparison with the flow (S1). (KG1) can also be (nearly) free of aromatics. In dependence on the type and amount of the aromatics remaining in the hydrocarbon mixture (KG1), in particular if benzene is present, a hydrogenation of (KG1) additionally can be performed before the isomerization. Furthermore, additional purification steps can optionally be performed before or after the isomerization or hydrogenation in dependence on the presence of other components of (KG1). Preferably high-purity cyclohexane (in accordance with specifications) is isolated from the hydrocarbon mixture (KG2) arising during the isomerization, wherein the specifications are given, for example, by the use of the cyclohexane for the production of caprolactam known to the person skilled in the art.

    摘要翻译： 本发明涉及一种通过含异构化在催化剂的存在下的烃混合物（KG1）甲基环戊烷（MCP）生产环己烷。 催化剂较好是在酸性离子液体。 从蒸汽裂解过程的流程（S1）源自被用作起始材料。 烃混合物（KG1）从所述流（S1）在一个设备中获得用于除去芳族化合物。 烃混合物具有与所述流（S1）相比较减少的芳族含量。 因此（KG1）可以（几乎）不含芳香烃。 在剩余在烃混合物（KG1）的芳族化合物的类型和量的依赖性，特别是如果是苯存在的（KG1）氢化另外可在异构化之前进行。 进一步，另外的纯化步骤可任选的异构化或氢化之前或之后执行。在依赖（KG1）的其它组分的存在。 优选高纯度的环己烷（与规格雅舞蹈）从烃混合物（KG 2）的异构化，worin规格中给出，对于实施例中所产生，通过使用环己烷为已知的本领域技术人员生产己内酰胺的分离 的技术人员。

    PROCESS FOR PRODUCING ADAMANTANE COMPOUND
    6.
    发明公开
    PROCESS FOR PRODUCING ADAMANTANE COMPOUND 审中-公开
    方法用于生产金刚烷

    公开(公告)号：EP1357100A4

    公开(公告)日：2006-08-02

    申请号：EP02711248

    申请日：2002-01-31

    申请人： IDEMITSU KOSAN CO

    发明人： KOJIMA AKIO ,  SAITO MASAO

    IPC分类号： C07B61/00 ,  C07C5/29 ,  C07C13/615

    CPC分类号： C07C13/615 ,  C07C5/29 ,  C07C2529/12 ,  C07C2603/74

    摘要： A process for highly selectively producing an adamantane compound with a production apparatus made from inexpensive materials, without adversely influencing the natural environment. The process comprises isomerizing a tricyclic saturated hydrocarbon having 10 or more carbon atoms in the presence of a solid acid catalyst having a metal supported thereon to produce an adamantane compound, and is characterized in that a compound having an unsaturated bond is caused to coexist during the isomerization.