摘要:
A water based drilling fluid comprises : (a) an aqueous medium, (b) a polyalkylene glycol of general formula : wherein R is H or CH 3 , R 1 is H or an alkyl group containing 1 to 4 carbon atoms, and n is a number in the range 4 to 200, and (c) a potassium salt. In the case of tetra- and higher molecular weight polyalkylene glycols, there is a synergistic clay-stablising effect between these compounds and the potassium salt.
摘要:
Olefin polymerization catalysts capable of polymerizing olefins such as ethylene to polyolefins with broad molecular weight distributions are made by depositing on an oxide suport (or especially phosphate derivative thereof) (i) a chromium complex of formula RCr-L, where R is optionally substituted pentadienyl or cyclopentadienyl and L is a reactive ligand, or a bis arene chromium and (ii) a metal complex of formula MR³ R⁴ R⁵ R⁶ wherein M is Ti, Zr or Hf, and R³-R⁶ can be allyl (when M is Zr or Hf) or of 4-20 carbons of formula (a) CH₂ X (R⁷ R⁸ R⁹) where X = C, Si or Ge and R⁷-R⁹ are hydrocarbyl, or (b) CH₂ Ar where Ar is optionally substituted aromatic, or said metal complex is of formula Ti R¹¹ R¹², where R¹¹ and R¹² are acyclic dienyl.
摘要翻译:能够将烯烃如乙烯聚合成具有宽分子量分布的聚烯烃的烯烃聚合催化剂通过在氧化物(或其特别是磷酸酯衍生物)上沉积(i)式RCr-L的铬络合物来制备,其中R是任选取代的戊二烯基 或环戊二烯基,L为反应性配体或双芳烃铬,和(ii)式为MR 3 R 4 R 5 R 6的金属络合物,其中M为Ti,Zr或Hf,R为 R 3可以是烯丙基(当M是Zr或Hf时)或4-20个碳原子的式(a)CH 2 X(R 7 R 8 R 9),其中X = C ,Si或Ge和R 7 -R 9是烃基,或(b)CH 2 Ar,其中Ar是任选取代的芳族,或所述金属络合物具有式Ti R 1 R 1, 2>,其中R 1和R 2均为非环状二烯基。
摘要:
The present invention relates to a process and a device for introducing a catalytically active powder into a reactor (20) for gas phase alpha-olefin polymerization. The device comprises a storage vessel (3) containing the powder, a metering valve (4) delivering metered quantities of the powder into an intermediate chamber (5) comprising at least one obstacle (6) separating an upper part (5a) of the chamber (5) comprising an auxiliary gas inlet (2a) from a lower part (5b) terminated by an outlet orifice (5c). A connecting pipe (18) connects the outlet orifice (5c) to a mixing device (8) situated on a conveying pipework (15) communicating with the reactor (20). The powder is introduced into the reactor in a dilute suspension form and in a more uniform rate.
摘要:
A lubricating oil soluble compound suitable for use as a dispersant additive is obtainable by reacting at elevated temperature an epoxyacrylate with a dispersant having at least one reactive nitrogen - containing moiety. Intermediates of the general formula IV
where Y′ is a group derived from the reaction of the epoxyacrylate with reactive nitrogen-containing moieties (ie primary or secondary amines) are novel. The process for preparing the lubricating oil soluble compounds can be a one step or multistep process. Lubricating oil compositions comprise a major proportion of lubricating oil and a minor proportion of the lubricating oil soluble compounds.
摘要:
A lubricating oil soluble compound suitable for use as a dispersant additive is obtainable by reacting at elevated temperature a polyacrylate with a dispersant having at least one reactive nitrogen - containing moiety. Intermediates of the general formula IV
where Y¹ is a group derived from the reaction of the polyacrylate with the reactive nitrogen-containing moieties (i.e. primary or secondary amine) are novel. The process for preparing the lubricating oil soluble compounds can be a one step or multistep process. Lubricating oil compositions comprise a major proportion of lubricating oil and a minor proportion of the lubricating oil soluble compounds.
摘要:
A method for recovering the surfactant from a dispersion or emulsion of oil and water containing a temperature sensitive surfactant which method comprises the steps of heating the dispersion or emulsion to a temperature above the cloud point of the surfactant under conditions of temperature and aqueous phase salinity such that the dispersion or emulsion breaks and separates into an oil layer, an aqueous layer and a surfactant layer, and recovering the surfactant layer. The recovered surfactant may be recycled for use in preparing further quantities of dispersion or emulsion, thus rendering the operation more economic.
摘要:
An electrocatalytic process is described for producing synthesis gas from light hydrocarbons such as methane or natural gas. The process generally comprises the steps of
(A) providing an electrochemical cell comprising a solid electrolyte having a first surface coated with conductive metal, metal oxide or mixtures thereof capable of facilitating the reduction of oxygen to oxygen ions, and a second surface coated with conductive metal, metal oxide or mixtures thereof, provided that both coatings are stable at the operating temperatures, (B) heating the cell to a temperature of at least 1000°C, (C) passing an oxygen-containing gas in contact with the first conductive coating, (D) passing methane, natural gas or other light hydrocarbons in contact with the second conductive coating, and (E) recovering synthesis gas.
摘要:
There is provided a process for reacting pentaerythritol with a trivalent phosphorus trihalide conducted in the presence of a phosphorus acid catalyst such as methyl acid phosphate. The reaction product is a useful intermediate for the preparation of flame retardants.
摘要:
Water soluble polymers from acrylic acid optionally with other monomers have a narrow molecular weight distribution and are made by continuous loop polymerisation particular in the presence of sodium chlorate and sodium metabisulphite as redox initiator. The loop polymerisation gives more uniform product than batch operation and the narrow molecular weight distribution gives polyacrylates useful in water treatment, scale inhibition and as dispersants.
摘要:
An oil field production chemical, especially a scale inhibitor, is in the form of particles thereof carrying a coating e.g. of a dispersing agent. The coating may be polymeric such as an oligomeric polyacid polyester, a polymeric alkoxylated alcohol or a fatty acid polyamine condensate or it may also be a surfactant and may be used in the form of a suspension in an inert oil, such as diesel oil or kerosene which may be injected into a subterranean formation to inhibit the formation of deposits, e.g. scale in oil wells over a longer period than compounds free of the coating.