WATER-BASED VARNISHES
    43.
    发明授权
    WATER-BASED VARNISHES 失效
    水基清漆。

    公开(公告)号:EP0489109B1

    公开(公告)日:1994-05-25

    申请号:EP90913749.9

    申请日:1990-08-17

    发明人: BIALE, John

    IPC分类号: C09D5/02 C09D133/00

    摘要: A polymeric emulsion comprising a (i) polymer, (ii) water, and (iii) a surfactant is useful as a binder for a water-based varnish that is resistant ot water, 50 % ethanol, and alkali. The polymer comprises about 20 to about 40 weight percent of a soft monomer whose homopolymer has a Tg of less than about -20 °C and about 60 to about 80 weight percent of a mixture of hard monomers each of whose homopolymer has a Tg of greater than about 30 °C. As part of the hard monomer component of the polymer, the polymer comprises about 5 to about 25 weight percent acrylonitrile and about 1 to about 5 weight percent of an olefinic carboxylic acid. Typically, the polymer comprises less than about 1 weight percent surfactant and has a calculated Tg of about 25° to about 60 °C, an actual Tg of about 30° to about 70 °C, and an average particle size of less than about 250 nm. The emulsion generally comprises at least about 40 weight percent solids and has a surface tension of at least about 45 dynes/cm.

    Polyolefin substrates with improved adhesion properties
    44.
    发明公开
    Polyolefin substrates with improved adhesion properties 失效
    聚烯烃底物mit verb dessertenAdhäsioneigenschaften。

    公开(公告)号:EP0595550A1

    公开(公告)日:1994-05-04

    申请号:EP93308395.8

    申请日:1993-10-21

    发明人: Harvey, Noel Gray

    摘要: The adhesion to polyolefin substrates of acrylic-based or other protective polymers, for example in the form of a plastic coating or a latex or solvent-based paint, is improved by use of a segmented copolymer of a polyolefin and a poly(methacrylate) in the form of a laminate or tie-coat adhering to the polyolefin.

    摘要翻译: 通过使用聚烯烃和聚(甲基丙烯酸酯)的分段共聚物来改进对丙烯酸类或其它保护性聚合物对聚烯烃基材的粘附性,例如塑料涂层或胶乳或溶剂型涂料的形式, 附着在聚烯烃上的层压体或粘结层的形式。

    Aqueous composition
    45.
    发明公开
    Aqueous composition 失效
    WässrigeZusammensetzung。

    公开(公告)号:EP0594321A1

    公开(公告)日:1994-04-27

    申请号:EP93307857.8

    申请日:1993-10-01

    发明人: Xiaohong, Ci

    摘要: An aqueous composition is described. The composition comprises a film-forming latex polymer having anionic character ; a water-soluble or water-dispersible polymer formed from at least about 20% by weight monomer containing amine functional groups ; and a volatile base in an amount effective to raise the pH of the composition to a point high enough where essentially all of the amine functional groups are in a nonionic state ; and optionally a water-soluble or water-dispersible multivalent metal. The composition provides an aqueous, quick-set noncementitious composition which is easily applied, develops early cohesive strength and leaves no waste under all curing conditions. The invention is particularly useful as an adhesive used in exterior insulating and finishing systems. The composition also provides an aqueous, exterior, quick-set coating composition having early washout resistance and dirt pick-up resistance. The invention is also particularly useful as a binder used in a traffic paint and as a base coat and/or top coat in exterior insulation finishing systems.

    摘要翻译: 描述了一种水性组合物。 该组合物包含具有阴离子特性的成膜胶乳聚合物; 由至少约20重量%的含有胺官能团的单体形成的水溶性或水分散性聚合物; 和挥发性碱,其量有效地将组合物的pH提高到足够高的程度,其中基本上所有的胺官能团都处于非离子状态; 和任选的水溶性或水分散性多价金属。 该组合物提供易于应用的水性快速固化非凝集组合物,产生早期凝聚力并在所有固化条件下不留下浪费。 本发明特别适用于外部绝缘和整理系统中使用的粘合剂。 该组合物还提供具有早期抗冲击性和耐污垢吸收性的水性,外部,快速固化的涂料组合物。 本发明在用于交通涂料中的粘合剂以及外部绝缘整理系统中的底涂层和/或顶涂层也是特别有用的。

    Cationic latex paint compositions
    47.
    发明授权
    Cationic latex paint compositions 失效
    阳离子胶乳涂料组合物。

    公开(公告)号:EP0407085B1

    公开(公告)日:1994-02-16

    申请号:EP90307006.8

    申请日:1990-06-27

    IPC分类号: C09D7/02 C09D133/06

    CPC分类号: C09D7/45

    摘要: A paint composition comprising cationic latex polymeric binder, pigment and selective cationic pigment dispersant is disclosed. The paint compositions, which demonstrate the advantages of a water-based system, also exhibit excellent stain blocking, corrosion resistance, water sensitivity resistance and adhesion to wood and alkyd surfaces which are competitive in performance with conventional solvent based alkyd primers.

    Polymeric particles
    50.
    发明公开
    Polymeric particles 失效
    Polymerteilchen。

    公开(公告)号:EP0565244A1

    公开(公告)日:1993-10-13

    申请号:EP93301935.8

    申请日:1993-03-15

    IPC分类号: C08F265/02

    摘要: Core and shell polymeric particles are described that have microvoids in the core and one or more channels connecting the microvoids to the exterior of the particle. These particles, or LCAPs are produced by forming a core of polymeric acid, encasing the core in a shell polymer permeable to base, and then neutralizing the core such that the core swells, causing the shell to "explode" in a controlled fashion. This controlled explosion causes channels to form in the shell. These particles can be used as control release devices for target compounds, to impart reinforcing properties to acrylic films, as an opacifying agent in coating compositions, and as a supplement or replacement of part or all of the pigmentary material or extenders that would otherwise be used in such coating compositions.

    摘要翻译: 描述了核和壳聚合物颗粒,其在芯中具有微孔,并且一个或多个通道将微孔连接到颗粒的外部。 这些颗粒或LCAP通过形成聚合酸的核心,将核心包裹在可渗透碱的壳聚合物中,然后中和核心,从而使核心膨胀,导致壳体以受控的方式“爆炸”来生产。 这种受控的爆炸导致通道在外壳中形成。 这些颗粒可以用作目标化合物的控制释放装置,以赋予丙烯酸膜的增强性能,作为涂料组合物中的遮光剂,以及补充或替代部分或全部的颜料或增量剂,否则将被使用 在这样的涂料组合物中。