POLYARYLENE SULFIDE AND PROCESS FOR PRODUCING THE SAME
    46.
    发明公开
    POLYARYLENE SULFIDE AND PROCESS FOR PRODUCING THE SAME 有权
    聚芳及其制造方法

    公开(公告)号:EP1577336A4

    公开(公告)日:2007-05-23

    申请号:EP03782836

    申请日:2003-12-19

    申请人: KUREHA CORP

    IPC分类号: C08G75/02 C08G75/04

    CPC分类号: C08G75/0259

    摘要: A process for producing a polyarylene sulfide which includes a dehydration step in which a mixture comprising an organic amide solvent, an alkali metal hydrosulfide, and an alkali metal hydroxide the amount of which is 0.95 to 1.05 mol per mol of the hydrosulfide is dehydrated by heating. According to need, an alkali metal hydroxide and water are added after the dehydration step so that the total number of moles of the alkali metal hydroxide becomes 1.00 to 1.09 per mol of the sulfur source including the alkali metal hydrosulfide present in the system and the number of moles of water becomes 0.5 to 2.0 per mol of the sulfur source introduced. A polymerization step is conducted through two stages.

    PROCESS FOR PRODUCING ALIPHATIC POLYESTER
    47.
    发明公开
    PROCESS FOR PRODUCING ALIPHATIC POLYESTER 有权
    VERFAHREN ZUR HERSTELLUNG VON ALIPHATIS​​CHEM聚酯

    公开(公告)号:EP1686146A4

    公开(公告)日:2006-11-15

    申请号:EP04792707

    申请日:2004-10-14

    申请人: KUREHA CORP

    IPC分类号: C08G63/91 C08G63/08

    CPC分类号: C08G63/912 C08G63/08

    摘要: A process in which an aliphatic polyester having improved water resistance is obtained using water positively as an initiator and/or molecular weight modifier. In the process, a cyclic ester containing as an initiator and/or molecular weight modifier a proton source compound containing water in an amount larger than 80 ppm is subjected to ring-opening polymerization using the total proton concentration in the cyclic ester as an index and a carboxy-blocking agent is incorporated into the resultant aliphatic polyester to thereby produce an aliphatic polyester.

    摘要翻译: 其中使用水积极地获得具有改善的耐水性的脂族聚酯作为引发剂和/或分子量调节剂的方法。 在该方法中,使用环酯中的总质子浓度作为指数对含有量大于80ppm的水的质子源化合物作为引发剂和/或分子量调节剂的环状酯进行开环聚合,和 在得到的脂肪族聚酯中加入羧基封端剂,制造脂肪族聚酯。