摘要:
This invention pertains to novel multiple quaternary ammonium salts and their derivatives represented by the formula: wherein each R1, R'1, R2, R'2, R3, R'3, R4 or R5 is independently selected from the group consisting alkyl, aryl, aralkyl and -CH2-CH(OR6)-CH2N R1R2R3; wherein one or more R6 group is selected from the group consisting of: and and wherein An is an anion. This invention also pertains to novel multiple quaternary ammonium salts and their derivatives represented by the formula: wherein each R1, R'1, R2, R'2, R3 or R'3 group is independently selected from the group consisting of alkyl, aryl, aralkyl and -CH2-CH(OR4)-CH2N R1R2R3; wherein one or more R4 group is selected from the group consisting of: and and wherein An is an anion.
摘要:
The present invention relates to a wet etching composition including a sulfonic acid, a phosphonic acid, a phosphinic acid or a mixture of any two or more thereof, and a fluoride, and to a process of selectively etching oxides relative to nitrides, high-nitrogen content silicon oxynitride, metal, silicon or silicide. The process includes providing a substrate comprising oxide and one or more of nitride, high-nitrogen content silicon oxynitride, metal, silicon or silicide in which the oxide is to be etched; applying to the substrate for a time sufficient to remove a desired quantity of oxide from the substrate the etching composition; and removing the etching composition, in which the oxide is removed selectively.
摘要:
This invention pertains to novel multiple quaternary ammonium salts and their derivatives represented by the formula: wherein each R1, R'1, R2, R'2, R3, R'3, R4 or R5 is independently selected from the group consisting alkyl, aryl, aralkyl and -CH2-CH(OR6)-CH2N+R1R2R3; wherein one or more R6 group is selected from the group consisting of: and and wherein An- is an anion. This invention also pertains to novel multiple quaternary ammonium salts and their derivatives represented by the formula: wherein each R1, R'1, R2, R'2, R3 or R'3 group is independently selected from the group consisting of alkyl, aryl, aralkyl and -CH2-CH(OR4)-CH2N+R1R2R3; wherein one or more R4 group is selected from the group consisting of: and and wherein An- is an anion.
摘要:
In one embodiment the present invention is a process for recovering an onium hydroxide from a cation exchange material having onium cations adsorbed thereto which comprises (A) contacting said cation exchange material with an aqueous solution of a base selected from alkali metal hydroxides and ammonium hydroxide to form an onium hydroxide, and (B) recovering an aqueous solution of the onium hydroxide. In another embodiment, the present invention relates to a process for recovering an onium hydroxide from a solution containing an onium compound such as an onium hydroxide and/or onium salt, including contacting the solution with a cation exchange material so that at least a portion of onium cations from the onium compound are adsorbed by the cation exchange material; contacting the cation exchange material having the onium cations adsorbed thereto with an aqueous solution of an inorganic base to form an onium hydroxide; and recovering the onium hydroxide solution. The onium hydroxides that can be recovered in this manner include quaternary ammonium hydroxides, quaternary phosphonium hydroxides, and tertiary sulfonium hydroxides.
摘要:
In one embodiment, the present invention relates to a process for recovering an onium hydroxide from a solution containing an onium compound, including contacting the solution with a cation exchange material so that at least a portion of onium cations from the onium compound are adsorbed by the cation exchanger material; contacting an acid with the cation exchanger material to elute an onium salt; charging the onium salt to an electrochemical cell (10) containing at least two compartments (14 and 15), a cathode (12), an anode (11), and an anion selective membrane (13) therebetween, and passing a current through the cell whereby the onium hydroxide is regenerated.
摘要:
On a mis au point un procédé de préparation d'ammoniaque quaternaire de pureté améliorée. Dans un mode de réalisation, cette invention concerne un procédé de préparation d'ammoniaque quaternaire à partir des sels d'ammonium quaternaire correspondants dans une cellule électrolytique, comprenant un compartiment d'analyte contenant une anode, et un compartiment de catholyte contenant une cathode et de l'eau. Lesdits compartiments d'anolyte et de catholyte sont séparés l'un de l'autre par une membrane d'échange de cations. Ledit procédé consiste à: (a) prévoir le catholyte avec une cathode en zinc, cadmium, étain, plomb ou des alliages de ceux-ci, mercure ou amalgame de mercure, (b) charger une solution aqueuse contenant un sel d'ammonium quaternaire dans le compartiment d'analyte, (c) faire passer un courant dans la cellule d'électrolyse pour produire de l'ammoniaque quaternaire dans le compartiement de catholyte, et (d) récupérer l'ammoniaque quaternaire du compartiment de catholyte.
摘要:
A composition including a quaternary onium hydroxide in a non-aqueous solvent, wherein the quaternary ammonium hydroxide has a concentration in the range from about 5% by weight to about 50% by weight of the composition; and imidazolidine-2,4-dione, wherein the imidazolidine-2,4-dione has a concentration in the range from about 10 to about 5000 parts per million of the composition.
摘要:
A process for recovering an onium hydroxide from a composition containing onium ions and a process residue, including providing a composition containing onium ions and a process residue; adding a quantity of a surfactant to the composition to obtain a surfactant-modified composition; providing a cation exchange media; collecting the onium ions by applying the surfactant-modified composition to the cation exchange media wherein the onium ions become bound to and retained by the cation exchange media and the process residue and the surfactant do not become bound to the cation exchange media and are substantially not retained by the cation exchange media; and recovering the onium ions from the cation exchange media as an onium hydroxide by applying a cation-containing hydroxide composition to the cation exchange media.
摘要:
A method of removing a residue from a surface, including applying to the surface a composition including (a) a quaternary ammonium hydroxide having a general formula (I): as defined herein, and (b) a dipolar aprotic solvent substantially free of water; and removing at least a substantial portion of the residue from the surface.
摘要:
A process for separating organic compounds from a mixture by reverse- phase displacement chromatography, including providing a hydrophobic stationary phase; applying to the hydrophobic stationary phase a mixture comprising organic compounds to be separated; displacing the organic compounds from the hydrophobic stationary phase by applying thereto an aqueous composition comprising a non-surface active hydrophobic cationic displacer molecule and about 10 wt% or less of an organic solvent; and collecting a plurality of fractions eluted from the hydrophobic stationary phase containing the separated organic compounds; in which the non-surface active hydrophobic cationic displacer molecule comprises a hydrophobic cation and a counterion, CI, having the general formula A or B, as defined in the disclosure: