Abstract:
A process for preparing a tin-containing zeolitic material having an MWW-type framework structure comprising providing a zeolitic material having an MWW-type framework structure having vacant tetrahedral framework sites, providing a tin-ion source in solid form, and incorporating tin into the zeolitic material via solid-state ion exchange.
Abstract:
The present invention relates to a process for the recovery of an at least bidentate organic compound comprised in a porous metal-organic framework material, the material comprising the at least bidentate organic compound coordinated to at least one metal ion, the process comprising the steps of (a) treating the metal-organic framework material with an acidic or alkaline liquid; (b) optionally separating off solid residue; and (c) isolating the at least bidentate organic compound.
Abstract:
The present invention relates to a gas-phase process for the preparation of butadiene comprising (i) providing a gas stream G-1 comprising ethanol; (ii) contacting the gas stream G-1 comprising ethanol with a catalyst, thereby obtaining a gas stream G-2 comprising butadiene, wherein the catalyst comprises a zeolitic material having a framework structure comprising YO2, Y standing for one or more tetravalent elements, wherein at least a portion of Y comprised in the framework structure is isomorphously substituted by one or more elements X, as well as to a zeolitic material having a framework structure comprising YO2, Y standing for one or more tetravalent elements, wherein at least a portion of Y comprised in the framework structure is isomorphously substituted by one or more elements X, wherein the zeolitic material displays a specific X-ray powder diffraction pattern, and to its use.
Abstract:
A tin containing zeolitic material having an MWW-type framework structure (Sn-MWW), having a tin content of at most 2 weight-%, calculated as element and based on the weight of the Sn-MWW, and having an X-ray diffraction pattern comprising peaks at 2 theta diffraction angles of (6.6 ± 0.1 ) °, (7.1 ± 0.1 ) °, and (7.9 ± 0.1 ) °.
Abstract:
The present invention relates to a process for the preparation of a zeolitic material having a CHA-type framework structure comprising YO 2 and X 2 O 3 , wherein said process comprises the steps of: (1) providing a mixture comprising one or more sources for YO 2 , one or more sources for X 2 O 3 , and one or more tetraalkylammonium cation R 1 R 2 R 3 R 4 N + -containing compounds as structure directing agent; (2) crystallizing the mixture obtained in step (1) for obtaining a zeolitic material having a CHA-type framework structure; wherein Y is a tetravalent element and X is a trivalent element, wherein R 1 , R 2 , and R 3 independently from one another stand for alkyl, wherein R 4 stands for cycloalkyl, and wherein the mixture provided in step (1) does not contain any substantial amount of a source for Z 2 O 5 , wherein Z is P, as well as to zeolitic materials which may be obtained ac- cording to the inventive process and to their use.
Abstract:
A process for the preparation of a zeolitic material having a structure comprising YO 2 and X 2 O 3 is provided, wherein said process comprises the steps of ( 1 ) providing a mixture comprising one or more ammonium compounds of which the ammonium cation has the formula (I): [R 1 R 2 NR 3 R 4+ (I) and further comprising one or more sources for Y0 2 and one or more sources for X 2 O 3 ; (2) crystallizing the mixture provided in step ( 1 ); wherein Y is a tetravalent element, and X is a trivalent element, and wherein the ammonium compounds are preferably derivatized or underivatized N,N-dimethylpyrrolidinium compounds, Ν,Ν-dimethylpiperidinium compounds, Ν,Ν-dimethylhexahydroazepinium compounds, and mixtures thereof, and wherein the molar ratio of ammonium cation having the formula (I) to Y in the mixture provided in step (1) and crystallized in step (2) is equal to or greater than 0.25.