公开(公告)号：EP2038245A1

公开(公告)日：2009-03-25

申请号：EP07765649.4

申请日：2007-06-27

Applicant: BASF SE

Inventor： PINKOS, Rolf ,  TEBBEN, Gerd ,  HAUK, Alexander ,  MÜLLER, Christian ,  RUST, Harald

IPC: C07C45/80 ,  C07C45/82 ,  C07C45/83 ,  C07C45/85 ,  C07C49/413 ,  C07C49/385 ,  C07C45/79 ,  C07C45/78 ,  C07C45/37 ,  C07C45/27

CPC classification number: C07C45/85 ,  C07C45/33 ,  C07C45/34 ,  C07C45/58 ,  C07C45/62 ,  C07C45/80 ,  C07C45/81 ,  C07C45/82 ,  C07C49/413 ,  C07C49/607

Abstract: The invention relates to a method for purifying a composition (I) containing at least one cyclic ketone having 7 to 16 C atoms. The method encompasses the thermal treatment of the composition (I) with at least one acid, then further purification by a method selected from the group consisting of destillation, extraction and crystallization. The invention also relates to a method for producing cyclododecanone, which includes a purification of this type, and to the use of at least one acid for purifying a composition (I) containing at least one cyclic ketone having 7 to 16 C atoms by thermal treatment of the composition (I) with the acid.

公开(公告)号：EP1924630B1

公开(公告)日：2009-03-11

申请号：EP06819860.5

申请日：2006-11-30

Applicant: BASF SE

Inventor： HATSCHER, Stephan ,  HESSE, Michael ,  WABNITZ, Tobias ,  KÄSHAMMER, Stefan ,  PINKOS, Rolf

IPC: C08G65/26 ,  B01J21/16 ,  B01J23/74 ,  B01J20/12

CPC classification number: B01J21/16 ,  B01J23/40 ,  B01J23/745 ,  B01J23/75 ,  B01J37/0009 ,  B01J37/0036 ,  C08G65/10 ,  C08G65/20 ,  C08G65/2642

Abstract: The present invention provides a catalyst comprising a mixture of at least one acid-activated sheet silicate with a transition metal oxide of groups 8 and/or 9 of the Periodic Table of the Elements, and also a process for preparing polytetrahydrofuran, polytetrahydrofuran copolymers, diesters or monoesters of these polymers, characterized in that tetrahydrofuran is polymerized in the presence of at least one telogen and/or comonomers over such a catalyst.

公开(公告)号：EP1999182A1

公开(公告)日：2008-12-10

申请号：EP07857306.0

申请日：2007-12-10

Applicant: BASF SE

Inventor： PINKOS, Rolf ,  STEINER, Jochen ,  KÄSHAMMER, Stefan ,  WABNITZ, Tobias

IPC: C08G65/20

CPC classification number: C08G65/20 ,  C08G65/2657 ,  C08G65/266 ,  C08G65/2696

Abstract: The object of the present invention is a method for changing the predefined mean molecular weight Mn during the continuous production of polytetrahydrofurane, or tetrahydrofurane copolymers, the monoesters or diesters of polytetrahydrofurane, or tetrahydrofurane copolymers, by the polymerization of tetrahydrofurane in the presence of telogen and/or a comonomer on an acid catalyst, wherein: a) the mol ratio of telogen to tetrohydrofurane, or to tetrahydrofurane and the comonomer, is changed, b) then the mean molecular weight of at least one sample is determined, c) as long as the mean molecular weight determined in this way deviates from the molecular weight to be achieved by the change, the previously formed polytetrahydrofurane, or the tetrahydrofurane copolymers, the monoesters or diesters of the polytetrahydrofurane, or tetrahydrofurane copolymers, are at least partially depolymerized on an acid catalyst, and d) the tetrahydrofurane recaptured by means of depolymerization is returned at least partially to the polymerization process.

公开(公告)号：EP1924630A1

公开(公告)日：2008-05-28

申请号：EP06819860.5

申请日：2006-11-30

Applicant: BASF SE

Inventor： HATSCHER, Stephan ,  HESSE, Michael ,  WABNITZ, Tobias ,  KÄSHAMMER, Stefan ,  PINKOS, Rolf

IPC: C08G65/26 ,  B01J21/16 ,  B01J23/74 ,  B01J20/12

CPC classification number: B01J21/16 ,  B01J23/40 ,  B01J23/745 ,  B01J23/75 ,  B01J37/0009 ,  B01J37/0036 ,  C08G65/10 ,  C08G65/20 ,  C08G65/2642

Abstract: The present invention provides a catalyst comprising a mixture of at least one acid-activated sheet silicate with a transition metal oxide of groups 8 and/or 9 of the Periodic Table of the Elements, and also a process for preparing polytetrahydrofuran, polytetrahydrofuran copolymers, diesters or monoesters of these polymers, characterized in that tetrahydrofuran is polymerized in the presence of at least one telogen and/or comonomers over such a catalyst.

公开(公告)号：EP3891115A1

公开(公告)日：2021-10-13

申请号：EP19809105.0

申请日：2019-12-02

Applicant: BASF SE

Inventor： WERNER, Albert ,  WENTINK, Annebart ,  KOKOLAKIS, Simon ,  WEICKGENANNT, Andreas ,  PINKOS, Rolf

IPC: C07C29/145 ,  C07C33/20 ,  B01J23/78

公开(公告)号：EP3679006A1

公开(公告)日：2020-07-15

申请号：EP18758629.2

申请日：2018-08-27

Applicant: BASF SE

Inventor： PINKOS, Rolf ,  WEIGUNY, Jens ,  BALDAMUS, Jens ,  SCHWARZ, Michael

IPC: C07C29/17

公开(公告)号：EP2004590B1

公开(公告)日：2018-07-04

申请号：EP07727808.3

申请日：2007-04-04

Applicant: BASF SE

Inventor： BAUDUIN, Christophe ,  FISCHER, Wolfgang ,  PINKOS, Rolf ,  SCHOLTEN, Edzard

IPC: C07C67/08 ,  C07C69/40 ,  C07D307/08 ,  C07D307/32 ,  C07C29/149 ,  C07C31/20

CPC classification number: C07C29/149 ,  C07C67/08 ,  C07D207/263 ,  C07D307/08 ,  C07D307/33 ,  Y02P20/127 ,  C07C69/40 ,  C07C31/12 ,  C07C31/207

公开(公告)号：EP3116845A1

公开(公告)日：2017-01-18

申请号：EP15709452.5

申请日：2015-03-05

Applicant: BASF SE

Inventor： PINKOS, Rolf ,  MARION, Nicolas ,  KRONEMAYER, Helmut

IPC: C07C29/141 ,  C07C29/90 ,  C07C31/20

CPC classification number: C07C29/141 ,  C07C29/90 ,  C07C31/20

Abstract: A method for the breakdown of formates in formate-containing substance mixtures, wherein the formate-containing substance mixtures are reacted in the presence of at least one lanthanum-containing heterogeneous catalyst at a temperature of 80 to 180 °C and at a pressure of 0.1 to 60 bar, and the formate-containing substance mixtures have a pH of 6.5 to 10. Formate-containing substance mixtures is understood to mean, in particular, substance mixtures comprising carbonyl compounds, which were formed, for example, by an aldol reaction of alkanones or alkanals with formaldehyde, such as, for example, methylolalkanals and the respective hydrogenation products thereof. Said products also contain formates in addition to the aforementioned carbonyl compounds.

Abstract translation: 在含甲酸盐的物质组合物中分解甲酸盐的方法包括在至少一种包含镧的非均相催化剂存在下，在80-180℃的温度和0.1至0.1的压力下反应含甲酸盐的物质组合物 60巴，含有甲酸盐的组合物，其pH为6.5至10

公开(公告)号：EP2244996B2

公开(公告)日：2015-11-11

申请号：EP09709624.2

申请日：2009-01-29

Applicant: BASF SE

Inventor： PINKOS, Rolf ,  SIRCH, Tilman ,  Dr. TEBBEN, Gerd-Dieter ,  FISCHER, Rolf-Hartmuth

IPC: C07C29/50 ,  C07C51/367 ,  C07C51/487 ,  C07C67/08 ,  C07C59/01 ,  C07C69/675 ,  C07C45/33

CPC classification number: C07C29/50 ,  C07C45/33 ,  C07C51/367 ,  C07C67/08 ,  C07C2601/14 ,  C07C49/403 ,  C07C59/01 ,  C07C69/675 ,  C07C35/08

公开(公告)号：EP2922819A1

公开(公告)日：2015-09-30

申请号：EP13792876.8

申请日：2013-11-12

Applicant: BASF SE

Inventor： PINKOS, Rolf ,  VOGLER, Thomas ,  OTT, Karl

IPC: C07D207/26

CPC classification number: C07D207/267

Abstract: The invention relates to a method for purifying N-alkylpyrrolidones that contain at least one of the contaminants of formula I or II, in which R stands for hydrogen or a C1 to C20 alkyl group, due to a prior use, characterized in that a basic compound is added to the N-alkylpyrrolidone to be purified and the temperature of the mixture is at least 80°C no later than 20 minutes after the addition of the basic compound and N-alkylpyrrolidone is removed from the obtained mixture by distillation.