Polymeric minus filter
    61.
    发明公开
    Polymeric minus filter 失效
    Minusfilter aus Polymermaterial。

    公开(公告)号:EP0540215A2

    公开(公告)日:1993-05-05

    申请号:EP92309434.6

    申请日:1992-10-15

    IPC分类号: G02B5/28 G02B1/10

    摘要: A polymeric minus filter for an incident electromagnetic spectral band comprises at least one polymeric interference stack tuned to a predetermined design wavelength centered around λ₀, wherein λ₀ is in the range of 300 nm to 2000 nm, said filter comprises an optically transparent substrate and having deposited thereon at ambient temperatures (20 to 23°C) a multiplicity of pairs of polymeric thin interference layers plus one final polymeric layer having index of refraction n₂, each pair of interference layers having a total optical thickness equal to 1/2 wavelength of λ₀, the members of each pair having refractive indices n₁ and n₂, respectively, wherein the layer having refractive index n₂ is directly superimposed upon said substrate having refractive index n s and wherein n s is approximately equal to n₁, and wherein n₂

    摘要翻译: 用于入射电磁光谱带的聚合负滤波器包括至少一个调谐到以g 4为中心的预定设计波长的聚合物干涉叠层,其中g 4在300nm至2000nm的范围内,所述滤光器包括 光学透明基底并且在环境温度(20至23℃)下沉积有多对聚合物薄干涉层加上具有折射率n 6的最终聚合物层,每对干涉层具有总光学厚度 等于1/2波长的g <4>,每对的构件分别具有折射率n 5和n 6,其中具有折射率n <6的层直接叠加在具有折射率 索引ns,其中ns近似等于n 5,并且其中n 6

    Antistatic film and method of manufacturing the same
    63.
    发明公开
    Antistatic film and method of manufacturing the same 失效
    Antistatische Folie und Verfahren zur Herstellung。

    公开(公告)号:EP0511650A1

    公开(公告)日:1992-11-04

    申请号:EP92107306.0

    申请日:1992-04-29

    IPC分类号: C09K3/16 C09D5/24

    摘要: An antistatic film comprising a chemically adsorbed film of straight chain molecules each containing a conductive group and provided on a chargeable substrate via covalent bonds each containing a Si group, said chemically adsorbed film having a conductivity of 10⁻¹⁰ S/cm or above. With the antistatic chemically adsorbed film according to the invention, conductive functional groups are secured via chemically adsorbed molecules and by siloxane bonds to the surface of a substrate material such as ceramics, glass, synthetic resins or synthetic fibers, a film, a plate, an display screen surface, a light-emitting tube. Thus, the film provides an antistatic effect and does not separate. In addition, this chemically adsorbed film has a thickness at the nanometer level and is thus excellently transparent, as well as capable of preventing contamination of the substrate surface due to charging thereof. The film is also excellently durable. Further, when a chemically adsorbed polymer film is formed, a high molecular density, chemically adsorbed film can be obtained.

    摘要翻译: 一种抗静电膜,其包含各自含有导电基团的直链分子的化学吸附膜,并且通过各自含有Si基团的共价键在带电基材上提供,所述化学吸附膜具有10 <1> S / cm以上。 根据本发明的抗静电化学吸附膜,通过化学吸附分子和硅氧烷键将导电官能团固定在基材材料如陶瓷,玻璃,合成树脂或合成纤维的表面上,膜,板, 显示屏表面,发光管。 因此,该胶片提供抗静电效果并且不分离。 此外,该化学吸附膜的厚度为纳米级,因此具有优异的透明性,并且能够防止由于其充电而导致的基板表面的污染。 这部电影也非常耐用。 此外,当形成化学吸附的聚合物膜时,可以获得高分子密度的化学吸附膜。

    Functional laminated chemically adsorbed films and methods of manufacturing the same
    64.
    发明公开
    Functional laminated chemically adsorbed films and methods of manufacturing the same 失效
    Funktionell laminierte,化学吸附剂Schicht und Verfahren zu deren Herstellung。

    公开(公告)号:EP0511590A1

    公开(公告)日:1992-11-04

    申请号:EP92106959.7

    申请日:1992-04-23

    发明人: Ogawa, Kazufumi

    IPC分类号: B05D1/18

    摘要: According to the invention, molecules having conductive, photofunctional and other functions are secured by chemical bonds to a substrate via a chemically adsorbed monomolecular film by an adsorption process. The process comprises a step of contacting the substrate with a non-aqueous solution containing a material. The material includes a straight chain molecules having a plurality of chlorosilyl groups at both ends. A reaction occures between hydroxyl groups on the substrate surface and chlorosilyl groups at one of the ends of the material having the chlorosilyl groups. Prior to the reaction the substrate is washed with a non-aqueous organic solution by dipping the substrate in a non-aqueous solution containing molecules having a specific function for causing the reaction of the molecules with the chlorosilyl groups at the other end of the molecules having the chlorosilyl groups, thereby securing the molecules to the surface of the substrate.

    摘要翻译: 根据本发明,具有导电性,光官能性和其它功能的分子通过化学键通过吸附过程通过化学吸附的单分子膜而固定到基底上。 该方法包括使基底与含有材料的非水溶液接触的步骤。 该材料包括在两端具有多个氯甲硅烷基的直链分子。 基材表面的羟基与具有氯甲硅烷基的材料的一端的氯甲硅烷基之间发生反应。 在反应之前,用非水有机溶液洗涤底物,将底物浸入含有分子的非水溶液中,所述分子具有特定功能,使分子与分子的另一端的氯代甲硅烷基反应, 氯甲硅烷基,从而将分子固定在基材的表面上。

    Polysilane monomolecular film and polysilane built-up film
    66.
    发明公开
    Polysilane monomolecular film and polysilane built-up film 失效
    Monocolekularer Polysilanfilm und aus Polysilanschichten aufgebauter Film。

    公开(公告)号:EP0506425A2

    公开(公告)日:1992-09-30

    申请号:EP92302664.5

    申请日:1992-03-26

    IPC分类号: B05D1/20 C09D183/16

    摘要: Disclosed are a polysilane monomolecular film and a polysilane built-up fllm formed by building up a plurality of said monomolecular films, said monomolecular film consisting of a polysilane having a repeating unit represented by general formula (1) given below:

       where, R¹ represents a substituted or unsubstituted alkyl group having 1 to 24 carbon atoms or a substituted or unsubstituted aryl group having 6 to 24 carbon atoms, R² represents a divalent hydrocarbon group having 1 to 24 carbon atoms which can be substituted, and X represents hydroxyl group, amino group, carboxyl group, or a hydrophilic group having at least one selected from the group consisting of hydroxyl group, amino group, carboxyl group, amide linkage, easter linkage, carbamate linkage and carbonate bond. The polysilane monomolecular film and built-up film can be formed on a substrate by an LB technique. In the films, the molecules of the polysilane having the repeating unit (1), that is, the Si-Si backbones are oriented in a fixed direction.

    摘要翻译: 公开了通过构建多个所述单分子膜而形成的聚硅烷单分子膜和聚硅烷,所述单分子膜由具有下述通式(1)表示的重复单元的聚硅烷构成; 其中,R 1表示具有1至24个碳原子的取代或未取代的烷基或具有6至24个碳原子的取代或未取代的芳基,R 2表示具有1至24个碳原子的二价烃基 可以被取代的原子,X表示羟基,氨基,羧基或具有选自羟基,氨基,羧基,酰胺键,复数线性化合物,氨基甲酸酯键的至少一种的亲水基团, 碳酸盐键。 可以通过LB技术在基板上形成聚硅烷单分子膜和积层膜。 在膜中,具有重复单元(1)的聚硅烷的分子,即Si-Si主链在固定方向上取向。

    Chromophore-containing compounds for opto-electronic applications
    67.
    发明公开
    Chromophore-containing compounds for opto-electronic applications 失效
    用于光电子应用的含色素化合物

    公开(公告)号:EP0474402A3

    公开(公告)日:1992-05-27

    申请号:EP91307718.6

    申请日:1991-08-21

    IPC分类号: G02F1/35 C09B23/14 C09B17/00

    摘要: The use of a multi-functional, chromophore containing, polymerisable compound for producing an optical element having non-linear optical properties (an NLO element) wherein the multi-functional chromophore is a compound capable of being polymerised into a cross-linked network and of being poled under the influence of an electric field whilst being polymerised into the cross-linked network, the compound having the generalised formula (D) (C) (A) (F) D, C, A and F representing covalently linked moieties where C represents at least one conjugated system of π-bonds,
    A and D represent at least one respectively π-electron acceptor and π -electron donor groups linked at opposite ends of the conjugated system, and are preferably conjugated with the conjugated system of π-bonds (C) and where more than one moiety A, C or D is present they may be the same or different,
    F represents at least two polymerisable functional groups, which may be the same or different, attached to the π-conjugated system C or the groups A and D via substituent groups R₁ and R₂, where R₁ and R₂ are selected from alkyl, cycloalkyl, aryl heteroalkyl, alkenyl, cycloalkenyl, and alkynyl including groups which have been substituted or contain heteroatom replacement, the groups F being linked to the compound so that after the compound has been polymerised to give a cross-linked network the interpolymerised functional groups prevent significant realignment of the chromophore groups when the optical element is subject to temperature changes during any further fabrication and in use.

    Chemically adsorbed monomolecular lamination film and method of manufacturing the same
    68.
    发明公开
    Chemically adsorbed monomolecular lamination film and method of manufacturing the same 失效
    Durch chemische吸附层压机单功能胶片和Verfahren zu seiner Herstellung。

    公开(公告)号:EP0484746A2

    公开(公告)日:1992-05-13

    申请号:EP91118094.1

    申请日:1991-10-23

    摘要: The invention to provide a chemically adsorbed monomolecular lamination film comprising a chemically adsorbed monomolecular film formed via a siloxane-based monomolecular or polymer film on a substrate surface. It also seeks to provide a method of forming a chemically adsorbed monomolecular film efficiently and with high density on a substrate surface with few hydroxyl groups, which method comprises a step of contacting a substrate containing hydroxyl groups present on the surface with a non-aqueous solution containing a material with plural chlorosilanol groups in molecule, a step of removing the material remaining on the substrate without reaction by washing the substrate with a non-aqueous organic solution (if this process is omitted, the siloxane-based polymer film is prepared on the substrate), a step of forming a monomolecular film constituted by a compound containing a silanol group in molecule on the substrate by exposing to the air containing moisture or washing with water, after the removal step, and a step of laminating a monomolecular adsorption film by adosorbing a chlorosilane-based surface active agent constituted by a straight hydrocarbon chain having a chlorosilane groups at one end onto the substrate after the monomolecular or polymer film formation step.

    摘要翻译: 本发明提供一种化学吸附的单分子层叠膜,其包含在基材表面上通过基于硅氧烷的单分子或聚合物膜形成的化学吸附的单分子膜。 它还寻求提供一种在几乎没有羟基的基板表面上有效且高密度地形成化学吸附的单分子膜的方法,该方法包括使表面存在的羟基的基材与非水溶液接触的步骤 含有分子中具有多个氯硅烷醇基团的材料,通过用非水有机溶液洗涤基材而除去残留在基材上的材料而不反应的步骤(如果省略该方法,则将硅氧烷基聚合物膜制备在 底物),在除去步骤之后,通过暴露于含有水分的空气或用水洗涤,在分子中分子内含有硅烷醇基的化合物构成的单分子膜的步骤,以及将单分子吸附膜层叠 将由具有氯代硅烷基团的直链烃链构成的氯硅烷基表面活性剂掺杂 在单分子或聚合物膜形成步骤之后的一端到基底上。

    Formation of organic membranes
    69.
    发明公开
    Formation of organic membranes 失效
    有机膜的形成

    公开(公告)号:EP0385506A3

    公开(公告)日:1991-11-13

    申请号:EP90104120.2

    申请日:1990-03-02

    发明人: Mino, Norihisa

    IPC分类号: B05D1/20 H01B1/12 G03F7/16

    摘要: The method of the present invention for forming a monomolecular membrane on a substrate comprises the steps of
    (1) mixing
    (a) at least one substance having a water-­soluble polar head (hydrophilic portion) and a water-­insoluble organic tail (hydrophobic portion) in the molecule, the head being ionizable into a cation when spread on water, and (b) at least one substance having a water-­soluble polar head (hydrophilic portion) and a water-­insoluble organic tail (hydrophobic portion) in the molecule, the head being ionizable into an anion when spread on water, to obtain a mixture, (2) developing the mixture on an aqueous subphase to form a monomolecular layer, and (3) transferring the monomolecular layer to a substrate while applying a surface pressure to the layer. According to the present invention, there can be formed a unidimensionally controlled membrane which develops a higher function than do the conventional two-­dimensionally controlled membranes. Consequently, the method of the present invention can be applied, for example, to the formation of wiring patterns of a molecular level.