METHOD FOR PREPARING METHYL FORMATE
    81.
    发明公开
    METHOD FOR PREPARING METHYL FORMATE 审中-公开
    制备甲酸甲酯的方法

    公开(公告)号:EP3222608A1

    公开(公告)日:2017-09-27

    申请号:EP14906314.1

    申请日:2014-11-17

    摘要: This application relates to a method for preparing methyl formate. A raw material containing formaldehyde, methanol and/or dimethyl ether is introduced into a first reaction zone to come into contact with a catalyst A, and a component I is obtained by separation. The component I is introduced into a second reaction zone to come into contact with a catalyst B so as to obtain, by separation, methyl formate as a product, dimethyl ether that is returned to the first reaction zone and a component II that is returned to the second reaction zone. The ratio of formaldehyde, methanol and/or dimethyl ether in the raw material is formaldehyde:methanol and/or dimethyl ether = 1:2-4 based on the mole number of carbon atoms contained in respective component; the mass hourly space velocity of formaldehyde in the raw material is 0.01-15.0 h -1 ; the temperature is 50-100°C in the first reaction zone; the temperature is 50-200°C and the pressure is 0.1-10 Mpa in the second reaction zone; and the components are each independently in a gas phase and/or a liquid phase. In the present application, the catalysts have a long service life, the reaction conditions are mild, and the utilization rate of the raw material is high, and thus the invention enables a continuous production and has the potential for large-scale industrial application.

    摘要翻译: 本申请涉及制备甲酸甲酯的方法。 将含有甲醛,甲醇和/或二甲醚的原料引入到第一反应区中以与催化剂A接触,并通过分离获得组分I. 将组分I引入第二反应区以与催化剂B接触,从而通过分离获得作为产物的甲酸甲酯,返回到第一反应区的二甲醚和返回到第二反应区的组分II 第二反应区。 基于各组分中所含碳原子的摩尔数,原料中甲醛,甲醇和/或二甲醚的比例为甲​​醛:甲醇和/或二甲醚= 1:2-4; 原料中甲醛的质量空速为0.01-15.0 h-1; 在第一反应区中温度为50-100℃; 第二反应区温度为50-200℃,压力为0.1-10MPa; 并且这些组分各自独立地处于气相和/或液相中。 在本申请中,催化剂使用寿命长,反应条件温和,原料利用率高,因此本发明可以连续生产,具有大规模工业应用的潜力。

    THERMOPLASTIC ELASTOMER RESIN COMPOSITION
    85.
    发明公开
    THERMOPLASTIC ELASTOMER RESIN COMPOSITION 审中-公开
    热塑弹性体弹性体

    公开(公告)号:EP3070123A4

    公开(公告)日:2017-05-17

    申请号:EP14861760

    申请日:2014-11-11

    申请人: DENKA COMPANY LTD

    摘要: [Problem] To provide a thermoplastic elastomer resin composition that excels in tensile breaking strength, softness, oil resistance and scratch resistance, and that has good heat fusion ability with respect to polyolefin resins. [Solution] A thermoplastic elastomer resin composition consisting of: 15 to 89 mass% of a cross-copolymer having a polymer consisting of aromatic vinyl monomer units as a cross-chain structure on an aromatic vinyl-olefin-aromatic polyene copolymer main chain consisting of 9.99 to 29.99 mmol% of aromatic vinyl monomer units, 70 to 90 mmol% of olefin monomer units and 0.01 to 0.5 mmol% of aromatic polyene monomer units; 1 to 55 mass% of a hydrogenated block copolymer; and 10 to 60 mass% of a polypropylene resin.

    摘要翻译: 本发明提供一种热塑性弹性体树脂组合物,该组合物具有优异的拉伸断裂强度,柔软性,耐油性和耐擦伤性,并且对聚烯烃树脂具有良好的热熔性。 一种热塑性弹性体树脂组合物,其由芳香族乙烯基 - 烯烃 - 芳香族多烯共聚物主链上具有由芳香族乙烯基单体单元构成的聚合物作为交联结构的交联共聚物15〜89质量% 9.99至29.99mmol%的芳族乙烯基单体单元,70至90mmol%的烯烃单体单元和0.01至0.5mmol%的芳族多烯单体单元; 1至55质量%的氢化嵌段共聚物; 和10〜60质量%的聚丙烯树脂。

    PRODUCTION METHOD FOR PHOTOCHROMIC OPTICAL MATERIAL
    89.
    发明公开
    PRODUCTION METHOD FOR PHOTOCHROMIC OPTICAL MATERIAL 有权
    HERSTELLUNGSVERFAHRENFÜREIN PHOTOCHROMES OPTISCHES MATERIAL

    公开(公告)号:EP3029123A1

    公开(公告)日:2016-06-08

    申请号:EP14831346.3

    申请日:2014-08-01

    发明人: RYU Akinori

    摘要: The process for producing photochromic optical materials of the present invention includes a step (i) of reacting at least one polymerizable monomer (A) having two or more ethylene-based unsaturated groups with at least one polythiol (B) having two or more mercapto groups to obtain a prepolymer; a step (ii) of mixing the prepolymer and a photochromic compound (C) to obtain a polymerizable composition; and a step (iii) of polymerizing the polymerizable composition, wherein, before the reaction of the step (i), the molar number of the mercapto groups included in the polythiol (B) is smaller than the molar number of the ethylene-based unsaturated groups included in the polymerizable monomer (A).

    摘要翻译: 本发明的光致变色光学材料的制造方法包括使至少一种具有2个以上的乙烯系不饱和基的可聚合单体(A)与至少一个具有两个以上巯基的多硫醇(B)反应的工序(i) 得到预聚物; 将预聚物和光致变色化合物(C)混合以获得可聚合组合物的步骤(ii); 和聚合组合物的步骤(iii),其中在步骤(i)的反应之前,包括在多硫醇(B)中的巯基的摩尔数小于乙烯类不饱和摩尔数的摩尔数 包含在可聚合单体(A)中的基团。