摘要:
This application relates to a method for preparing methyl formate. A raw material containing formaldehyde, methanol and/or dimethyl ether is introduced into a first reaction zone to come into contact with a catalyst A, and a component I is obtained by separation. The component I is introduced into a second reaction zone to come into contact with a catalyst B so as to obtain, by separation, methyl formate as a product, dimethyl ether that is returned to the first reaction zone and a component II that is returned to the second reaction zone. The ratio of formaldehyde, methanol and/or dimethyl ether in the raw material is formaldehyde:methanol and/or dimethyl ether = 1:2-4 based on the mole number of carbon atoms contained in respective component; the mass hourly space velocity of formaldehyde in the raw material is 0.01-15.0 h -1 ; the temperature is 50-100°C in the first reaction zone; the temperature is 50-200°C and the pressure is 0.1-10 Mpa in the second reaction zone; and the components are each independently in a gas phase and/or a liquid phase. In the present application, the catalysts have a long service life, the reaction conditions are mild, and the utilization rate of the raw material is high, and thus the invention enables a continuous production and has the potential for large-scale industrial application.
摘要:
Hydrolyzed divinylbenzene/maleic anhydride polymeric materials and methods of making these polymeric materials are provided. These polymers have a high BET specific surface area that results from the presence of micropores and/or mesopores. The polymers are useful for the adsorption of low molecular weight (e.g., no greater than 150 gram/mole), basic nitrogen-containing compounds.
摘要:
Synthetic nanocomposites in microparticle form allowing great deformation before breaking, especially useful for the preparation of synthetic low density proppants to be used in unconventional extraction processes of oil and gas (fracking). The process to obtain said nanocomposites, proppants and fracture fluids for extraction processes of oil and gas is also described.
摘要:
[Problem] To provide a thermoplastic elastomer resin composition that excels in tensile breaking strength, softness, oil resistance and scratch resistance, and that has good heat fusion ability with respect to polyolefin resins. [Solution] A thermoplastic elastomer resin composition consisting of: 15 to 89 mass% of a cross-copolymer having a polymer consisting of aromatic vinyl monomer units as a cross-chain structure on an aromatic vinyl-olefin-aromatic polyene copolymer main chain consisting of 9.99 to 29.99 mmol% of aromatic vinyl monomer units, 70 to 90 mmol% of olefin monomer units and 0.01 to 0.5 mmol% of aromatic polyene monomer units; 1 to 55 mass% of a hydrogenated block copolymer; and 10 to 60 mass% of a polypropylene resin.
摘要:
Embodiments of the present invention provide for anion exchange membranes and processes for their manufacture. The anion exchange membranes described herein are made the polymerization product of at least one functional monomer comprising a tertiary amine which is reacted with a quaternizing agent in the polymerization process.
摘要:
Polymers for use as protective layers and other components in electrochemical cells are provided. In some embodiments, the electrochemical cell is a lithium-based electrochemical cell.
摘要:
The process for producing photochromic optical materials of the present invention includes a step (i) of reacting at least one polymerizable monomer (A) having two or more ethylene-based unsaturated groups with at least one polythiol (B) having two or more mercapto groups to obtain a prepolymer; a step (ii) of mixing the prepolymer and a photochromic compound (C) to obtain a polymerizable composition; and a step (iii) of polymerizing the polymerizable composition, wherein, before the reaction of the step (i), the molar number of the mercapto groups included in the polythiol (B) is smaller than the molar number of the ethylene-based unsaturated groups included in the polymerizable monomer (A).
摘要:
The invention relates to production of sorbents. The proposed method of production involves acylation of a macroporous styrene-divinylbenzene copolymer in the presence of the Friedel-Crafts catalyst - aluminum chloride. The acylation reaction is carried out using acetyl chloride in a dichloroethane solvent at boiling the solution. This is followed by phosphorylation of the obtained acylated copolymer with phosphorus trichloride at room temperature; the product is hydrolyzed with water, washed and dried. The technical result consists in production of a complexing adsorbent highly selective for scandium and simplification of the production process.