SYSTEM AND METHOD FOR PURIFYING AND PREPARING HIGH-PURITY VANADIUM PENTOXIDE POWDER
    89.
    发明公开
    SYSTEM AND METHOD FOR PURIFYING AND PREPARING HIGH-PURITY VANADIUM PENTOXIDE POWDER 审中-公开
    用于净化和制备高纯度五氧化二钒粉末的系统和方法

    公开(公告)号:EP3252014A1

    公开(公告)日:2017-12-06

    申请号:EP16742784.8

    申请日:2016-01-28

    IPC分类号: C01G31/02

    摘要: The present invention provides a system and method for purifying and preparing vanadium pentoxide powder. Industrial grade vanadium pentoxide is converted to vanadium oxytrichloride by low temperature fluidizing chlorination, wherein chlorinating gas is preheated via heat exchange between fluidizing gas and chlorination flue gas, and an appropriate amount of air is added to enable a part of carbon powder to combust so as to achieve a balanced heat supply during the chlorination, thereby increasing the efficiency of chlorination and ensuring good selectivity in low temperature chlorination. The vanadium oxytrichloride is purified by rectification, and then subjected to fluidized gas phase ammonification, thereby obtaining ammonium metavanadate, and further obtaining a high-purity vanadium pentoxide powder product through fluidized calcination. The system and method have advantages of favorable adaptability to a raw material, no discharge of contaminated wastewater, low energy consumption and chlorine consumption in production, stable product quality and so on.

    摘要翻译: 本发明提供了用于纯化和制备五氧化钒粉末的系统和方法。 通过低温流化氯化将工业级五氧化二钒转化为三氯氧化钒,其中通过流化气体与氯化烟气之间的热交换预热氯化气体,并加入适量的空气以使一部分碳粉燃烧 在氯化过程中实现均衡供热,从而提高氯化效率并确保低温氯化中的良好选择性。 通过精馏纯化三氯氧化钒,然后进行流化气相氨化,由此获得偏钒酸铵,并通过流化煅烧进一步获得高纯度五氧化二钒粉末产物。 该系统和方法具有对原料适应性好,污染废水不排放,生产能耗低,耗氯量少,产品质量稳定等优点。

    SYSTEM AND METHOD FOR PRODUCING HIGH-PURITY VANADIUM TETRAOXIDE POWDER
    90.
    发明公开
    SYSTEM AND METHOD FOR PRODUCING HIGH-PURITY VANADIUM TETRAOXIDE POWDER 审中-公开
    用于生产高纯度钒酸四氧化物粉末的系统和方法

    公开(公告)号:EP3252013A1

    公开(公告)日:2017-12-06

    申请号:EP16742781.4

    申请日:2016-01-28

    IPC分类号: C01G31/02

    摘要: The present invention provides a system and method for producing high-purity vanadium tetraoxide powder. Industrial grade vanadium pentoxide is converted to vanadium oxytrichloride by low temperature fluidizing chlorination, wherein chlorinating gas is preheated via heat exchange between fluidizing gas and chlorination flue gas, and an appropriate amount of air is added to enable a part of carbon powder to combust so as to achieve a balanced heat supply during the chlorination, thereby increasing the efficiency of chlorination and ensuring good selectivity in low temperature chlorination. The vanadium oxytrichloride is purified by rectification, and then subjected to fluidized gas phase hydrolyzation, thereby producing a high-purity vanadium pentoxide product and a by-product solution of hydrochloric acid, and further obtaining a high-purity vanadium tetraoxide powder product through fluidized hydrogen reduction. The system and method have advantages of favorable adaptability to a raw material, no discharge of contaminated wastewater, low energy consumption and chlorine consumption in production, stable product quality and so on.

    摘要翻译: 本发明提供了生产高纯度四氧化钒粉末的系统和方法。 通过低温流化氯化将工业级五氧化二钒转化为三氯氧化钒,其中通过流化气体与氯化烟气之间的热交换预热氯化气体,并加入适量的空气以使一部分碳粉燃烧 在氯化过程中实现均衡供热,从而提高氯化效率并确保低温氯化中的良好选择性。 通过精馏纯化三氯氧化钒,然后进行流化气相水解,由此生产高纯度五氧化二钒产品和盐酸副产品溶液,并且进一步通过流化氢气获得高纯度四氧化钒粉末产品 减少。 该系统和方法具有对原料适应性好,污染废水不排放,生产能耗低,耗氯量少,产品质量稳定等优点。