摘要:
The present invention relates to the use of cryolithionite-based lithium-containing fluorides having a garnet crystal structure in electrochemical applications, wherein the use is selected from the group consisting of the use in an electrochemical storage and/or conversion device, the use in an electrode, and the use as electrode material comprised in an electrode. The present invention also relates to novel lithium-containing fluorides which are suitable for these uses as well as to processes for preparing these fluorides.
wherein, in Formula 1, A is a monovalent cation, G is at least one of a monovalent cation, a divalent cation, a trivalent cation, a tetravalent cation, a pentavalent cation, or a hexavalent cation, with the proviso that G is not Ti or Cr, wherein 0
摘要:
A process for producing a metal oxide powder comprising: providing a precursor solution or dispersion containing a metal complex;spraying the precursor solution on to a heated substrate in the presence of water, thereby depositing material on the substrate; drying the deposited material; and removing the deposited material from the substrate to produce the metal oxide powder.
摘要:
The present invention provides a system and method for producing high-purity vanadium tetraoxide powder. Industrial grade vanadium pentoxide is converted to vanadium oxytrichloride by low temperature fluidizing chlorination, wherein chlorinating gas is preheated via heat exchange between fluidizing gas and chlorination flue gas, and an appropriate amount of air is added to enable a part of carbon powder to combust so as to achieve a balanced heat supply during the chlorination, thereby increasing the efficiency of chlorination and ensuring good selectivity in low temperature chlorination. The vanadium oxytrichloride is purified by rectification, and then subjected to fluidized gas phase hydrolyzation, thereby producing a high-purity vanadium pentoxide product and a by-product solution of hydrochloric acid, and further obtaining a high-purity vanadium tetraoxide powder product through fluidized hydrogen reduction. The system and method have advantages of favorable adaptability to a raw material, no discharge of contaminated wastewater, low energy consumption and chlorine consumption in production, stable product quality and so on.
摘要:
VO2 and V2O5 nano- or micro-materials. The VO2 nano-materials and micro-materials have an M1 phase structure and oxygen stoichiometry that deviates 2% or less from theoretical stoichiometry. The VO2 nano-materials and micro-materials may doped with cation dopants and/or anion dopants. The VO2 and V2O5 nano- or micro-materials can be made by hydrothermal methods starting with V3O7.H2O nano- or micro-material. The VO2 and V2O5 nano- or micro-materials can be used as, for example, thermochromic window coatings.
摘要:
A method for treating a liquid redox electrolyte solution for use in a flow battery includes feeding a liquid redox electrolyte solution into a first half-cell of an electrochemical cell and feeding a gaseous reductant into a second half-cell of the electrochemical cell, and electrochemically reducing at least a portion of the liquid redox electrolyte solution in the electrochemical cell using the gaseous reductant.
摘要:
The present invention provides a system and method for producing high-purity vanadium tetraoxide powder. Industrial grade vanadium pentoxide is converted to vanadium oxytrichloride by low temperature fluidizing chlorination, wherein chlorinating gas is preheated via heat exchange between fluidizing gas and chlorination flue gas, and an appropriate amount of air is added to enable a part of carbon powder to combust so as to achieve a balanced heat supply during the chlorination, thereby increasing the efficiency of chlorination and ensuring good selectivity in low temperature chlorination. The vanadium oxytrichloride is purified by rectification, and then subjected to fluidized gas phase hydrolyzation, thereby producing a high-purity vanadium pentoxide product and a by-product solution of hydrochloric acid, and further obtaining a high-purity vanadium tetraoxide powder product through fluidized hydrogen reduction. The system and method have advantages of favorable adaptability to a raw material, no discharge of contaminated wastewater, low energy consumption and chlorine consumption in production, stable product quality and so on.
摘要:
The present invention provides a system and method for purifying and preparing vanadium pentoxide powder. Industrial grade vanadium pentoxide is converted to vanadium oxytrichloride by low temperature fluidizing chlorination, wherein chlorinating gas is preheated via heat exchange between fluidizing gas and chlorination flue gas, and an appropriate amount of air is added to enable a part of carbon powder to combust so as to achieve a balanced heat supply during the chlorination, thereby increasing the efficiency of chlorination and ensuring good selectivity in low temperature chlorination. The vanadium oxytrichloride is purified by rectification, and then subjected to fluidized gas phase ammonification, thereby obtaining ammonium metavanadate, and further obtaining a high-purity vanadium pentoxide powder product through fluidized calcination. The system and method have advantages of favorable adaptability to a raw material, no discharge of contaminated wastewater, low energy consumption and chlorine consumption in production, stable product quality and so on.
摘要:
The present invention provides a system and method for producing high-purity vanadium tetraoxide powder. Industrial grade vanadium pentoxide is converted to vanadium oxytrichloride by low temperature fluidizing chlorination, wherein chlorinating gas is preheated via heat exchange between fluidizing gas and chlorination flue gas, and an appropriate amount of air is added to enable a part of carbon powder to combust so as to achieve a balanced heat supply during the chlorination, thereby increasing the efficiency of chlorination and ensuring good selectivity in low temperature chlorination. The vanadium oxytrichloride is purified by rectification, and then subjected to fluidized gas phase hydrolyzation, thereby producing a high-purity vanadium pentoxide product and a by-product solution of hydrochloric acid, and further obtaining a high-purity vanadium tetraoxide powder product through fluidized hydrogen reduction. The system and method have advantages of favorable adaptability to a raw material, no discharge of contaminated wastewater, low energy consumption and chlorine consumption in production, stable product quality and so on.