摘要:
Microemulsions are provided in which the oil phase comprises a reaction product of an organosilicon compound having amino groups and an organosilicon compound having epoxy groups, wherein the reaction product has at least one amino group and two silicon-bonded -OR groups. A method for making the microemulsions which comprises reacting the two organosilicon compounds sufficiently to allow the reaction of some of the amine groups with the epoxy groups, but avoiding the excessive crosslinking of the components and their application in the treatment of fibrous materials is also described.
摘要:
Microemulsions are provided in which the oil phase comprises a reaction product of an organosilicon compound having amino groups and an organosilicon compound having epoxy groups, wherein the reaction product has at least one amino group and two silicon-bonded -OR groups. A method for making the microemulsions which comprises reacting the two organosilicon compounds sufficiently to allow the reaction of some of the amine groups with the epoxy groups, but avoiding the excessive crosslinking of the components and their application in the treatment of fibrous materials is also described.
摘要:
Flexible polyester film is coated with a silicone release coating by applying and curing a solventless composition which comprises a polydiorganosiloxane having solely in its terminal units hydroxyl or alkenyl groups, an organohydrogen siloxane crosslinker and a catalyst which is preferably a Pt compound. The ratio of SiH groups over the hydroxyl or alkenyl groups is at least 2/1. The release coating adheres well to the polyester film without the need to pretreat the film with electron beam irradiation.
摘要:
A method for making siloxane resins consisting essentially of tetravalent Si0 2 units and monovalent R 3 SiO 0.5 and H s R 3s , SiO 0.5 units wherein each R denotes an alkyl group or an aryl group having less than 9 carbon atoms and a denotes 1 or 2, comprises reacting in the presence of an acidic catalyst a siloxane resin consisting essentially of R 3 SiO 0.5 units and SiO 2 units with (H a R 3-a Si) 2 O, where R and a are as defined above. Novel resins wherein only 0.1 to 30 percent of the monovalent units have SiH groups are also disclosed.
摘要翻译:一种制备基本上由四价SiO 2单元和一价的R 3 SiO 0.5和HaR 3 a SiO 0.5单元组成的硅氧烷树脂的方法,其中每个R表示烷基或具有小于9个碳原子的芳基,a表示1或2,包括使 酸性催化剂的存在基本上由R3SiO0.5单元组成的硅氧烷树脂和具有(HaR 3-a Si)2 O的SiO 2单元,其中R和a如上所定义。 还公开了其中仅0.1%至30%的一价单元具有SiH基团的新型树脂。
摘要:
Organosilicon compounds which are silanes or siloxanes characterised by the presence of silicon-bonded groups of the formula in which X represents -OH, -OCH 3 or OC 2 H 5 when p = 1 or -OH or dialkylamino when p = 0, n can be 0 or 1 and p = 0 or 1. The compounds are prepared by the reaction of a silane or siloxane containing silicon-bonded hydrogen with a compound
摘要:
Surface active silicone compounds which have an improved stability at a pH above 9 or below 4, have the general formula wherein each R independently represents an alkyl or aryl group, each R′ represents an alkylene group preferably separating neighbouring silicon atoms by up to 3 carbon atoms, each R˝ independently denotes R or, only if a is 0, the group R₃SiR′-, Z represents a hydrophilic sulphur, nitrogen or phosphor containing substituent or a carboxy-functional group or a salt thereof, and a has the value 0, 1 or 2.
摘要翻译:在pH高于9或低于4的情况下具有改善的稳定性的表面活性硅氧烷化合物具有通式,其中每个R独立地表示烷基或芳基,每个R min表示亚烷基,优选将相邻的硅原子分开 至3个碳原子,每个R sec独立地表示R,或者只有a为0时,基团R 3 SiR min - ,Z表示亲水性硫,氮或含荧光体的取代基或羧基官能团或其盐,并且具有 值0,1或2。
摘要:
Improved pharmaceutical delivery devices which can deliver hydrophilic or polar pharmaceutically active materials, as well as optionally hydrophobic or non-polar materials, have small particles with on average a diameter below 20 microns of a drug component comprising the hydrophilic or polar pharmaceutically active material, dispersed in a silicone matrix. These devices are produced by using certain organopolysiloxane-polyoxyalkylene copolymers. Preferably an emulsion of the drug component in a silicone containing composition is made before curing the composition to an elastomer.
摘要:
An articulated prosthesis for a joint such as for a finger. The prosthesis, capable of joining two bones, basically consists of two stems (4, 5), each having a bearing component integral with one end which together form a hinged joint pivotable about an axis. Snap on coupling means integral with a hinge pin component is provided on each side of the bearing.
摘要:
A siloxane treating composition comprises (1) a mixture and/or a reaction product of (A) a polydiorganosiloxane having at least one silicon-bonded -OX group, X being H, alkyl or alkoxyalkyl and at least one silicon-bonded aminoalkyl or polyaminoalkyl acid salt group, and (B) a silicon compound having more than 2 silicon-bonded groups which are reactive with -OX of (A), and (2) a water-soluble solvent for (A) which comprises one or both glycol ethers of the formula C 4 H 9 -O-(CH 2 -CH 2 -O) n H where n is 1 or 2. These compositions have improved penetration ability and stability, especially when used as aqueous composition for rendering substrates, such as masonry, hydrophobic. Also claimed is a process for making such compositions and a process for applying them to substrates.
摘要:
Siloxane-polyester compositions comprising (1) a siloxane-polyester copolymer resin (2) one or more solvents forthe siloxane-polyester copolymer, (3) a silane wherein one of the groups attached to silicon is an epoxy-substituted organic group, at least two of the remaining valencies of the silicon atom being satisfied by alkoxy or alkoxyalkoxy groups, and (4) a titanium chelate. The presence of (3) and (4) improvesthe rate of cure of the siloxane-polyester, and the compositions are useful for providing decorative and/or protective coatings on metals, plastics and other substrates.