公开(公告)号：EP2886678A1

公开(公告)日：2015-06-24

申请号：EP14199052.3

申请日：2014-12-18

申请人： EDISON S.p.A.

发明人： Bindi, Massimiliano

IPC分类号： C23C14/54 ,  C23C14/30 ,  C23C14/08 ,  C23C14/58

CPC分类号： C23C14/545 ,  C23C14/083 ,  C23C14/088 ,  C23C14/30 ,  C23C14/5806 ,  C23C14/5853 ,  H01M4/8867 ,  H01M4/8882 ,  H01M4/8885 ,  H01M4/9033 ,  H01M8/1213 ,  H01M8/1246 ,  H01M2008/1293 ,  Y02E60/525 ,  Y02P70/56

摘要： In a method for the deposition of a film of mixed oxide on a composite material substrate, a step of evaporation-deposition of the mixed oxide, carried out with the aid of an electron beam sent to a target of mixed oxide having the same stoichiometric composition as the film to deposit, is carried out at an increasing deposition rate, measured on the substrate; in particular, the evaporation-deposition step comprises at least one first step of growth carried out at a deposition rate lower than or equal to a predetermined threshold, and at least one second step of growth carried out at a deposition rate higher than the threshold.

摘要翻译： 在用于在复合材料基板上沉积混合氧化物膜的方法中，借助于发送到具有相同化学计量组成的混合氧化物靶的电子束进行蒸发沉积混合氧化物的步骤 作为沉积膜，以增加的沉积速率进行，在基底上测量; 特别地，蒸发沉积步骤包括以低于或等于预定阈值的沉积速率进行生长的至少一个第一步骤，以及以高于阈值的沉积速率进行的生长的至少一个第二步骤。

公开(公告)号：EP1361617B1

公开(公告)日：2008-03-05

申请号：EP03076342.9

申请日：2003-05-06

申请人： EDISON S.p.A.

发明人： Giunchi, Giovanni ,  Ceresara, Sergio

IPC分类号： H01L39/24

CPC分类号： H01L39/2487 ,  B82Y30/00 ,  C04B35/62272 ,  C04B2235/401 ,  C04B2235/421 ,  C04B2235/5284 ,  C04B2235/79 ,  Y10S505/704 ,  Y10T29/49014

公开(公告)号：EP2684977B1

公开(公告)日：2015-06-17

申请号：EP13175966.4

申请日：2013-07-10

申请人： Edison S.p.A.

发明人： Bindi, Massimiliano

IPC分类号： C23C14/16 ,  C23C14/58 ,  H01M8/02 ,  H01M8/12

CPC分类号： C23C14/16 ,  C23C14/5853 ,  H01M8/021 ,  H01M8/0217 ,  H01M8/0228 ,  H01M2008/1293

公开(公告)号：EP2684977A1

公开(公告)日：2014-01-15

申请号：EP13175966.4

申请日：2013-07-10

申请人： Edison S.p.A.

发明人： Bindi, Massimiliano

IPC分类号： C23C14/16 ,  C23C14/58 ,  H01M8/02

CPC分类号： C23C14/16 ,  C23C14/5853 ,  H01M8/021 ,  H01M8/0217 ,  H01M8/0228 ,  H01M2008/1293

摘要： The invention relates to a method for the formation of a protective film comprising a spinel of formula Mn x Co y O 4-δ , where x+y=3, on a metallic substrate, characterised in that it comprises the steps of:
a) depositing on the substrate manganese and cobalt as metal species in a molar ratio x/y corresponding to the above-mentioned formula by thermal co-evaporation; and
b) oxidising in situ the metal species to form the spinel. The method is applied in particular for the coating of metal interconnections for solid oxide fuel cells (SOFC).

摘要翻译： 本发明涉及在金属基底上形成包含式Mn x Co y O 4-'尖晶石的保护膜的方法，其中x + y = 3，其特征在于它包括以下步骤：a） 通过热共蒸发，以与上述式相对应的摩尔比x / y作为金属物质沉积在基底上的锰和钴; 和b）原位氧化金属物质以形成尖晶石。 该方法特别用于固体氧化物燃料电池（SOFC）的金属互连涂层。

公开(公告)号：EP2264799B1

公开(公告)日：2013-03-06

申请号：EP10165781.5

申请日：2010-06-14

申请人： Edison S.p.A.

发明人： Giunchi, Giovanni

IPC分类号： H01L39/14 ,  H01L39/16 ,  H01L39/24 ,  C04B35/45 ,  C04B35/547 ,  C04B35/58 ,  C22C28/00 ,  C22C38/00

CPC分类号： H01L39/14 ,  C04B35/45 ,  C04B35/547 ,  C04B35/58057 ,  C04B2235/3213 ,  C04B2235/3272 ,  C04B2235/77 ,  C22C28/00 ,  C22C38/00 ,  H01L39/141 ,  H01L39/16 ,  H01L39/24 ,  H01L39/2477 ,  H01L39/2487

公开(公告)号：EP1678341A2

公开(公告)日：2006-07-12

申请号：EP04769352.8

申请日：2004-09-10

申请人： EDISON S.p.A.

发明人： BALDINI, Alberto ,  GAUZZI, Andrea ,  ZANNELLA, Sergio

IPC分类号： C23C14/22 ,  C23C14/56

CPC分类号： C23C14/5846 ,  C23C14/0021 ,  C23C14/228 ,  C23C14/24 ,  C23C14/562 ,  C23C14/5853 ,  H01L39/2432

摘要： There are provided herein a method and an apparatus for deposition of films of coating materials on a substrate, of particular use in obtaining superconductive composite tapes for deposition of films of superconductive oxides and/or buffer layers. A step of deposition of the film (2) on the substrate (4) is associated to a step of gas treatment in situ, in which a flow (13) of gas is sent towards a working surface (14) of the substrate or of the film growing on the substrate. The gas-treatment step is performed via ultrasound­expansion nozzles (26).

公开(公告)号：EP2886678A8

公开(公告)日：2015-10-28

申请号：EP14199052.3

申请日：2014-12-18

申请人： EDISON S.p.A.

发明人： Bindi, Massimiliano

IPC分类号： C23C14/54 ,  C23C14/30 ,  C23C14/08 ,  C23C14/58

CPC分类号： C23C14/545 ,  C23C14/083 ,  C23C14/088 ,  C23C14/30 ,  C23C14/5806 ,  C23C14/5853 ,  H01M4/8867 ,  H01M4/8882 ,  H01M4/8885 ,  H01M4/9033 ,  H01M8/1213 ,  H01M8/1246 ,  H01M2008/1293 ,  Y02E60/525 ,  Y02P70/56

摘要： In a method for the deposition of a film of mixed oxide on a composite material substrate, a step of evaporation-deposition of the mixed oxide, carried out with the aid of an electron beam sent to a target of mixed oxide having the same stoichiometric composition as the film to deposit, is carried out at an increasing deposition rate, measured on the substrate; in particular, the evaporation-deposition step comprises at least one first step of growth carried out at a deposition rate lower than or equal to a predetermined threshold, and at least one second step of growth carried out at a deposition rate higher than the threshold.

摘要翻译： 在用于在复合材料基底上沉积混合氧化物膜的方法中，借助于发送到具有相同化学计量组成的混合氧化物靶的电子束进行混合氧化物的蒸发沉积步骤 作为要沉积的膜，以在衬底上测量的增加的沉积速率进行; 特别地，蒸发沉积步骤包括以低于或等于预定阈值的沉积速率进行的至少一个第一生长步骤和以高于阈值的沉积速率进行的至少一个第二生长步骤。

公开(公告)号：EP1867602A2

公开(公告)日：2007-12-19

申请号：EP07109054.2

申请日：2007-05-29

申请人： Edison S.p.A.

发明人： Zanella, Pierino ,  Crociani, Laura ,  Giunchi, Giovanni

IPC分类号： C01B3/00 ,  C01B3/06 ,  C01B6/04 ,  C01B6/21 ,  C01B21/064

CPC分类号： C01B3/065 ,  C01B6/04 ,  C01B6/21 ,  Y02E60/324 ,  Y02E60/362

摘要： A process is described for the preparation of magnesium borohydride having a high purity and crystallinity, which comprises the reaction of an organometallic compound of magnesium of the type MgX 2 , wherein X is an organic binder selected from alkyl, amide, alkoxide, cyclopentadienyl, aryl, with a derivative of a boron hydride, in a hydrocarbon solvent.

摘要翻译： 描述了制备具有高纯度和结晶度的硼氢化镁的方法，其包括MgX 2型镁的有机金属化合物的反应，其中X是选自烷基，酰胺，醇盐，环戊二烯基，芳基的有机粘合剂 与硼氢化物的衍生物在烃溶剂中反应。

公开(公告)号：EP1668713A2

公开(公告)日：2006-06-14

申请号：EP04769347.8

申请日：2004-09-10

申请人： EDISON S.p.A.

发明人： BALDINI, Alberto ,  GAUZZI, Andrea ,  ZANNELLA, Sergio

IPC分类号： H01L39/24

CPC分类号： H01L39/2461

摘要： There is provided a method for making biaxially textured layers on non-textured substrates, in particular for making intermediate buffer layers in superconductive composite tapes. A non-textured substrate is provided with a surface having a roughness of less than approximately 10 nm and preferably less than approximately 5 nm. This is followed by a deposition step, in which a deposition material is deposited on said surface with direct evaporation without any concern for orientation; the deposition material grows in a natural texture on the surface to form an oriented layer with biaxial texture.

公开(公告)号：EP1390992A2

公开(公告)日：2004-02-25

申请号：EP02727859.7

申请日：2002-05-10

申请人： Edison S.P.A.

发明人： GIUNCHI, Giovanni ,  CERESARA, Sergio

IPC分类号： H01L39/24

CPC分类号： H01L39/2487 ,  C04B35/58057 ,  C04B35/6261 ,  C04B35/65 ,  C04B35/653 ,  C04B2235/40 ,  C04B2235/401 ,  C04B2235/421 ,  C04B2235/5292 ,  C04B2235/5436 ,  C04B2235/80

摘要： A method is described for the preparation of superconductor massive bodies of MgB2, having a density close to the theorical value, which comprises the following passages: mechanical activation of crystalline boron with the formation of activated powders; formation of a porous preform of said powders; assembly of the porous boron preform and massive precursors of metallic magnesium in a container and sealing thereof in an atmosphere of inert gas or with a low oxygen content; thermal treatment of the boron and magnesium as assembled above, at a temperature higher than 700 °C for a time greater than 30 minutes, with the consequent percolation of the magnesium, in liquid phase, through the activated crystalline boron powders.