CHROMIUM DIOXIDE (CRO SB 2 /SB ) AND COMPOSITES OF CHROMIUM DIOXIDE AND OTHER OXIDES OF CHROMIUM SUCH AS CRO SB 2 /SB /CR SB 2 /SB O SB 3 /SB AND CRO SB 2 /SB /CR SB 2 /SB O SB 5 /SB AND PROCESS FOR MANUFACTURING THE SAME
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    发明公开
    CHROMIUM DIOXIDE (CRO SB 2 /SB ) AND COMPOSITES OF CHROMIUM DIOXIDE AND OTHER OXIDES OF CHROMIUM SUCH AS CRO SB 2 /SB /CR SB 2 /SB O SB 3 /SB AND CRO SB 2 /SB /CR SB 2 /SB O SB 5 /SB AND PROCESS FOR MANUFACTURING THE SAME 审中-公开
    二氧化铬(CRO SB 2 / Sb)和复合氧化物的二氧化铬和其它铬氧化物,例如氧化铬SB 2 / SB / CR SB 2 / SBøSB 3 / Sb和CRO SB 2 / SB / CR SB 2 / SBøSB 5 / SB和 VERFHAREN生产

    公开(公告)号:EP1534634A2

    公开(公告)日:2005-06-01

    申请号:EP03791168.2

    申请日:2003-08-22

    摘要: A novel process for preparing chromium dioxide of substantially high purity as well as composites of CrO 2 /Cr 2 O 3 and CrO 2 /Cr 2 O 5 following a sequence of simple steps. The process does not require pressure as a control parameter during the process of synthesis. No chemical modifier has been used to bring down the working pressure during synthesis. Fairly hard sintered pellets of CrO 2 can be obtained without introducing any detectable impurity phase that usually appears during the process of sintering. Further, CrO 2 /Cr 2 O 3 and CrO 2 /Cr 2 O 5 composites have also been prepared where the fraction of insulating Cr 2 O 3 or Cr 2 O 5 in metallic CrO 2 can be easily controlled. Significant negative magnetoresistance is found in pure CrO 2 (5% MR) as well as CrO 2 /Cr 2 O 3 (33% MR) composites near room temperature. The MR studies on the CrO 2 /Cr 2 O 5 composites have been done and significant negative MR (22%) has been found in CrO 2 /Cr 2 O 5 composites near room temperature.

    摘要翻译: 用于制备基本上高纯度的二氧化铬以及以CrO 2 / Cr的 2 0 3 和的CrO 2的复合材料的新方法 / Cr的 2 0 5 继的简单的步骤的序列。 过程合成的过程中不要求压力作为控制参数。 无化学修饰已被用于合成过程中,以降低工作压力。 的CrO 2 的相当硬烧结粒料可以在不烧结的过程中引入的任何可检测杂质相做了一般显示来获得。 此外,氧化铬 2 / Cr的 2 0 3 和的CrO 2 / Cr的 2 0 5 因此复合材料已被制得,其中绝缘的Cr 2 0 3 或Cr 2 0 5 在金属的CrO 2 可以容易地控制。 显著负磁阻以纯的CrO 2 (5%MR)以及以CrO 2 / Cr的 2 0 3 室温附近(33%MR)复合材料。 2 / Cr的 2 0 5 复合材料已经完成和显著负MR(22%)已经以CrO发现上的CrO 的MR研究 2 / Cr的 2 0 5 室温附近的复合材料。