摘要:
The present disclosure relates to a method of applying a pressure sensitive adhesive to a substrate, which comprises the steps of: a) providing an uncrosslinked curable precursor of a pressure sensitive adhesive comprising: (1) a (meth)acrylate copolymer component comprising: i. C 1 -C 32 (meth)acrylic acid ester monomer units; ii. ethylenically unsaturated monomer units having functional groups selected from the group consisting of acid, hydroxyl, acid anhydride, epoxide, amine, amide groups, and any combinations thereof; and iii. optionally, further ethylenically unsaturated monomer units which are copolymerizable with monomer units (i) and/or (ii);
(2) a thermal crosslinking system; (3) at least one expandable microsphere; (4) optionally, a tackifying system; and (5) optionally, at least one pigment;
b) subjecting the curable precursor of a pressure sensitive adhesive to a first heating step such that the curable precursor of a pressure sensitive adhesive is partially crosslinked; c) contacting the curable precursor of a pressure sensitive adhesive obtained in step b) to at least part of the surface of the substrate; d) subjecting the curable precursor of a pressure sensitive adhesive to a second heating step such that the curable precursor of a pressure sensitive adhesive is fully crosslinked; and e) optionally, allowing the polymeric foam layer to cool down on the substrate.
摘要:
The present disclosure relates to a multilayer pressure sensitive adhesive assembly comprising at least a first pressure sensitive adhesive layer and a second pressure sensitive adhesive layer adjacent to the first pressure sensitive adhesive layer, wherein the first pressure sensitive adhesive layer and the second pressure sensitive adhesive layer comprise a polymer base material selected from the group of polyacrylates, wherein the second pressure sensitive adhesive layer has a thickness no greater than 250 micrometres and comprises silica nanoparticles having an average particle size no greater than 400 nm when measured by Dynamic Light Scattering (DLS) techniques according to the test method described in the experimental section, and wherein the first pressure sensitive adhesive layer has a thickness in a range from 250 to 5000 micrometres and is substantially free of particulate filler material. According to another aspect, the present disclosure is directed to an article comprising a medium surface energy substrate and a multilayer pressure sensitive adhesive assembly as described above adjacent to the medium surface energy substrate. In another aspect, the present disclosure relates to the use of a multilayer pressure sensitive adhesive assembly as described above for the bonding to a medium surface energy substrate or a high surface energy substrate.
摘要:
The present disclosure is directed to a curable precursor of a pressure sensitive adhesive comprising: a) a (co)polymeric material comprising the reaction product of a (co)polymerizable material comprising a (meth)acrylate ester monomer; and optionally, a co-monomer having an ethylenically unsaturated group; b) a polyfunctional aziridine curing agent; and c) an acid generating agent. The present disclosure is also directed to a method of manufacturing such pressure sensitive adhesives and uses thereof.
摘要:
The present disclosure is directed to a curable precursor of a pressure sensitive adhesive comprising: a) a (co)polymeric material comprising a rubber-based elastomeric material; b) a polyfunctional aziridine curing agent; and c) an acid generating agent. The present disclosure is also directed to a method of manufacturing such pressure sensitive adhesives and uses thereof.
摘要:
A multilayer pressure sensitive adhesive (PSA) film having a first pressure sensitive adhesive layer for bonding glass substrates and at least a second opposing layer, the first pressure sensitive adhesive layer being a polymerization reaction product of a precursor comprising a monomer or a partially prepolymerized monomer, in particular a (meth)acrylate based monomer having a curable ethylene group, whereas the precursor further comprises an oligomeric organofunctional silane having at least 2 Si atoms, in particular 2 to 10 Si atoms, wherein the monomer further has a coupling group with a Zerewitinow-active H-atom and wherein the oligomeric organofunctional silane has at least one coupling group which is reactive to the coupling group of the monomer having a curable ethylene group, or wherein the oligomeric organofunctional silane has at least one coupling group with a Zerewitinow-active H-atom and wherein the monomer has a coupling group which is reactive to the coupling group of the oligomeric organofunctional silane.
摘要:
The present disclosure is directed to a curable precursor of a pressure sensitive adhesive comprising: a) a (co)polymeric material comprising a rubber-based elastomeric material; b) a polyfunctional aziridine curing agent; and c) an acid generating agent. The present disclosure is also directed to a method of manufacturing such pressure sensitive adhesives and uses thereof.