摘要:
Provided are a recycling method for industrially, simply and effectively recycling a phenolic body from a phenolic antioxidant which is masked by an organoaluminum compound and contained in an olefin polymer obtained by supplying the masked phenolic antioxidant upon polymerization; and an olefin polymer obtained by this method. In a method for recycling a phenolic antioxidant wherein a phenolic antioxidant which is masked by an organoaluminum compound and contained in an olefin polymer obtained by supplying the masked phenolic antioxidant upon polymerization is recycled to a phenolic body, a nitrogen gas comprising water and/or a proton donor at a volume ratio of 1.0×10 -6 to 2.5×10 -2 with respect to 1 volume of nitrogen is brought into contact with the olefin polymer.
摘要:
Provided is a method of producing a stabilized polymer by which, while imparting sufficient stabilizing effect to the polymer of a monomer having an ethylenically unsaturated bond, the amount of residual solvent in the polymer can be reduced and the occurrence of foaming can be inhibited. The method of producing a stabilized polymer comprises the step of adding an antioxidant having a melting point of 70°C or lower to a catalyst system or a polymerization system before or during polymerization of a monomer having an ethylenically unsaturated bond such that 0.005 to 0.5 parts by mass of the antioxidant is incorporated with respect to 100 parts by mass of a polymer obtained by the polymerization of the monomer having an ethylenically unsaturated bond.
摘要:
Provided is a method of producing a nucleator masterbatch, by which a nucleator masterbatch capable of improving the transparency and the physical properties of an olefin resin can be produced. This method is a method of producing a masterbatch in which a nucleator is blended in an olefin polymer, the method being characterized by comprising the step of polymerizing an olefin monomer with incorporation of a nucleator component, which is dissolved in an organoaluminum compound or in an organoaluminum compound and an organic solvent, before or during polymerization of the olefin monomer such that the nucleator component is blended in an amount of 0.05 to 20 parts by mass with respect to 100 parts by mass of the olefin polymer obtained by the polymerization of the olefin monomer.
摘要:
The present invention provides a method of producing an olefin resin composition by which an olefin resin composition in which reduction in the physical properties and occurrence of yellowing after a sterilization treatment by irradiation with radiation are suppressed can be produced. The method of producing an olefin resin composition according to the present invention is a method of producing an olefin resin composition for a molded article to be used after a sterilization treatment by irradiation with radiation, the method comprising: blending, before or during polymerization of an olefin monomer, a phenolic antioxidant, which is represented by the following Formula (1) and masked with an organoaluminum compound, in an amount of 0.001 to 0.5 parts by mass with respect to 100 parts by mass of an olefin resin obtained by the polymerization; and blending, at any one point of before, during or after the polymerization of the olefin monomer, a phosphorus-based antioxidant in an amount of 0.001 to 3 parts by mass with respect to 100 parts by mass of the olefin resin obtained by the polymerization: (wherein, R represents, for example, an alkyl group having 12 to 24 carbon atoms which is optionally branched and/or substituted).