Reactivation of spent chromia-alumina catalyst by zinc oxide doping
    4.
    发明公开
    Reactivation of spent chromia-alumina catalyst by zinc oxide doping 失效
    通过用氧化锌中掺杂激活废铬 - 铝氧化物催化剂。

    公开(公告)号:EP0048409A1

    公开(公告)日:1982-03-31

    申请号:EP81107168.7

    申请日:1981-09-10

    IPC分类号: B01J23/92 B01J23/26

    摘要: A method for the reactivation of aged chromia-alumina dehydrogenation catalyst which involves doping the aged catalyst with minor amounts of zinc oxide, preferably in the range of about 0.35% zinc oxide to 1.35% zinc oxide on the catalyst. The zinc oxide is added to the aged catalyst preferably by impregnation by immersion or spraying of a zinc nitrate solution, followed by drying and heat treating. Alternatively the zinc oxide addition can be accomplished by use of a volatile organic zinc compound added to the saturated feedstock and subsequent air regeneration of the catalyst in situ without removal of the catalyst from the reactor.

    Amines via the amination of olefins using offretite
    6.
    发明公开
    Amines via the amination of olefins using offretite 失效
    Amine durch Aminierung von Olefinen mit der Verwendung von Offretit。

    公开(公告)号:EP0101921A1

    公开(公告)日:1984-03-07

    申请号:EP83107291.3

    申请日:1983-07-25

    IPC分类号: C07C85/18

    CPC分类号: C07C209/60

    摘要: This invention relates to an improvement in the vapor phase catalytic production of an amine by the reaction of a mixture comprising a C 2-4 olefin and ammonia. The improvement which provides for high conversion and selectivity to the amine resides in the use of an acidic offretite as the catalyst.

    摘要翻译: 本发明涉及通过包含C2-4烯烃和氨的混合物的反应来气化催化生产胺的改进。 提供对胺的高转化率和选择性的改进在于使用酸性漂白剂作为催化剂。