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公开(公告)号：EP2516375A1
公开(公告)日：2012-10-31
申请号：EP10808909.5
申请日：2010-12-21
申请人： Adisseo France S.A.S. , Centre National de la Recherche Scientifique , Université Lille 1 - Sciences Et Technologies
IPC分类号： C07C45/52 , C07C319/20 , C07C323/22 , C07C323/52 , C07C47/22
CPC分类号： C07C319/18 , B01J27/188 , B01J27/28 , B01J29/0308 , B01J29/0341 , B01J29/90 , B01J2229/12 , B01J2229/34 , C07C45/52 , C07C319/20 , Y02P20/584 , C07C47/22 , C07C323/22 , C07C323/60 , C07C323/58 , C07C323/52
摘要： The invention relates to a method for preparing acrolein from glycerol or glycerine, according to which the glycerol or glycerine is dehydrated in the presence of a catalyst that consists of least one silica modified by zirconium dioxide, titanium dioxide or tungsten trioxide or any combination of said oxides, and a heteropolyacid. Said method can be used for the production of 3-(methylthio)propionaldehyde (MMP), 2-hydroxy-4(methylthio)butyronitrile (HMTBN), methionine or analogue substances thereof, using acrolein.
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公开(公告)号：EP3124462B1
公开(公告)日：2019-01-30
申请号：EP15306244.3
申请日：2015-07-30
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3.发明公开
公开(公告)号：EP3328821A1
公开(公告)日：2018-06-06
申请号：EP16744738.2
申请日：2016-07-27
申请人： Centre National de la Recherche Scientifique , Ecole Centrale De Lille , National Institute of Advanced Industrial Science and Technology , Université Lille 1 - Sciences Et Technologies
IPC分类号： C07C29/60 , C07C33/03 , B01J23/656
CPC分类号： B01J23/36 , B01J21/04 , B01J35/1019 , B01J37/0201 , C07C29/60 , C07C33/03 , C07C2523/36
摘要： The present invention relates to the use of an alumina-supported rhenium oxide catalyst for the deoxydehydration of glycerol to allyl alcohol, as well as to a process for the production of allyl alcohol from glycerol in the presence of such a heterogeneous catalyst.
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公开(公告)号：EP2943436B1
公开(公告)日：2018-11-21
申请号：EP14703116.5
申请日：2014-01-09
申请人： Centre National de la Recherche Scientifique (C.N.R.S.) , Université Lille 1 - Sciences Et Technologies
IPC分类号： C01B3/32
CPC分类号： B01J23/83 , B01J35/002 , B01J35/023 , B01J35/1014 , B01J35/1019 , B01J37/009 , B01J37/03 , B01J37/14 , B01J37/18 , C01B3/326 , C01B2203/0233 , C01B2203/1058 , C01B2203/1217 , C01B2203/1229 , Y02P20/52
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公开(公告)号：EP2943436A1
公开(公告)日：2015-11-18
申请号：EP14703116.5
申请日：2014-01-09
申请人： Centre National de la Recherche Scientifique (C.N.R.S.) , Université Lille 1 - Sciences Et Technologies
IPC分类号： C01B3/32
CPC分类号： B01J23/83 , B01J35/002 , B01J35/023 , B01J35/1014 , B01J35/1019 , B01J37/009 , B01J37/03 , B01J37/14 , B01J37/18 , C01B3/326 , C01B2203/0233 , C01B2203/1058 , C01B2203/1217 , C01B2203/1229 , Y02P20/52
摘要： The present invention relates to a method for producing hydrogen at a low temperature from alcohols without forming carbon, using a cerium and nickel oxyhydride material, and to the use of such a material as a catalyst for transforming alcohols into hydrogen.
摘要翻译： 本发明涉及一种使用铈和氢氧化镍材料从醇形成低温氢而不形成碳的方法，并且涉及这种材料作为将醇转化成氢的催化剂的用途。
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6.发明公开USE OF MOLYBDENUM AND VANADIUM MIXED OXIDES AS CATALYSTS FOR THE OXIDATION OF UNSATURATED ALCOHOLS INTO UNSATURATED CARBOXYLIC ACIDS 审中-公开钼和钒混合氧化物作为催化剂将不饱和醇氧化成未饱和羧酸
公开(公告)号：EP3310749A1
公开(公告)日：2018-04-25
申请号：EP15777997.6
申请日：2015-06-18
申请人： Centre National de la Recherche Scientifique , UNIVERSITE DES SCIENCES ET TECHNOLOGIES DE LILLE , Ecole Centrale De Lille , HOKKAIDO UNIVERSITY
发明人： PAUL, Sébastien , DUMEIGNIL, Franck , KATRYNIOK, Benjamin , ARAQUE MARIN, Marcia , MURAYAMA, Toru , UEDA, Wataru
CPC分类号： C07C51/235 , B01J23/28 , B01J23/8877 , B01J37/06 , B01J37/10 , B01J2523/00 , C07C57/04 , B01J2523/17 , B01J2523/55 , B01J2523/68 , B01J2523/56 , B01J2523/64 , B01J2523/57 , B01J2523/69
摘要： The present invention relates to the use of molybdenum and vanadium mixed oxides, optionally iron doped, as catalysts for the oxidation of unsaturated alcohols, in particular allyl alcohol, and also to a process for the production of unsaturated carboxylic acids, in particular acrylic acid, in the gas phase, in the presence of such a catalyst.
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公开(公告)号：EP3066066A1
公开(公告)日：2016-09-14
申请号：EP14806022.1
申请日：2014-11-06
申请人： Pivert , Centre National de la Recherche Scientifique (CNRS) , Université des Sciences et Technologies de Lille 1 , Ecole Centrale De Lille
CPC分类号： C07C67/40 , C07C29/149 , C07C67/00 , C07F15/0046 , C07C33/025 , C07C69/58
摘要： According to one embodiment, the invention relates to a method for synthesising a second ester from a first ester, said method including the following steps: a) placing a first ester and a catalyst in the presence of dihydrogen such as to obtain a first alcohol and a second alcohol; b) extracting said second alcohol from the reaction medium; c) reacting said first alcohol with the catalyst of step a) in order to obtain a second ester and dihydrogen; and d) recirculating the dihydrogen obtained in step c) by injecting same into step a).
摘要翻译： 一种从第一酯合成第二酯的方法，所述方法包括以下步骤：a）在二氢的存在下放置第一酯和催化剂以获得第一醇和第二醇; b）从反应介质中提取第二种醇; c）使第一醇与步骤a）的催化剂反应，以获得第二酯和二氢; 和d）将步骤c）中获得的二氢循环通过将其注入步骤a）中。
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公开(公告)号：EP3310749B1
公开(公告)日：2019-05-15
申请号：EP15777997.6
申请日：2015-06-18
申请人： Centre National de la Recherche Scientifique , Université des Sciences et Technologies de Lille - Lille 1 , Ecole Centrale De Lille , Hokkaido University
发明人： PAUL, Sébastien , DUMEIGNIL, Franck , KATRYNIOK, Benjamin , ARAQUE MARIN, Marcia , MURAYAMA, Toru , UEDA, Wataru
IPC分类号： C07C51/235 , C07C57/04 , B01J23/28 , B01J23/887
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9.发明公开PRODUCTION D'ACIDES OU D'ESTERS D'ACIDES CARBOXYLIQUES INSATURÉS AVEC UN CATALYSEUR À BASE D'HALOGENO-APATITE 审中-公开生产德酸欧达酯类羧酸油品保健品AVEC UN CATALYSEURÀBASE D'HALOGENO-APATITE
公开(公告)号：EP3229955A1
公开(公告)日：2017-10-18
申请号：EP15816819.5
申请日：2015-12-08
申请人： Centre National de la Recherche Scientifique , Ecole Centrale De Lille , Université des Sciences et Technologies De Lille - Lille 1
IPC分类号： B01J27/18 , B01J27/138 , C07C51/377 , B01J35/02 , C01B25/32 , C07C67/327 , C07C69/54 , C07C57/04 , C07C59/08
CPC分类号： B01J27/1806 , B01J27/12 , B01J27/138 , B01J37/03 , C01B25/455 , C07C51/377 , C07C57/04
摘要： The invention relates to the use of haloapatites as a catalyst in the dehydration reaction of α-hydroxylated carboxylic acids or acid esters, in particular lactic acid or methyl lactate, as well as to a method for synthesizing unsaturated carboxylic acids or acid esters, in particular acrylic acid or methyl acrylate, in the gaseous phase in a stainless steel reactor in the presence of a catalyst of said type.
摘要翻译： 本发明涉及卤代磷灰石作为催化剂在α-羟基化羧酸或酸酯，特别是乳酸或乳酸甲酯的脱水反应中的用途，以及合成不饱和羧酸或酸酯的方法，特别是 丙烯酸或丙烯酸甲酯在气相中在不锈钢反应器中在所述类型的催化剂存在下进行。
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公开(公告)号：EP2953936B1
公开(公告)日：2019-04-17
申请号：EP14702615.7
申请日：2014-02-05
发明人： CLACENS, Jean-Marc , DECAMPO, Floryan , GRASSET, Fabien , KATRYNIOK, Benjamin , DUMEIGNIL, Franck , PAUL, Sébastien , RATAJ, Véronique
IPC分类号： C07D307/46 , C07C45/38
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